Optimization of organic electrochemical transistors for sensor applications

Despite the recent interest in organic electrochemical transistors (OECTs) as chemical and biological sensors, little is known about the role that device architecture and materials parameters play in determining sensor performance. We use numerical modeling to establish design rules in two regimes of operation: We find that for operation as an ion‐to‐electron converter, the response of OECTs is maximized through the use of a gate electrode that is much larger than the channel or through the use of a nonpolarizable gate electrode. Improving the conductivity of the polymer and using a channel geometry that maximizes channel width and thickness, and minimizes channel length helps increase the response. For operation as an electrochemical sensor, the sensitivity is maximized in OECTs with gate electrodes that are smaller than their channels. The sensitivity can be improved by increasing the charge carrier mobility and the capacitance per unit area of the conducting polymer, and also its ability to be penetrated by ions from the electrolyte. A channel geometry that maximizes channel width and minimizes channel length also improves sensitivity. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010     

A Dimroth rearrangement approach for the synthesis of selenopheno[2,3-e][1,2,4]triazolo[1,5-c]pyrimidines with cytotoxic activity on breast cancer cells

Molecular Diversity - New selenopheno[2,3-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives have been synthesized via Dimroth rearrangement by cyclocondensation of...     

Modified nanoporous silicas for oral delivery of the water insoluble organotin compound: loading and release of methylphenyltin dichloride as an anti-tumor drug model

Different nanoporous silica materials, MCM-41, MCM-48 and SBA-15, were modified by pyridine and their applications for oral drug delivery system were evaluated. These pyridine functionalized nanoporous silicas were loaded with a water insoluble diorganotin(IV) dichloride complex as an antitumor drug model and its release from them were investigated by changing pH. An efficient pH-responsive carrier system was constructed by coordination of the pyridine group in modified nonoporous materials to tin complex. In vitro, releasing of loaded tin complex was studied in three different kinds of fluids, including a simulated gastric medium and a simulated body fluid. The loading and releasing of the diorganotin(IV) dichloride from various modified nanoporous silicas and also a non-porous silica (SiO₂) were investigated, and the results were compared. In addition, the effect of some factors such as pH, time of loading and releasing were investigated through this study.     

Synthesis of ethyl 3-phenyl-4-(trifluoromethyl)isoxazole-5-carboxylate via regioselective dipolar cycloaddition

Efforts to prepare ethyl 3-phenyl-4-(trifluoromethyl)isoxazole-5-carboxylate (1) by developing a regioselective 1,3-dipolar cycloaddition between phenyl nitrile oxide and various 4,4,4-trifluoromethyl crotonates are described. The substitution at the C2-position of crotonate dipolarophile 4 significantly influenced the regiochemistry and yield of the cycloaddition. Enol and enol ether-based crotonates underwent regioselective cycloadditions with phenyl nitrile oxide to provide 4-trifluoromethyl isoxazoles in good yields.     

A new image encryption method: parallel sub-image encryption with hyper chaos

A new image encryption scheme, based on a total shuffling and parallel encryption algorithm is proposed in this paper. Two chaotic systems have been used in the encryption algorithm to confuse the relationship between the plain-image and the cipher-image. To make the encryption procedure more confusing and complex, the plain-image is first divided into 4 sub-images and then the position of each sub-image is changed pseudo-randomly according to a logistic map. Next, a total shuffling matrix is used to shuffle the position of pixels in the whole image and then sub-images are encrypted simultaneously in a parallel manner. The experimental results on USC data base demonstrate that the proposed encryption algorithm has a low time complexity and has the advantages of large key space and high security. Moreover, the robustness of this locally encryption method is much more in contrast with other encryption schemes and the distribution of gray values has a random-like behavior in the encrypted image.     

A concise review on the role of nanoparticles upon the productivity of solar desalination systems

Journal of Thermal Analysis and Calorimetry - In recent years, nanofluids have been widely used to improve the performance of various energy systems due to their favourable thermo-physical and...     

Recent Advances in Heat and Mass Transfer

Journal of Thermal Analysis and Calorimetry -     

Experimental investigation on the effect of natural gas premixed ratio on combustion and emissions in an IDI engine

Journal of Thermal Analysis and Calorimetry - Usage of natural gas in an internal combustion engine that has different combustion technologies is considered a possible solution to reduce engine...     

Thermal performance improvement in water nanofluid/GNP–SDBS in novel design of double-layer microchannel heat sink with sinusoidal cavities and rectangular ribs

In this numerical study, laminar flow of water nanofluid/GNP–SDBS (graphene nanoplatelet–sodium dodecylbenzene sulfonate) for 0–0.1% solid nanoparticles mass fraction was investigated for Reynolds numbers of 50–1000 in 3D space via finite volume method. In the newly proposed microchannel design, the cooling fluid is moving in countercurrent in the upper and lower layers of the microchannels, and there are cavities and sinusoidal routes on the solid walls of the microchannel, and the presence of rectangular ribs on the flow centerline along the fluid path enhances mixing for cooling fluid and creates better heat transfer for warm surfaces. The results of this study show that this special design of the microchannel can have a substantial increase in Nusselt number and heat transfer so that in the considered geometry by adding solid nanoparticles mass fraction it is possible to increase average Nusselt number for each Reynolds number by approximately 20%. Also, the mixing of the fluid because of formation of secondary flows has a strong effect on making the temperature distribution uniform in the cooling fluid and solid bed (wall) of the microchannel, especially in the lower layer. The upper layer of the microchannel always has a lower temperature due to indirect contact with heat flux compared with the lower layer. In this study, by increasing Reynolds number and mass fraction of solid nanoparticles the Nusselt number is increased and heat resistance of the lower wall of the microchannel is reduced. Based on the investigation of flow field and heat transfer, the use of the proposed design of the microchannel is recommended for Reynolds number less than 300.

     

Interplay between the intramolecular hydrogen bonds and cation–π interactions in various complexes of salicylaldehyde,thiosalicylaldehyde and selenosalicylaldehyde with Li+, Na+, K+, Mg2+ and Ca2+ cations

For the first time, the mutual influences of the intramolecular hydrogen bond (IMHB) and cation–π interactions in various complexes of salicylaldehyde, thiosalicylaldehyde and selenosalicylaldehyde with Li⁺, Na⁺, K⁺, Mg²⁺ and Ca²⁺ cations were studied. First, the strength of IMHB and cation–π interactions of the mentioned complexes by energetic, geometrical, spectroscopic, topological and molecular orbital parameters was evaluated and compared with the corresponding results of benzene–cation complexes and salicylaldehyde analogues. The results show that the coexistence of IMHB and cation–π interactions increases the IMHB strength and decreases the cation–π interactions. Second, the significance of π–electron delocalisation (π–ED) within the resonance-assisted hydrogen bond (RAHB) unit and aromaticity of benzene ring in the studied complexes were estimated by using the harmonic oscillator model of aromaticity and compared with the respective amounts of references. The results indicated that the mentioned coupling decreases the π–ED of RAHB unit and aromaticity of the benzene ring. In addition, it was found that variations in the strength of the interactions, π–ED and aromaticity, depend on the charge-to-radius ratio of cations. Finally, the effects of replacement of O by S and Se atoms in both of the mentioned cases were explored.