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81.
82.
Eric L. Kendall Jung Yeon Han Michael S. Wiederoder Alex Sposito Andrew Wilson Omid D. Rahmanian Don L. DeVoe 《Journal of Polymer Science.Polymer Physics》2015,53(18):1315-1323
A soft lithographic method is described for casting functional thermoplastic devices with microscale features without the need for specialized tools or equipment. In the thermoplastic soft lithography process, termed solvent casting, low temperature supersaturated solutions of thermoplastic are poured over solvent permeable PDMS molds which allow omnidirectional solvent removal as they template functional microstructures into the thermoplastic layers. Rapid gelation of supersaturated solutions enables the deposition of multiple patterned layers of varying composition, with self‐adhesion of the solvent‐laden thermoplastic ensuring intimate bonding between adjacent layers. This latter feature is further used in this work to realize sealed thermoplastic microfluidic devices with high fidelity replication of microchannel features with negligible channel deformation. The incorporation of functional dopants into patterned thermoplastic layers allows the fabrication of thermoplastic devices with embedded fluorescent sensors and integrated conductive elements. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1315–1323 相似文献
83.
84.
Mahdi Sadeghi Omid Kiavar S. Hamed Hosseini Rozhin Fatehi Claudio Tenreiro 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(2):565-571
The Nitinol stent was bombarded in a cyclotron at a flux rate of 4 μA/cm2 to produce 48V via 48Ti (p, n) 48V reaction. In this study dose distribution of 48V radioactive stent was investigated for renal arteries. Version X-2.6 of the MCNP Monte Carlo radiation transport system
code was employed to calculate dose distribution around the stent. As 48V is a mixed gamma and beta particle emitter, two separate runs of MCNP for both beta and gamma particles were performed and
the total deposited dose was acquired by adding the two mentioned values. In order to verify the simulation, the calculated
results have been compared with previous published data for the source. Calculated results show high dose gradient near the
stent and the maximum amount of dose deposits at the vessel wall. According to (AAPM) TG-60/149 protocol, the dosimetric parameters,
including geometry function, G(ρ,z), radial dose function, g
L
(ρ), and anisotropy function, F(ρ,z), were also determined. 相似文献
85.
Methyl tertiary butyl ether (MTBE) is an organic compound thatis used to increase the gasoline octane number. At the beginning of 1980s, by discovering the undesirable effects of tetra ethyl lead usage in fuel, MTBE began to be used worldwide. But gradually the undesirable effects of MTBE on environment had been revealed. Adsorption is the most conventional and economical technology for MTBE removal from polluted water. In this research, some experiments have been done for studying the adsorption of MTBE on different solid adsorbent in continuous processes. In continuous experiments, the water polluted with known initial MTBE concentration passes through an adsorption column containing two kinds of adsorbent including granular activated carbon (GAC), powdered activated carbon (PAC). By measuring MTBE concentration in exit flow at different times the effect of different operating parameters such as temperature, pH, and flow rate have been studied and the optimum condition have been determined. The batch experimental results have been used to calculate the constant parameters of Langmuir adsorption isotherm equations. A dynamic simulation of MTBE adsorption on activated carbon in an adsorption column has been proposed. The comparison of the experimental data with the values given by the proposed model for similar operating conditions, verifies the accuracy of the proposed mathematical model. 相似文献
86.
Forouzan Aboufazeli Hamid Reza Lotfi Zadeh Zhad Omid Sadeghi Mohammad Karimi Ezzatolla Najafi 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(1):18-24
In this work, MCM-41 (Mobil Composition of Matter number 41) nanoporous silica has been synthesized and characterized by X-ray powder diffraction and IR spectroscopy. In the next step, poly-thiophene was coated on the nanoporous silica in order to increase its surface area. This composite was characterized by X-Ray powder diffraction, High resolution transmission electronic microscopy micrograph (HRTEM), elemental analysis (CHNS) and Thermal analysis (TG/DTA). The application of this composite was investigated in mercury ions removal from waste water prior to determination by inductively coupled plasma atomic emission spectroscopy (ICP-OES). In order to investigate the effect of nanoporous structure on the efficiency of this composite, the same composite without porous structure has been synthesized and the results were compared. 相似文献
87.
