MCM-41分子筛和催化剂的特殊吸附等温线

测定了MCM-41中孔分子筛和催化剂的吸附等温线, 发现它们形状非常特殊, 不仅可逆部分分两段, 并且还存在两个滞后环, 在相对压力0.4以前出现的第一个滞后环可归属于中孔孔道内的毛细凝聚, 在饱和压力附近出现的第二个滞后环可归属于分子筛颗粒之间的毛细凝聚。利用吸附和XRD数据, 可有效地表征MCM-41分子筛和催化剂的结构有序度和孔道畅通情况。     

血管输入阻抗的拟合方法与初值选取

研究了模拟动脉系统的集中参数模型的数据拟合问题,分析了用修正的Noordeergraaf五单元模型计算血管输入阻抗的有关问题,对参数拟合问题中被广泛运用的Newton迭代法与正交试验法作了评述,就其中至关重要的初值选取问题建议了一些简单实用的方法,讨论了参数选取的范围与参考值,并将数值计算结果与实测结果作了比较,所建议方法的有效性得到了证实。     

环形激波绕射、反射和聚焦流场的间断有限元模拟

采用间断有限元方法对环形激波在圆柱形激波管内绕射、反射和聚焦流场进行了数值模拟。将二维守恒方程的间断有限元方法发展到轴对称Euler方程,并对环形激波绕后台阶流动进行了数值计算。计算结果表明,采用间断有限元方法能够有效地捕捉运动激波在圆柱形激波管内传播的复杂流场结构;在聚焦点附近,数值解具有较大的梯度变化,表明该方法对间断解具有较强的捕捉能力,在聚焦点附近不会产生振荡或抹平间断现象。     

Simulation of 200–400 Me V/u ~(12)C+~(12)C elastic scattering on SHARAQ spectrometer

In order to further obtain the information of three-body force(TBF) from 200–400 Me V/u12C+12C elastic scattering, we plan to perform this experiment on a SHARAQ spectrometer. Based on the experimental condition of the Radioactive Ion Beam Factory(RIBF)-SHARAQ facility, a simulation is given to find a compromise between the better energy and angular resolutions, and higher yield by optimizing the target thickness, beam transport mode, beam intensity and angular step. From the simulation, we found that the beam quality mainly limits the improvements of energy and angular resolutions. A beam tracking system as well as a lateral and angular dispersionmatching technique are adopted to reduce the influence of beam quality. According to the two angular settings of SHARAQ as well as the expected cross sections on the basis of the theoretical model, the energy and angular resolutions, and statistical accuracy are estimated.     

A transmission problem with non‐linear internal damping in elasticity

We consider an anisotropic body constituted by two different types of materials: a part is simple elastic while the other has a non‐linear internal damping. We show that the dissipation caused by the damped part is strong enough to produce uniform decay of the energy, more precisely, the energy decays exponentially when the dissipation is linear with respect to the velocity. For a non‐linear class of dissipations we prove that the energy decays polynomially. Copyright © 2003 John Wiley & Sons, Ltd.     

广义Lebesgue-Ramanujan-Nagell方程研究的新进展

广义Lebesgue-Ramanujan-Nagell方程是数论中一类重要的Diophantine方程.本文介绍了此类方程的近期结果和尚未解决的问题.     

HPLC-ELSD法测定绞股蓝中绞股蓝皂苷A的含量

采用HPLC-ELSD法测定绞股蓝中绞股蓝皂苷A的含量。色谱柱为HibarC18(250×4.6mm,5μm),流动相为乙腈-水梯度洗脱,流速0.5mL/min,柱温为20℃,绞股蓝皂苷A在0.0425—1.995mg/mL范围内线性关系良好(r2=0.9962),并通过正交法优化其提取工艺。该方法简便、有效,为绞股蓝的质量控制提供一种准确可行的检测方法。     

Schiff碱药物对产气杆菌代谢抑制的热力学研究

用微量热法测定产气杆菌在不同温度条件下受到Schiff碱药物抑制的热谱曲线, 根据其指数生长期的热谱信息, 确定它在不同温度条件下的生长速率常数和反应活化能, 找出了该细菌的最佳生长温度。同时借用化学反应中的过渡态理论, 得到一系列热力学参数, 对细菌在受到抑制时的生长代谢进行了热力学分析。     

三齿NS2型配体Cu(Ⅱ)配合物的合成、光谱性质及电化学性质

A variety of complexes Cu(NS₂)(Im)(NO₃)₂ and Cu(NS₂)(Py)(NO₃)₂ where NS₂=HN(CH₂CH₂SR)₂(R=CH₃CH₂CH₂, (CH₃)₂CH,CH₃CH₂CH₂CH₂ and (CH₃)₂CHCH₂), have been synthesized and characterized by elementary analyses, molar conductivity, IR, UV/Vis and ESR spectra as well as by electrochemical methods. The new complexes exhibit exceptionally high redox potentials(500～580 mV) and complexes for HN(CH₂CH₂SCH(CH₃)₂)₂ exihibit rather hyperfine splitting constants(a_‖<70G) in the powder ESR spectra, which are close to those for the blue copper proteins.     

Studies on NaXe Clusters

In this paper all NaCl crystal samples containing metallic sodium colloids used in experiments were cleaved to ~1mm thickness from a block of NaCl single crystal at room temperature1,2. Two parallel large surfaces of each crystal were polished. Then these NaCl crystal specimens were implanted at 10-6 Torr with xenon ions using an accelerating voltage of 36 keV. The xenon ion fluences were in the range from 1(1015/cm2 to 7(1017/cm2. The chemical shifts of 23Na in these NaCl crystal specime…