New phase transition between partially and fully polarized quantum Hall states with charge and spin gaps at nu = 2/3

The average electron spin polarization Rho of a two-dimensional electron gas confined in GaAs/GaAlAs multiple quantum wells was measured by NMR near the fractional quantum Hall state with filling factor nu = 2/3. Above this filling factor (2/3< or = nu < 0.85), a strong depolarization is observed corresponding to two spin flips per additional flux quantum. The most remarkable behavior of the polarization is observed at nu = 2/3, where a quantum phase transition from a partially polarized (Rho approximately 3/4) to a fully polarized (Rho = 1) state can be driven by increasing the ratio between the Zeeman and the Coulomb energy above a critical value eta(c) = Delta(Z)/Delta(C) = 0.0185.     

Intensity of the RQ0 branch in the v9 fundamental of ethane

The intensity of the ^RQ₀ branch of the v₉ fundamental of ethane has been measured to be 0.74±0.09cm^-2atm^-1 at 300°K. Rotational structure of the laboratory spectrum is discussed by means of a comparison with a computed spectrum.     

Studies on multiferroic materials in high magnetic fields

In this article, studies on the magnetoelectric effects of multiferroic materials in high magnetic fields, particularly pulsed magnetic fields, are discussed and results for some representative materials are presented. In the discussions on representative materials, the relationship between the crystallographic symmetry and the linear magnetoelectric effect in Cr₂O₃ is introduced. Then drastic changes in polarization caused by magnetic transitions are discussed through a case study of manganites with a perovskite-type structure. In addition, high field studies on the magnetoelectric effects in BiFeO₃, which is an exceptional multiferroic material, are presented and discussed in the framework of the Landau-Ginzburg theory.     

Reaction of β-Sulfinyl and β-Sulfenyl α,β-Unsaturated Ketones with Diimines; Preparation of 1,2-Dihydro-Pyrimidines

2-Acetonyl or 2-phenacyl-l,2-dihydropyrimidines (5) were obtained by the reaction of β-sulfinyl or β-sulfenyl-α,β-unsaturated ketones (2 or 3) with diimines (1). The formation of 1,2-dihydropyrimidines (5) can be explained in terms of substitution reaction and subsequent Michael addition of amino group of diimines (1).     

Asymmetric aldol reactions between cyclic ketones and benzaldehyde catalyzed by chiral Zn2+ complexes of aminoacyl 1,4,7,10-tetraazacyclododecane: effects of solvent and additives on the stereoselectivities of the aldol products

The direct aldol reaction between cyclic ketones and 4-nitrobenzaldehyde catalyzed by chiral Zn²⁺ complexes of aminoacyl 1,4,7,10-tetraazacyclododecane is reported. The anti-aldol products were mainly formed in cyclohexanone/N-methylpyrrolidone(NMP)/MeOH with good diastereo- and enantioselectivity, while syn-aldol adducts were obtained as major products with good enantioselectivity in cyclohexanone/H₂O and cyclohexanone/NMP/H₂O. The fact that the UV/vis spectra of 2,6-diphenyl-4-(2,4,6-triphenyl-1-pyridinio)phenolate (Reichardt’s dye) were nearly identical in these solvent systems suggests that the switch in the relative configuration of the aldol products is induced by a large excess of H₂O rather than the polarity of the solvent system. Furthermore, the addition of a small amount of TFA improved the enantioselectivity of the syn-aldol adducts produced in cyclohexanone/H₂O with up to 92% ee (anti/syn ratio = 30:70).     

N-Fluoro-(3,5-di-tert-butyl-4-methoxy)benzenesulfonimide (NFBSI): A sterically demanding electrophilic fluorinating reagent for enantioselective fluorination

We disclose here a novel electrophilic fluorinating reagent, N-fluoro-(3,5-di-tert-butyl-4-methoxy)benzenesulfonimide (NFBSI) as a sterically demanding analogue of popular fluorinating reagent, N-fluorobenzenesulfonmide (NFSI). NFBSI improves the enantioselectivity of the products as much as 18% for the cinchona alkaloid-catalyzed enantioselective fluorination of silylenol ether compared to the use of NFSI.