The polythiophene nanoparticles (nano-PT) were prepared with average diameter of 20–35 nm. The nanostructurals of polythiophene were confirmed by TEM and SEM analyzes. The kinetics of the thermal degradation and thermal oxidative degradation of nano-PT were investigated by thermogravimetric analysis. Kissinger method, Flynn–Wall–Ozawa method, and advanced isoconversional method have been used to determine the activation energies of nano-PT degradation. The results showed that the thermal stability of nano-PT in pure N2 is higher than that in air atmosphere. The analyzes of the solid-state processes mechanism of nano-PT by Criado et al. method showed: the thermal degradation process of nano-PT goes to a mechanism involving second-order (F 2 mechanism); otherwise, the thermo-oxidative degradation process of nano-PT is corresponding to a phase boundary controlled reaction mechanism (R 2 mechanism). 相似文献
88.
Masoud Salavati-Niasari Zeynab Behfard Omid Amiri Elahe Khosravifard S. Mostafa Hosseinpour-Mashkani 《Journal of Cluster Science》2013,24(1):349-363
Well-segregated bismuth sulfide (Bi2S3) nanorods with a high order of crystallinity have been successfully prepared from bismuth(III) monosalicylate [BiO(C7H5O3)] by a simple hydrothermal reaction in H2O at 180 °C. Bismuth(III) monosalicylate and thioglycolic acid act as the starting materials. The products were characterized by powder X-ray diffraction, Ultraviolet–Visible (UV–Vis) spectroscopy, transmission electron microscopy photoluminescence spectroscopy, and Fourier transform infrared spectra. The powder X-ray diffraction pattern shows the product belongs to the orthorhombic Bi2S3 phase. Their UV–Vis spectrum shows the absorbance at 328 nm, with its direct energy band gap of 2.6 eV. Bismuth salicylate, which is known to be a complex, may play a critical role as a precursor and a template for the growth of linear bismuth sulfide nanorods. Finally the influences of the reaction conditions are discussed and a possible mechanism for the formation of Bi2S3 nanorods is proposed. 相似文献
89.
Masoud Salavati-Niasari Sakineh Alizadeh Mehdi Mousavi-Kamazani Noshin Mir Omid Rezaei Eshagh Ahmadi 《Journal of Cluster Science》2013,24(4):1181-1191
Copper sulfide nanoparticles have been synthesized from copper salicylate and thioglycolic acid by a hydrothermal method. The obtained product was analyzed by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy and photoluminescence spectroscopy. The effect of reaction time, temperature, solvent and sulfur sources was investigated. 相似文献
90.
Omid Sayar Kheirollah Mehrani Fatemeh Hoseinzadeh Azadeh Mehrani Omid Sadeghi 《Mikrochimica acta》2014,181(3-4):313-320
Graphene nanosheets were modified with amino groups and the resulting material was used as a sorbent for the extraction of cadmium and lead ions. The nanosheets were characterized by IR spectroscopy, transmission electron microscopy, thermal gravimetric analysis and elemental analysis. The effects of sample pH, eluent parameters (type, concentration and volume of eluent), flow rates (of both sample and eluent), and of a variety of other ions on the efficiency of the extraction of Cd(II) and Pb(II) were optimized. Following solid phase extraction, the elements were determined by FAAS. The limits of detection are <0.9 μg L?1 for Pb(II) and <5 ng L?1 for Cd(II). The relative standard deviations are <2.2 %. The method was validated by analyzing several certified reference materials and was then used for Pb(II) and Cd(II) determination in natural waters and vegetables. Figure
In this work, grapheme oxide nanosheets were modified with amino and tri-amino groups and their application were investigated in Cd(II) and Pb(II) determination in food sample. The results show high preconcentration factor and adsorption capacities for these nanosheets. 相似文献