Ein Elektrodialyse-Elektrophorese-Apparat für präparative kolloidchemische Zwecke

Zusammenfassung Es wird ein Apparat zur elektrodialytischen Reinigung und elektrophoretischen Trennung von Kolloiden beschrieben. Die Reproduzierbarkeit der bei diesem Trennungsverfahren erhaltenen Ergebnisse an fraktioniertem St?rkekleister wird gezeigt.     

The formation of host–guest complexes between surfactants and cyclodextrins

Cyclodextrins are able to act as host molecules in supramolecular chemistry with applications ranging from pharmaceutics to detergency. Among guest molecules surfactants play an important role with both fundamental and practical applications. The formation of cyclodextrin/surfactant host–guest compounds leads to an increase in the critical micelle concentration and in the solubility of surfactants. The possibility of changing the balance between several intermolecular forces, and thus allowing the study of, e.g., dehydration and steric hindrance effects upon association, makes surfactants ideal guest molecules for fundamental studies. Therefore, these systems allow for obtaining a deep insight into the host–guest association mechanism. In this paper, we review the influence on the thermodynamic properties of CD–surfactant association by highlighting the effect of different surfactant architectures (single tail, double-tailed, gemini and bolaform), with special emphasis on cationic surfactants. This is complemented with an assessment of the most common analytical techniques used to follow the association process. The applied methods for computation of the association stoichiometry and stability constants are also reviewed and discussed; this is an important point since there are significant discrepancies and scattered data for similar systems in the literature.     

In situ Wilhelmy balance surface energy determination of poly(3-hexylthiophene) and poly(3,4-ethylenedioxythiophene) during electrochemical doping-dedoping

Changes in the contact angle between conjugated polymers surface poly(3-hexylthiophene) [P3HT] and poly(3,4-ethylenedioxythiophene) (PEDOT) upon electrochemical doping-dedoping in aqueous electrolyte were determined in situ using a Wilhelmy plate tensiometer in an electrochemical cell. The hydrophobic P3HT was less hydrophobic in the oxidized state than in the neutral state; the more hydrophilic PEDOT was less hydrophilic in the oxidized state than when neutral. The tensiometry results were in good agreement with those measured by contact angle goniometry, and further corroborated by the capillary rise upon doping in a fluid cell with two parallel polymer coated plates, another in situ dynamic determination method. The contact angle changes depend on doping potential, electrolyte type, and concentration. We also deconvoluted the surface energy into components of van der Waals and acid-base interactions, using three probe liquids on the polymer surfaces, ex situ the electrochemical cell. The methods and the obtained results are relevant for the science and technology areas of printed electronics and electrochemical devices and for the understanding of surface energy modification by electrochemical doping.     

Interactions between gemini surfactants, 12-s-12, and beta-cyclodextrin as investigated by NMR diffusometry and electric conductometry

The interaction between beta-cyclodextrin (CD) and gemini surfactant of the type alkyl-alpha,omega-bis(dodecyldimethylammonium bromide) with different spacer lengths of 2, 8, and 10 carbons has been investigated by means of electric conductivity (EC) and proton self-diffusion NMR at 298 K. The formation of a 2:1 (CD:gemini) complex in a two-step mechanism is observed with the first association constant (K(11)) higher than the second one (K(21)), but both relatively small in comparison with single C(12)-tailed surfactant. The value of the association constants increased with spacer length both for the first and second associated CD, which indicates that the available space on the gemini molecule is important. The magnitudes of the association constant both for the first and second complexation are discussed. The first association constant is small (when compared with the homologous single-chain surfactant) due to hydrophobic interaction between the hydrocarbon tails within the gemini molecule, while the second association constant shows no cooperativity and its magnitude is discussed in terms of steric constrains.     

Refinements of stochastic domination

In a recent paper by two of the authors, the concepts of upwards and downwards -movability were introduced, mainly as a technical tool for studying dynamical percolation of interacting particle systems. In this paper, we further explore these concepts which can be seen as refinements or quantifications of stochastic domination, and we relate them to previously studied concepts such as uniform insertion tolerance and extractability.     

Why standard estimates of electron-phonon coupling in cuprates do not work

The problem of estimating the coupling strength between oxygen-breathing phonons and electrons in cuprates is discussed. Some of these modes are found in experiments to be strongly coupled, in particular at low doping concentrations. Standard tools, like local density approximation, give a too small coupling. Many-body techniques compare instead much better with experiments. This suggests that electronic correlation effects play a crucial role in the estimate of the electron-phonon coupling from first principles.     

Magnetism of Co overlayers and nanostructures on W(0 0 1): A first-principles study

The magnetic properties of Co nanostructures and a Co monolayer on W(0 0 1) have been studied in the framework of density functional theory. Different geometries such as planar and three-dimensional clusters have been considered, with cluster sizes varying between 2 and 13 atoms. The calculations were performed using the real-space linear muffin-tin orbital method (RS-LMTO-ASA). With respect to the stability of the magnetic state, we predict an antiferromagnetic (AFM) structure for the ground state of the planar Co clusters and a ferromagnetic (FM) state for the three-dimensional clusters. For the three-dimensional clusters, one of the AFM arrangements leads to frustration due to the competing FM and AFM exchange interactions between different atoms in the cluster, and gives rise to a non-collinear state with energy close to that of the FM ground state. The relative role of the Co–Co and Co–W exchange interactions is also investigated.     

Discussion of “human life is unlimited-but short” by H Rootzén and D Zholud

The statistical paper human life is short-but unlimited is briefly discussed. The possibilities and limitations of statistical inference concerning very long human life spans are considered. The restricted models of tail distributions that arise from assumption of renormalized convergence of max- or conditional peaks over thresholds-distributions are questioned in the application context of the reviewed paper. The restrictions of natural systems designs on possibilities of extreme life spans, and the potential to adopt modified extreme value models, allowing seasonal variation of death rates, are also pointed out.