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21.
Tatsuo Iwasa Fumio Tokunaga Tôru Yoshizawa Thomas G. Ebrey 《Photochemistry and photobiology》1980,31(1):83-85
Abstract— Quantum efficiencies for photoconversion of bacteriorhodopsin (trans-bR) to a bathochromic product (batho-bRt ) and its photoreversion in purple membrane at 77 and 9 K were investigated with low temperature spectrophotometry. The kinetics of the photoconversion and its photoreversion cannot be expressed by a single exponential curve. The photoconversions at 77 and 9 K showed the same slope in the early stage. The kinetics of the photoreversions were identical at the two temperatures. These results indicate that the quantum efficiencies for the conversion of trans-bR to batho-bRt or for its photoreversion are identical at the two temperatures.
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bRt due to the trimer structure of the purple membrane. 相似文献
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bR
22.
Numerical calculations of eigenfunctions and the participation ratio P are carried out for a two-dimensional square lattice where the site diagonal and/or off-diagonal matrix elements of a one-electron Hamiltonian are disordered. We show that, for purely off-diagonal disorder, states near the centre of the band will never be localized but states in the wings of the band are localized. We also see that the combined effects of diagonal and off-diagonal disorder yield several interesting results. Moreover, we confirm that, as suggested by Economou and Antoniou, the mobility-edge surface takes a bottle-neck shape in the three-dimensional space defined by energy E, the degree of diagonal randomness Γ and the degree of off-diagonal randomness V1. 相似文献
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24.
Local magnetization and current distribution in (La(1-y)Pr(y))0.7Ca0.3MnO3 (y=0.7) crystals are studied by a magneto-optical (MO) imaging technique. MO images below 120 K visualize inhomogeneous magnetization and conduction paths that manifest the percolative conduction originated from the mesoscopic phase separation into ferromagnetic metals and antiferromagnetic insulators. Application of large amounts of current switches the current distribution from inhomogeneous to homogeneous concomitantly with a steep increase in resistivity. These phenomena are discussed in view of current induced collapse of the phase separation through a local heating. 相似文献
25.
Hayashi T Ueyama K Tokunaga N Yoshida K 《Journal of the American Chemical Society》2003,125(38):11508-11509
As a new type of chiral ligand, a C2-symmetric norbornadiene derivative (1R,4R)-2,5-dibenzylbicyclo[2.2.1]hepta-2,5-diene (1) was prepared and used for the rhodium-catalyzed asymmetric addition of organoboron and -tin reagents to alpha,beta-unsaturated ketones, which gave high yields of the 1,4-addition products with up to 99% enantioselectivity. 相似文献
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27.
K. Asayama Y. Kitaoka G. -Q. Zheng K. Ishida Y. Tokunaga H. Mukuda T. Ohno 《Applied magnetic resonance》2000,19(3-4):305-319
This paper introduces nuclear magnetic resonance works in the strongly correlated super-conductors: heavy-Fermion, high-T C superconductors and Sr2RuO4. The analyses strongly support the spin-fluctuation-mediated superconductivity model in a high-T C superconductor. 相似文献
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29.
Akiyuki Hamasaki Akiko Muto Shingo Haraguchi Xiaohao Liu Takanori Sakakibara Takushi Yokoyama Makoto Tokunaga 《Tetrahedron letters》2011,52(51):6869-6872
A treatment of cobalt oxide supported gold nanoparticles (Au/Co3O4) under syngas atmosphere effectively generated a cobalt carbonyl-like active species in the reaction vessel. The preparation of Au/Co3O4 was quite simple and the in situ generated cobalt species could be used as a stable and easy handling alternative for dicobalt octacarbonyl without bothersome purification prior to use. The reactions, which are sensitive to the purity of the dicobalt octacarbonyl, such as the alkoxycarbonylation of epoxides and the Pauson-Khand reaction, smoothly progressed with Au/Co3O4. 相似文献
30.
Copper-mediated chemoselective trifluoromethylation at the benzylic position by the use of shelf-stable electrophilic trifluoromethylating reagents 3 in good to high yields under mild conditions is described for the first time. The generality of this trifluoromethylation for a wide variety of benzyl bromides facilitates the rapid creation of structural diversity of medicinal candidates in drug discovery. 相似文献