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21.
Tsukasa Ikeda Ryoichi Kojin Chul-joong Yoon Hiroshi Ikeda Masao Iijima Kenjiro Hattori Fujio Toda 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(3-4):669-674
Cyclodextrin (CD) has a hydrophobic cavity which acts like a binding site of an actual enzyme. But enzymatic turnover reaction did not occur in CD-catalyzed reactions. -CD was modified by a histamine group to attach a reactive functional group. -CD-histamine accelerates the hydrolysis of p-nitrophenyl acetate. Catalytic rate constant of this reaction is close to an actual enzyme, -chymotrypsin. Enzymatic turnover reaction is realized with this compound at around neutral pH value. 相似文献
22.
23.
Morimoto Y Kohyama S Nakai K Matsuo H Karasawa F Kikuchi M 《Photochemistry and photobiology》2003,78(4):372-376
Several studies have shown that UV irradiation may be effective for preventing vascular restenosis or vasopasm. However, the long-term effects of UV light on the physiological properties of vessels such as arterial tension have not been elucidated. We therefore studied the long-term effects of UV using rat carotid arteries treated with UV-B light (wavelength = 313 nm, total energy = 14 mJ/mm2). The animals were sacrificed at 1, 7 and 14 days after UV light exposure, and the carotid arteries were studied by light microscopy and the contractile responses of isolated arterial rings were recorded under isometric tension. UV treatment had induced a substantial loss of smooth muscle cells (SMC) along the entire circumference of the media on days 7 and 14, whereas loss of SMC on day 1 was negligible. Contractile responses of arteries that had been exposed to UV light were significantly reduced on days, 1, 7 and 14. The susceptibility of UV-treated arteries to phenylephrine and prostaglandin F2 alpha was significantly decreased on days 1 and 7, but decreased susceptibility was not seen on day 14. Acetylcholine-induced relaxations were not altered by UV treatment. These results suggest that the long-term effect of UV light is an attenuation of smooth muscle contractility without impairment of endothelial function. 相似文献
24.
Masafumi Yano Yorichika Okino Yuji Ichihara Masakazu Tatsumi Munetaka Oyama Kazunobu Sato Takeji Takui 《Polyhedron》2009,28(9-10):1764-1767
Three highly π-extended tetraaryl-1,3-phenylenediamines for charged high-spin molecular systems were successfully synthesized using Suzuki coupling. Their electrochemical and spectroscopic properties were also examined. They showed blue fluorescence. The dications derived from highly π-extended tetraaryl-1,3-phenylenediamines were generated and characterized by electron transfer stopped-flow method. 相似文献
25.
Ryu Sato Toshiyuki Fujio Shiduko Nakajo Satoshi Ogawa Ashraful Alam 《Tetrahedron letters》2007,48(17):3013-3016
The synthesis of benzopentathiepin having a hydroxyl group at the neighboring position of polysulfur ring was performed by demethylation of 6-ethyl-9-methoxybenzopentathiepin with hydrogenbromide. Benzotrithiole having hydroxyl group was not isolated at all. The hydroxyl group was also alkylated with alkyl iodide in the presence of weak base. 相似文献
26.
Hideo Inaba Fujio Komatsu Akihiko Horibe Naoto Haruki Akito Machida 《Heat and Mass Transfer》2008,44(11):1305-1313
This paper describes heat and mass transfer characteristics of organic sorbent coated on heat transfer surface of a fin-tube
heat exchanger. The experiments in which the moist air was passed into the heat exchanger coated with sorption material were
conducted under various conditions of air flow rate (0.5–1.0 m/s) and the temperature of brine (14–20°C) that was the heat
transfer fluid to cool the air flow in the dehumidifying process. It is found that the sorption rate of vapor is affected
by the air flow rate and the brine temperature. Meanwhile, the attempt of clarifying the sorption mechanism is also conducted.
Finally the average mass transfer coefficient of the organic sorbent coated on heat transfer surface of a fin-tube heat exchanger
is non-dimensionalzed as a function of Reynolds number and non-dimensional temperature, and it is found that the effect of
non-dimensional temperature on them is larger than Reynolds number . 相似文献
27.
Urita K Shiga Y Fujimori T Iiyama T Hattori Y Kanoh H Ohba T Tanaka H Yudasaka M Iijima S Moriguchi I Okino F Endo M Kaneko K 《Journal of the American Chemical Society》2011,133(27):10344-10347
An outstanding compression function for materials preparation exhibited by nanospaces of single-walled carbon nanohorns (SWCNHs) was studied using the B1-to-B2 solid phase transition of KI crystals at 1.9 GPa. High-resolution transmission electron microscopy and synchrotron X-ray diffraction examinations provided evidence that KI nanocrystals doped in the nanotube spaces of SWCNHs at pressures below 0.1 MPa had the super-high-pressure B2 phase structure, which is induced at pressures above 1.9 GPa in bulk KI crystals. This finding of the supercompression function of the carbon nanotubular spaces can lead to the development of a new compression-free route to precious materials whose syntheses require the application of high pressure. 相似文献
28.
Image analysis applied to study on frictional-drag reduction by electrolytic microbubbles in a turbulent channel flow 总被引:1,自引:0,他引:1
We investigate frictional-drag reduction with electrolytic microbubbles based on image measurement of a turbulent flow in
a water channel at Re = 4800 (based on the half channel height). Microbubbles with a diameter ranging 30–200 μm can reduce frictional drag by as
much as 30% relative to single-phase flow even at low void fractions (α ≈ 3 × 10−4); however, drag reduction is only effective within a limited downstream distance from an electrode array. Arrangement of
the optical system allows us to measure the bubble-production rate by water electrolysis from images near the wall and to
trace the motion of bubbles. We also measure velocity fields using particle-tracking velocimetry based on a shallow depth-of-field
approach by segregating tracer particles from microbubbles. Vertically oscillating microbubbles likely represent interaction
with vortical structures near the wall, and bubbles approaching the wall appear to induce negative streamwise velocity relative
to the surrounding fluid. We relate the wall friction with the double integral of the Reynolds-stress profile and show that
its variation due to microbubbles decreases the drag on the wall. Microbubbles tend to coalesce downstream resulting in a
fewer bubbles but with greater size; accordingly, the oscillatory motion diminishes, and the frictional drag rather increases. 相似文献
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