首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3581篇
  免费   106篇
  国内免费   16篇
化学   2234篇
晶体学   34篇
力学   75篇
数学   377篇
物理学   983篇
  2023年   12篇
  2022年   61篇
  2021年   88篇
  2020年   77篇
  2019年   97篇
  2018年   108篇
  2017年   104篇
  2016年   140篇
  2015年   102篇
  2014年   101篇
  2013年   182篇
  2012年   194篇
  2011年   266篇
  2010年   165篇
  2009年   154篇
  2008年   200篇
  2007年   218篇
  2006年   258篇
  2005年   182篇
  2004年   136篇
  2003年   117篇
  2002年   108篇
  2001年   66篇
  2000年   60篇
  1999年   43篇
  1998年   27篇
  1997年   31篇
  1996年   38篇
  1995年   21篇
  1994年   23篇
  1993年   21篇
  1992年   12篇
  1991年   11篇
  1990年   14篇
  1989年   10篇
  1986年   9篇
  1984年   11篇
  1983年   13篇
  1982年   13篇
  1981年   10篇
  1979年   17篇
  1978年   15篇
  1975年   9篇
  1974年   19篇
  1973年   12篇
  1972年   15篇
  1971年   23篇
  1970年   10篇
  1969年   11篇
  1968年   10篇
排序方式: 共有3703条查询结果,搜索用时 15 毫秒
21.
This Note deals with the two-dimensional Navier–Stokes system. In this context, we prove a result concerning its global approximate controllability by means of boundary controls. To cite this article: S. Guerrero et al., C. R. Acad. Sci. Paris, Ser. I 343 (2006).  相似文献   
22.
The work is devoted to the analysis of the surface photometric observations of two total lunar eclipses in 2004. The lunar surface relative brightness distribution inside the umbra was used to retrieve the vertical distribution of aerosol extinction of the solar radiation expanding by a tangent path and its dependence on the location at the limb of the Earth. The upper altitude of troposphere aerosol layer was estimated for different latitude zones. The correlation between additional aerosol extinction in the upper troposphere and cyclones was investigated.  相似文献   
23.
We study the spectral properties of Jacobi matrices. By combining Killip's technique [12] with the technique of Killip and Simon [13] we obtain a result relating the properties of the elements of Jacobi matrices and the corresponding spectral measures. This theorem is a natural extension of a recent result of Laptev-Naboko-Safronov [17]. The author thanks Sergei Naboko for useful discussions and Barry Simon for pointing out the conjecture.  相似文献   
24.
The reactions of bis(trimethylstannyl)ethyne, Me3Sn–C?C–SnMe3 ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by 29Si and 119Sn NMR, and the products were characterized by an extensive NMR data set (1H, 11B, 13C, 29Si, 119Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
25.
The macrocyclic title compound crystallizes as a dioxane solvate, C30H22Cl2N4O4·C4H8O2, with two independent formula units in the unit cell. The observed syn conformation is controlled by both intramolecular N—H...O hydrogen bonds and intermolecular C—H...π interactions. The relative macrocyclic inner bore is estimated to be 4.19 Å. In the crystal structure, molecules form dimers via intermolecular C—H...π interactions, and these dimers are, in turn, linked to form columns along the a axis by intermolecular C—H...O hydrogen bonds. Both X‐ray diffraction analysis and density functional theory (DFT) calculations reveal that the macrocycle possesses very high flexibility. This property, as well as the presence of six donor atoms accessible for coordination, makes the title macrocycle a very promising ligand for complexation with the majority of transition metals.  相似文献   
26.
27.
The necessary and sufficient conditions for the decoupling of a quasi-linear system of partial differential equations into k non-interacting subsystems are derived. Several necessary conditions for the decoupling are found and applied to the Benney system.  相似文献   
28.
The frequency dispersion of the magnetic permeability is taken into account in a calculation of the impedance of an amorphous microconductor. Possible methods of measuring the magnetic parameters are analyzed, and the main characteristics of an amorphous microconductor in the microwave range are described. Zh. Tekh. Fiz. 68, 136–137 (January 1998)  相似文献   
29.
A change in the spontaneous polarization and the nonlinear susceptibility in H: LiNbO3 waveguides is calculated from experimental data for the shift of the fundamental absorption for variously polarized rays and from IR reflection data in the range of NbO6 octahedron vibrations. It is shown that taking into account the lattice disorder provides good agreement between the theory and experiment.  相似文献   
30.
The possibility of using time-resolved vibronic spectroscopy for spectral analysis of mixtures of chemical compounds with similar optical properties, when traditional methods (based on stedy-state spectra) are inefficient, is demonstrated by using the method of computer simulation. The analysis is carried out by the example of molecules of a series of polyenes (butadiene, hexadiene, octatetraene, decapentaene, and decatetraene), their various cis-and trans-rotational isomers, and phenyl-substituted polyenes. Ranges of relative concentrations of molecules similar in their spectral properties, where reliable interpretation of time-resolved spectra of mixtures and both qualitative and quantitative analyses are possible, are determined. The use of computer simulation methods for optimizing full-scale experiments in femtosecond spectroscopy is shown to hold much promise.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号