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91.
We present new sharp embedding theorems for mixed-norm analytic spaces in pseudoconvex domains with smooth boundary. New related sharp results in minimal bounded homogeneous domains in higher dimension are also provided. Last domains we consider are domains which are direct generalizations of the well-studied so-called bounded symmetric domains in Cn. Our results were known before only in the very particular case of domains of such type in the unit ball. As in the unit ball case, all our proofs are heavily based on nice properties of the r-lattice. Some results of this paper can be also obtained in some unbounded domains, namely tubular domains over symmetric cones. 相似文献
92.
Evgenija A. Djurendi? Marina P. Savi? Olivera R. Klisuri? Marija N. Saka? Gordana M. Bogdanovi? Dimitar S. Jakimov Katarina M. Penov Ga?i 《Structural chemistry》2012,23(6):1761-1767
A series of d-homo lactones 4?C10 from dehydroepiandrosterone 1 via 16-hydroximino derivatives 2 and 3 were synthesized. The d-homo lactone 4 was transformed by the Oppenauer oxidation to obtain compound 5. The (Z)-2-hydroxymethylene-4-en-3-one compound 6, was obtained through reaction of 4-en-3-one compound 5 with ethyl formate and sodium hydride. The epoxides 8 and 9 were prepared from compound 7 by oxidation with m-chloroperbenzoic acid. Compound 10 was obtained by treating epoxides 8 and 9 with chromium(VI)-oxide. The structure of compounds 6 and 10 were confirmed by X-ray structural analysis. These derivatives were screened for antitumor activity against three tumor cell lines (human breast adenocarcinoma ER+, MCF-7, human breast adenocarcinoma ER?, MDA-MB-231, prostate cancer AR?, PC-3), and one human non-tumor cell line, MRC-5. Compounds 4, 7, 8, and 10 exhibited significant antitumor activity against MDA-MB-231 cells, while compound 5 showed strong cytotoxicity against MDA-MB-231. No compounds displayed toxicity against MRC-5 cells. 相似文献
93.
Markovic BD Vladimirov SM Cudina OA Odovic JV Karljikovic-Rajic KD 《Molecules (Basel, Switzerland)》2012,17(1):480-491
The permeation properties of twenty newly synthesized α-alkoxyalkanoyl and α-aryloxyalkanoyl C-21 esters of standard corticosteroids: Fluocinolone acetonide, dexamethasone, triamcinolone acetonide and hydrocortisone were established using a PAMPA assay (70% silicone oil and 30% isopropyl myristate). The data were compared with parent corticosteroids with addition of mometasone furoate and hydrocortisone acetate. All newly synthesized corticosteroid C-21 esters have effective permeability coefficients higher then -6, mostly followed with high values of retention factors and low permeation. The examined compounds were grouped through relationship between obtained retention factors and permeation parameters (groups I-III). The classification confirmed group I (membrane retentions as well as permeation lower then 30%) for all corticosteroid standards except mometasone furoate, a potent topical corticosteroid which, with high membrane retention (81%) and low permeation (7.7%) fits into group III. The largest number of new synthesized corticosteroids C-21 esters, among them all fluocinolone acetonide C-21 esters, have high membrane retentions (32.4%-86.5%) and low permeations (1.3%-27.1%), fitting in group III. The classification was related to previously obtained anti-inflammatory activity data for the fluocinolone acetonide C-21 esters series. According to the PAMPA results the new synthesized esters could be considered as potential new prodrugs with useful benefit/risk ratio. 相似文献
94.
Velicković S Djordjević V Cvetićanin J Djustebek J Veljković M Nesković O 《Rapid communications in mass spectrometry : RCM》2006,20(20):3151-3153
Molecules of Li(n)X (n = 2, 3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C60). The ionization energies obtained for Li(2)Cl, Li(2)Br and Li(2)I molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV, respectively. The first ionization energy of Li(2)Cl is documented, while there are no literature data for the ionization energies of Li(2)Br and Li(2)I. The molecules of Li(3)Cl, Li(3)Br and Li(3)I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of Li(n)X (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. 相似文献
95.
96.
R. Sanmartin R. Olivera E. Domínguez X. Solans M. Font-bardia M. K. Urtiaga 《Crystal Research and Technology》1997,32(7):1015-1020
The X-ray crystal structure of 4-phenyl-5-(2,3,4-trimethoxyphenyl)-isoxole, C18H17NO4, (I) has been determined, revealing an interesting lack of coplanarity for the aromatic rings system. This preferred conformation implies reduction of the conjugation degree, as shown by the C(2)-C(10) and C(3)-C(4) bond-length values. The arrangement of the three methoxy substituents is also examined. 相似文献