全文获取类型
收费全文 | 2579篇 |
免费 | 94篇 |
国内免费 | 13篇 |
专业分类
化学 | 1806篇 |
晶体学 | 23篇 |
力学 | 48篇 |
数学 | 324篇 |
物理学 | 485篇 |
出版年
2024年 | 3篇 |
2023年 | 10篇 |
2022年 | 47篇 |
2021年 | 71篇 |
2020年 | 52篇 |
2019年 | 74篇 |
2018年 | 75篇 |
2017年 | 75篇 |
2016年 | 112篇 |
2015年 | 88篇 |
2014年 | 73篇 |
2013年 | 151篇 |
2012年 | 161篇 |
2011年 | 225篇 |
2010年 | 129篇 |
2009年 | 116篇 |
2008年 | 153篇 |
2007年 | 163篇 |
2006年 | 211篇 |
2005年 | 156篇 |
2004年 | 103篇 |
2003年 | 91篇 |
2002年 | 83篇 |
2001年 | 41篇 |
2000年 | 37篇 |
1999年 | 25篇 |
1998年 | 21篇 |
1997年 | 23篇 |
1996年 | 21篇 |
1995年 | 12篇 |
1994年 | 13篇 |
1993年 | 11篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1972年 | 3篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有2686条查询结果,搜索用时 406 毫秒
161.
Fedor M. Trukhachev Roman E. Boltnev Mikhail M. Vasiliev Oleg F. Petrov 《Molecules (Basel, Switzerland)》2022,27(1)
The nonlinear dust-acoustic instability in the condensed submicron fraction of dust particles in the low-pressure glow discharge at ultra-low temperatures is experimentally and theoretically investigated. The main discharge parameters are estimated on the basisof the dust-acoustic wave analysis. In particular, the temperature and density of ions, as well as the Debye radius, are determined. It is shown that the ion temperature exceeds the temperature of the neutral gas. The drift characteristics of all plasma fractions are estimated. The reasons for the instability excitation are considered. 相似文献
162.
Mikhail V. Vener Andrei V. Churakov Alexander P. Voronin Olga D. Parashchuk Sergei V. Artobolevskii Oleg A. Alatortsev Denis E. Makhrov Alexander G. Medvedev Aleksander Filarowski 《Molecules (Basel, Switzerland)》2022,27(3)
Two new peroxosolvates of drug-like compounds were synthesized and studied by a combination of X-ray crystallographic, Raman spectroscopic methods, and periodic DFT computations. The enthalpies of H-bonds formed by hydrogen peroxide (H2O2) as a donor and an acceptor of protons were compared with the enthalpies of analogous H-bonds formed by water (H2O) in isomorphic (isostructural) hydrates. The enthalpies of H-bonds formed by H2O2 as a proton donor turned out to be higher than the values of the corresponding H-bonds formed by H2O. In the case of H2O2 as a proton acceptor in H-bonds, the ratio appeared reversed. The neutral O∙∙∙H-O/O∙∙∙H-N bonds formed by the lone electron pair of the oxygen atom of water were the strongest H-bonds in the considered crystals. In the paper, it was found out that the low-frequency Raman spectra of isomorphous crystalline hydrate and peroxosolvate of N-(5-Nitro-2-furfurylidene)-1-aminohydantoin are similar. As for the isostructural hydrate and peroxosolvate of the salt of protonated 2-amino-nicotinic acid and maleic acid monoanion, the Raman spectra are different. 相似文献
163.
Alexandr Kh. Plyamovatyi Raviya M. Mukhamadeeva Vasily A. Milyukov Oleg G. Sinyashin Alexandr E. Vandyukov Roald R. Shagidullin Allan G. Ginzburg Vyacheslav I. Sokolov 《Heteroatom Chemistry》1995,6(2):177-181
FT-IR spectroscopy and a special mathematical program were used for the real-time monitoring of the mechanistic path of the reaction of S-ethyl-N,N-tetraethyldiamidothiophosphite with [CpMn(CO)-2NO]+BFequation/tex2gif-stack-3.gif. The formation of a few intermediates is described. 相似文献
164.
165.
Oleg Burdakov Anders Grimvall Oleg Sysoev 《计算数学(英文版)》2006,24(6):771-790
Monotonic regression (MR) is a least distance problem with monotonicity constraints induced by a partiaily ordered data set of observations. In our recent publication [In Ser. Nonconvex Optimization and Its Applications, Springer-Verlag, (2006) 83, pp. 25-33], the Pool-Adjazent-Violators algorithm (PAV) was generalized from completely to partially ordered data sets (posets). The new algorithm, called CPAV, is characterized by the very low computational complexity, which is of second order in the number of observations. It treats the observations in a consecutive order, and it can follow any arbitrarily chosen topological order of the poset of observations. The CPAV algorithm produces a sufficiently accurate solution to the MR problem, but the accuracy depends on the chosen topological order. Here we prove that there exists a topological order for which the resulted CPAV solution is optimal. Furthermore, we present results of extensive numerical experiments, from which we draw conclusions about the most and the least preferable topological orders. 相似文献
166.
Georgiy O. Kachkovskyi Oleg I. Kolodiazhnyi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2238-2242
Two synthetic routes to phosphonic analogues of indoprofen, a nonsteroidal anti-inflammatory drug, were developed by the cyclization of aniline 2 (method A) and by the Arbuzov reaction of corresponding alkylchloride 3 with triethylphosphite (method B). 相似文献
167.
We discuss model-independent constraints on spin observables in exclusive and inclusive reactions, with special attention to the case of photoproduction. 相似文献
168.
169.
170.