The Formation of Thioacylthioketenes by Flash Vacuum Pyrolysis of 1,2-Dithiole Derivatives

Abstract

The formation of thioacylthioketenes has been observed in Flash Vacuum Pyrolysis of various 1,2-dithiole derivatives. In some cases C₃S₂, 1,2-propadiene-1,3-dithione is formed too.     

A treatment of shocks in one-dimensional thermomechanical media

Received March 03, 1999     

On the Material Symmetry of Elastic Rods

This paper presents a treatment of material symmetry for hyperelastic rods. The rod theory of interest is based on a Cosserat (or directed) curve with two director fields, and was developed in a series of works by Green, Naghdi and several of their co-workers. The treatment is based on Murdoch and Cohen's work on material symmetry of Cosserat surfaces. Two material symmetry groups are discussed: one pertains to the strain-energy function, while the other pertains to the response functions. The paper closes by showing how the treatment relates to the form-invariant approach used in Green and Naghdi's papers and a treatment proposed recently by Cohen. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characterization of rubber particles and rubber chain elongation in <Emphasis Type="Italic">Taraxacum koksaghyz</Emphasis>

Background  

Natural rubber is a biopolymer with exceptional qualities that cannot be completely replaced using synthetic alternatives. Although several key enzymes in the rubber biosynthetic pathway have been isolated, mainly from plants such as Hevea brasiliensis, Ficus spec. and the desert shrub Parthenium argentatum, there have been no in planta functional studies, e.g. by RNA interference, due to the absence of efficient and reproducible protocols for genetic engineering. In contrast, the Russian dandelion Taraxacum koksaghyz, which has long been considered as a potential alternative source of low-cost natural rubber, has a rapid life cycle and can be genetically transformed using a simple and reliable procedure. However, there is very little molecular data available for either the rubber polymer itself or its biosynthesis in T. koksaghyz.