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51.
Ten new α-diazo-β-oxoaldehydes were condensed with aniline, ammonia, hydroxylamine, and semicarbazide to yield new 4-acyl-(1-substituted)-1H-1,2,3-triazoles in moderate-to-good yields. The method is simple and regiospecific. The latter feature makes this method superior to the widely used acylacetylene + azide approach.  相似文献   
52.
Ethyl imidate hydrochlorides 1 were prepared by passing HCl gas through solutions of substituted benzyl cyanides and absolute ethanol. Ethoxycarbonylhydrazones 2 were synthesized from the reaction of compounds 1 with ethyl carbazate. Treatment of 2 with hydrazine hydrate leads to the formation of substituted 4-amino-4,5-dihydro-1H-1,2,4-triazole-5-ones 3. Isatin and 5-chloroisatin were added to 3 to form Schiff bases 4 and N-Mannich bases 5 of these compounds were synthesized by reacting with formaldehyde and piperidine. Their chemical structures were confirmed by means of IR, (1)H- and (13)C-NMR data and by elemental analysis.  相似文献   
53.
54.
We generalize the fundamental theorem for Burnside rings to the mark morphism of plus constructions defined by Boltje. The main observation is the following: If D is a restriction functor for a finite group G, then the mark morphism φ:D+D+ is the same as the norm map of the Tate cohomology sequence (over conjugation algebra for G) after composing with a suitable isomorphism of D+. As a consequence, we obtain an exact sequence of Mackey functors
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55.
Bayes estimation in a mixture inverse Gaussian model   总被引:1,自引:0,他引:1  
In this paper a mixture model involving the inverse Gaussian distribution and its length biased version is studied from a Bayesian view-point. Using proper priors, the Bayes estimates of the parameters of the model are derived and the results are applied on the aircraft data of Proschan (1963,Technometrics,5, 375–383). The posterior distributions of the parameters are expressed in terms of the confluent-hypergeometric function and the modified Bessel function of the third kind. The integral involved in the expression of the estimate of the mean is evaluated by numerical techniques.  相似文献   
56.
We have investigated 1,5‐electrocyclic ring‐closure reactions of conjugated esters with dimethyl diazomalonate in the presence of [Cu(acac)2] as catalyst. Our new protocol offers an easy entry to various polyfunctionalized γ‐lactones in high yields. Their subsequent derivatives may be used as valuable intermediates, especially in the synthesis of natural products and their analogues.  相似文献   
57.
A new, simple, rapid and sensitive separation, preconcentration and speciation procedure for chromium in environmental liquid and solid samples has been established. The present speciation procedure for Cr(III) and Cr(VI) is based on combination of carrier element-free coprecipitation (CEFC) and flame atomic absorption spectrometric (FAAS) determinations. In this method a newly synthesized organic coprecipitant, 5-chloro-3-[4-(trifluoromethoxy) phenylimino]indolin-2-one (CFMEPI), was used without adding any carrier element for coprecipitation of chromium(III). After reduction of chromium(VI) by concentrated H2SO4 and ethanol, the procedure was applied for the determination of total chromium. Chromium(VI) was calculated as the difference between the amount of total chromium and chromium(III). The optimum conditions for coprecipitation and speciation processes were investigated on several commonly tested experimental parameters, such as pH of the solution, amount of coprecipitant, sample volume, etc. No considerable interference was observed from the other investigated anions and cations, which may be found in natural water samples. The preconcentration factor was found to be 40. The detection limit for chromium(III) corresponding to three times the standard deviation of the blank (N = 10) was found 0.7 μg L−1. The present procedure was successfully applied for speciation of chromium in several liquid and solid environmental samples. In order to support the accuracy of the method, the certified reference materials (CRM-TMDW-500 Drinking Water and CRM-SA-C Sandy Soil C) were analyzed, and standard APDC-MIBK liquid-liquid extraction method was performed. The results obtained were in good agreement with the certified values.  相似文献   
58.
2‐Phenyl‐5‐p‐tolyl‐1‐salicylideneamino‐1,3,4‐triazole (PTST) was studied among 2,5‐diaryl‐1‐salicylidene amino‐1,3,4‐triazole derivatives as a novel potential pH indicator. In terms of absorption intensity coming from the acid‐base reactions, PTST showed strong yellow‐green colour with high extinction coefficient in the pH range 7.0–9.5. In addition, the corresponding colour development at the transition point can be attributed to the resonance structures of PTST, which were caused by the hydrogen ion dissociation from the acidic form of the compound in the presence of alkali. The full geometric optimization and achievement of the electronic structure of the molecule were performed by an AM1 semiempirical method. The triazole compound was compared with phenolphthalein (PT), which is widely used as an acid‐base indicator in titrimetry, for accuracy test.  相似文献   
59.
For remanufacturing or recycling companies, a reverse supply chain is of prime importance since it facilitates in recovering parts and materials from end-of-life products. In reverse supply chains, selective separation of desired parts and materials from returned products is achieved by means of disassembly which is a process of systematic separation of an assembly into its components, subassemblies or other groupings. Due to its high productivity and suitability for automation, disassembly line is the most efficient layout for product recovery operations. A disassembly line must be balanced to optimize the use of resources (viz., labor, money and time). In this paper, we consider a sequence-dependent disassembly line balancing problem (SDDLBP) with multiple objectives that requires the assignment of disassembly tasks to a set of ordered disassembly workstations while satisfying the disassembly precedence constraints and optimizing the effectiveness of several measures considering sequence dependent time increments. A hybrid algorithm that combines a genetic algorithm with a variable neighborhood search method (VNSGA) is proposed to solve the SDDLBP. The performance of VNSGA was thoroughly investigated using numerous data instances that have been gathered and adapted from the disassembly and the assembly line balancing literature. Using the data instances, the performance of VNSGA was compared with the best known metaheuristic methods reported in the literature. The tests demonstrated the superiority of the proposed method among all the methods considered.  相似文献   
60.
In this paper, we introduce a new family of multivariate distributions as the scale mixture of the multivariate power exponential distribution introduced by Gómez et al. (Comm. Statist. Theory Methods 27(3) (1998) 589) and the inverse generalized gamma distribution. Since the resulting family includes the multivariate t distribution and the multivariate generalization of the univariate GT distribution introduced by McDonald and Newey (Econometric Theory 18 (11) (1988) 4039) we call this family as the “multivariate generalized t-distributions family”, or MGT for short. We show that this family of distributions belongs to the elliptically contoured distributions family, and investigate the properties. We give the stochastic representation of a random variable distributed as a multivariate generalized t distribution. We give the marginal distribution, the conditional distribution and the distribution of the quadratic forms. We also investigate the other properties, such as, asymmetry, kurtosis and the characteristic function.  相似文献   
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