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71.
Gordon L. Olson 《Journal of computational physics》2009,228(8):3072-3083
Using polynomials to represent the angular variation of the radiation intensity is usually referred to as the PN or spherical harmonics method. For infinite order, the representation is an exact solution of the radiation transport solution. For finite N, in some physical situations there are oscillations in the solution that can make the radiation energy density be negative. For small N, the oscillations may be large enough to force the material temperature to numerically have non-physical negative values. The second-order time evolution algorithm presented here allows for more accurate solutions with larger time steps; however, it also can resolve the negativities that first-order time solutions smear out. Therefore, artificial scattering is studied to see how it can be used to decrease the oscillations in low-order solutions and prevent negativities. Small amounts of arbitrary, non-physical scattering can significantly improve the accuracy of the solution to test problems. Flux-limited diffusion solutions can also be improved by including artificial scattering. One- and two-dimensional test results are presented. 相似文献
72.
73.
P. Meunier C. Blancpain F. R. Olson D. M. Hegstedt W. H. Peterson D. W. Bolin A. M. Khalapur A. Fujita T. Ebihara und Fr. Folkmann 《Fresenius' Journal of Analytical Chemistry》1942,124(1-2):68-69
Ohne Zusammenfassung 相似文献
74.
75.
A O Valkirs P F Seligman G J Olson F E Brinckman C L Matthias J M Bellama 《The Analyst》1987,112(1):17-21
76.
Joseph H Bunton Jesse D Olson Daniel R Lenz Thomas F Kelly 《Microscopy and microanalysis》2007,13(6):418-427
The performance of the pulsed-laser atom probe can be limited by both instrument and specimen factors. The experiments described in this article were designed to identify these factors so as to provide direction for further instrument and specimen development. Good agreement between voltage-pulsed and laser-pulsed data is found when the effective pulse fraction is less than 0.2 for pulsed-laser mode. Under the conditions reported in this article, the thermal tails of the peaks in the mass spectra did not show any significant change when produced with either a 10-ps or a 120-fs pulsed-laser source. Mass resolving power generally improves as the laser spot size and laser wavelength are decreased and as the specimen tip radius, specimen taper angle, and thermal diffusivity of the specimen material are increased. However, it is shown that two of the materials used in this study, aluminum and stainless steel, depend on these factors differently. A one-dimensional heat flow model is explored to explain these differences. The model correctly predicts the behavior of the aluminum samples, but breaks down for the stainless steel samples when the tip radius is large. A more accurate three-dimensional model is needed to overcome these discrepancies. 相似文献
77.
Low levels of water (limit of detection 2-5 mg kg1?)can be determined in a non-polar organic solvents such as benzene, 1,2-dichloroethane (DCE) and n-hexane by utilizing the reaction of water with SnCl4 or SbCl5. The reaction results of hydrolysis in halide and is accompanied by a decrease in optical absorption. With SnSl4, the reaction is monitored near 300 nm and with SbCl5 it is monitored at lower wavelengths (350-420). Niether reactons proceeds well in media containing only DCE and n-hexane. For this reason, the arrangemens involves a halide reagent dissolved in benzene which is merged with a benzene/n-hexane/DCE carrier stream into which samlpe is injected. A configuration in which only 2μl of a concentrated halide reagent solution is injected into the flowing sample stream is also shown to be viable for the determination of water in benzene. A membrane-permeation-based calibration method for preparing trace water standards is described. 相似文献
78.
Stephen D. Bond Jehanzeb Hameed Chaudhry Eric C. Cyr Luke N. Olson 《Journal of computational chemistry》2010,31(8):1625-1635
The Poisson‐Boltzmann equation is an important tool in modeling solvent in biomolecular systems. In this article, we focus on numerical approximations to the electrostatic potential expressed in the regularized linear Poisson‐Boltzmann equation. We expose the flux directly through a first‐order system form of the equation. Using this formulation, we propose a system that yields a tractable least‐squares finite element formulation and establish theory to support this approach. The least‐squares finite element approximation naturally provides an a posteriori error estimator and we present numerical evidence in support of the method. The computational results highlight optimality in the case of adaptive mesh refinement for a variety of molecular configurations. In particular, we show promising performance for the Born ion, Fasciculin 1, methanol, and a dipole, which highlights robustness of our approach. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
79.
Experiments using bovine semen reveal that the addition of a high-gain water soluble dye results in random laser action when excited by a Q-switched, frequency doubled, Nd:Yag laser. The data shows that the linewidth collapse of the emission is correlated to the sperm count of the individual samples, potentially making this a rapid, low sample volume approach to count determination. 相似文献
80.
Gordon L. Olson 《Journal of computational physics》2012,231(7):2786-2793
When using polynomial expansions for the angular variables in the radiation transport equation, the usual procedure is to truncate the series by setting all higher order terms to zero. At low order, such simple closures may not give the optimum solution. This work tests alternate closures that scale either the time- or spatial-derivatives in the highest order equation. These scale factors can be chosen such that waves propagate at exactly the speed of light in optically thin media. Alternatively, they may be chosen to significantly improve the accuracy of low-order solutions with no additional computational cost. The same scaling procedure and scale factors work in one- and multi-dimensions. In multidimensions, reducing the order of a solution can save significant amounts of computer time. 相似文献