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51.
Lifetime of levels up to 22+, have been measured in 78Kr and an oblate shape is assigned to the ground state using the CSM and the configuration dependent shell correction calculations.
Calculations further show that 78Kr is highly γ-soft nucleus. The experimental Q
t values coupled with theoretical calculations indicate an oblate shape for 78Kr at low spins and triaxial shape at higher spins 相似文献
52.
Ryan KM Erts D Olin H Morris MA Holmes JD 《Journal of the American Chemical Society》2003,125(20):6284-6288
We report a "clean" and fast process, utilizing supercritical carbon dioxide, for producing ultrahigh densities, up to 10(12) nanowires per square centimeter, of ordered germanium nanowires on silicon and quartz substrates. Uniform mesoporous thin films were employed as templates for the nucleation and growth of unidirectional nanowire arrays orientated almost perpendicular to a substrate surface. Additionally, these nanocomposite materials display room-temperature photoluminescence (PL), the energy of which is dependent on the diameter of the encased nanowires. The ability to synthesis ultrahigh-density arrays of semiconducting nanowires on-chip is a key step in future "bottom-up" fabrication of multilayered device architectures for nanoelectronic and optoelectronic devices. 相似文献
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Adsorption properties of a fast iminodiacetate-agarose adsorbent, IDA-Novarose, with a capacity of 120-140 mumol/ml were studied for preconcentration of eight transition elements. A FIA-ICP-AES system was used in the study. It was shown that 0.3 ml of the adsorbent, packed in a column, can quantitatively accumulate Cr(3+), Mn(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), Zn(2+) and Cd(2+) from standard solutions in the pH range between 4 and 8 at high loading flow rates (10-80 ml/min). The rate of adsorption was studied in batch experiments and found to be fast and equal for the divalent metal ions but relatively slow for accumulation of Cr(3+) and Fe(3+). On-line buffering of acidified samples improved the accumulation of metal ions from synthetic samples spiked with humic acid. Quantitative uptakes were observed for most of the studied metals. The accumulation of Cr(3+) was found to be quite sensitive to the ionic strength and some loss of inert complexes of Fe(3+) was also observed. The method was applied to the analysis of certified riverine water (SLRS-3), a tap water and a lake water. With few exceptions the results obtained by ICP-AES after preconcentration agreed well with the certified concentrations and results found by ICP-MS. 相似文献
56.
Stable isotope methods are potentially quite useful for validating natural or enhanced mineral degradation of contaminants. For this reason, a continuous flow gas chromatograph (GC), isotope ratio mass spectrometer (IRMS) has been coupled with a quadrupole mass selective detector (MSD) to allow simultaneous mass spectral and stable carbon isotope ratio data to be obtained from a single chromatographic analysis. This allows the target contaminant and any extra-cellular degradation intermediates to be both qualified and quantified. Previously acceptable limits of precision (0.3 parts per mil) are undesirable given the small fractionation observed during aerobic degradation. To further understand the fate of organic contaminants and to gain information about the metabolic degradative pathway employed by a microorganism, routine isotopic analyses on a range of analytes have been performed. Quantities of sample producing mass-44 ion beam signal (I(44)) of 2 x 10(-10) to 1 x 10(-8) A were analysed. When the IRMS was tuned for high sensitivity, ion source nonlinearities were overcome by peak height correction from an algorithm that was produced using known isotopic standards of varying concentrations. This led to sample accuracy of <0.01 per thousand and sample precision of 0.1 per thousand. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
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KM Clauwaert Van Bocxlaer JF HJ Major JA Claereboudt WE Lambert Van den Eeckhout EM Van Peteghem CH De Leenheer AP 《Rapid communications in mass spectrometry : RCM》1999,13(14):1540-1545
This paper describes the investigation of the potential of a quadrupole orthogonal acceleration time-of-flight mass spectrometer (Q-TOF) equipped with an atmospheric pressure ionisation interface for quantitative measurements of small molecules separated by reversed phase liquid chromatography. To this end, the detection limits and linear dynamic range in particular were studied in an LC/MS/MS experiment using 3,4-methylenedioxymethamphetamine standards and 3,4-methylenedioxyethylamphetamine for internal standardisation. In a second phase, the experiment was repeated with real biological extracts (whole blood, serum, and vitreous humour). A calibration for 3,4-methylenedioxymethamphetamine and its metabolite 3,4-methylenedioxyamphetamine was prepared in each of these matrices again using 3,4-methylenedioxyethylamphetamine as internal standard. The resulting quantitative data were compared with those obtained by liquid chromatography with fluorescence detection for the same extracts. The Q-TOF results revealed excellent sensitivity and a linear dynamic range of nearly four decades (2-10 000 pg on-column, r(2) = 0.9998, 1/x weighting). Furthermore, all the calibration curves prepared in biological material were superimposable, LC/MS/MS and LC-fluorescence, and the quantitative results for actual samples compared very favourably. It was concluded that the Q-TOF achieves a linear dynamic range for quantitative LC/MS/MS work exceeding that of fluorescence detection and at much better absolute sensitivity. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
58.
D. Erts A. L?hmus R. L?hmus H. Olin 《Applied Physics A: Materials Science & Processing》2001,72(7):S71-S74
A scanning tunneling microscope (STM) combined with a transmission electron microscope (TEM) is a powerful tool for direct investigation of structures, electronic properties, and interactions at the atomic scale. Here, we report on two different designs of such TEM-STM as well as an extension with an atomic force microscope (TEM-AFM). In the first TEM-STM design, a stepper motor, combined with a one-dimensional inertial slider, was used to perform the coarse approach. The advantage of this design was the strong pulling force that enabled notched metallic wires to be broken inside the TEM, which lead to clean sample surfaces. A second design, with a three-dimensional inertial slider, allowed lateral motion inside the TEM, which simplified the adjustment of tip location on the sample. By replacing the STM tip with a standard AFM-cantilever chip, a new combination was demonstrated: TEM-AFM. Here the force was simply measured by direct TEM imaging of the motion of the AFM tip. Some experimental results are included to illustrate the capabilities of TEM-STM and TEM-AFM. 相似文献
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Musser JR Bayes R Davydov YI Depommier P Doornbos J Faszer W Gagliardi CA Gaponenko A Gill DR Green P Gumplinger P Hasinoff MD Henderson RS Hu J Jamieson B Kitching P Koetke DD Krushinsky AA Lachin YY Macdonald JA MacDonald RP Marshall GM Mathie EL Miasoedov LV Mischke RE Nord PM Olchanski K Olin A Openshaw R Porcelli TA Poutissou JM Poutissou R Quraan MA Rodning NL Selivanov V Sheffer G Shin B Sobratee F Stanislaus TD Tacik R Torokhov VD Tribble RE Vasiliev MA Wright DH;TWIST Collaboration 《Physical review letters》2005,94(10):101805
The TWIST Collaboration has measured the Michel parameter rho in normal muon decay, mu(+)--> e(+)nu(e)nu (mu). In the standard model, rho = 3/4. Deviations from this value imply mixing of left- and right-handed muon and electron couplings. We find rho=0.750 80+/-0.000 32(stat) +/- 0.000 97(syst) +/- 0.000 23, where the last uncertainty represents the dependence of rho on the Michel parameter eta. This result sets new limits on the W(L)-W(R) mixing angle in left-right symmetric models. 相似文献