全文获取类型
收费全文 | 701篇 |
免费 | 20篇 |
国内免费 | 1篇 |
专业分类
化学 | 561篇 |
晶体学 | 17篇 |
力学 | 5篇 |
数学 | 23篇 |
物理学 | 116篇 |
出版年
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 11篇 |
2017年 | 6篇 |
2016年 | 11篇 |
2015年 | 8篇 |
2014年 | 18篇 |
2013年 | 26篇 |
2012年 | 49篇 |
2011年 | 40篇 |
2010年 | 29篇 |
2009年 | 27篇 |
2008年 | 53篇 |
2007年 | 41篇 |
2006年 | 47篇 |
2005年 | 25篇 |
2004年 | 37篇 |
2003年 | 31篇 |
2002年 | 22篇 |
2001年 | 13篇 |
2000年 | 13篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 11篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 11篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 14篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1977年 | 12篇 |
1976年 | 4篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1968年 | 5篇 |
1967年 | 3篇 |
排序方式: 共有722条查询结果,搜索用时 0 毫秒
61.
1H NMR chemical shifts of solutions of the following cationic surfactants in D2O were determined as a function of their concentrations: cetyltrimethylammonium chloride, CTACl, a 1 : 1 molar mixture of
CTACl and toluene, cetylpyridinium chloride, CPyCl, cetyldimethylphenylam-monium chloride, CDPhACl, cetyldimethylbenzylammonium
chloride, CDBzACl, cetyldimethyl-2-phenylethylammonium chloride, CDPhEtACl, and cetyldimethyl-3-phenylpropylammonium chloride,
CDPhPrACl. Plots of observed chemical shifts versus [surfactant] are sigmoidal, and were fitted to a model based on the mass-action
law. Satisfactory fitting was obtained for the discrete protons of all surfactants. From these fits, we calculated the equilibrium
constant for micelle formation, K, the critical micelle concentration, CMC and the chemical shifts of the monomer, δmon and the micelle δmic. 1H NMR-based CMC values are in excellent agreement with those which we determined by surface tension measurements of surfactant
solutions in H2O, allowing for the difference in structure between D2O and H2O. Values of K increase as a function of increasing the size of the hydrophilic group, but the free energy of transfer per CH2 group of the phenylalkyl moiety from bulk water to the micellar interface is approximately constant, 1.9±0.1 kJ mol-1. Values of (δmic–δmon) for the surfactant groups at the interface, e.g., CH3–(CH2)15–N+(CH3)2 and within the micellar core, e.g., CH3–(CH2)15–N+ were used to probe the (average) conformation of the phenyl group in the interfacial region. The picture that emerges is
that the aromatic ring is perpendicular to the interface in CDPhACl and is more or less parallel to it in CDBzACl, CDPhEtACl,
and CDPhPrACl.
Received: 23 February 1996 Accepted: 29 August 1996 相似文献
62.
M. Fujiwara T. Okano T. -H. Nakashima A. A. Nakamura G. Sugihara 《Colloid and polymer science》1997,275(5):474-479
For a sodium salt of α-sulfonatomyristic acid methyl ester (14SFNa), one of the α-SFMe series surfactants, critical micellization
concentration (CMC), solubility and degree of counterion binding (β) were determined by means of electrocon-ductivity measurements
at different temperatures (at every 5 °C) ranging from 15 to 50 °C. The phase diagram of 14SFNa in pure water was constructed
from the CMC- and solubility-temperature data, in which the Krafft temperature (critical solution temperature) was found around
0 °C. The changes in the Gibbs energy, ΔG
0
m, enthalpy, ΔH
0
m, and entropy, ΔS
0
m, upon micelle formation as a function of temperature were evaluated taking βvalues into calculation.
Received: 28 August 1996 Accepted: 5 November 1996 相似文献
63.
Fujisawa Kiyoshi Okano Mitsuki Martín-Pastor Manuel López-Sánchez Rubén Elguero José Alkorta Ibon 《Structural chemistry》2021,32(1):215-224
Structural Chemistry - Experimental multinuclear determination of the chemical shifts, especially 15N and 109Ag, of five silver(I) trinuclear pyrazolate complexes, (PzAg)3, coupled with ZORA... 相似文献
64.
The potassium-selective PVC membrane electrodes based on naphtho-15-crown-5 have rapid, stable and Nernstian response in the range 10-1–10-5 M. The selectivity coefficient for potassium over sodium is 4 × 10-4. 相似文献
65.
An azaanalog of adamantene, 2-azaadamant-1-ene () and 4-azaprotoadamant-3-ene () were generated in the nonstatistical ratio via photolysis of 3-azidonoradamantane (). The highly strained and could not be isolable but were trapped by MeOH. Acidolysis of was also reported, and discussed in comparison with the photolysis. 相似文献
66.
Treatment of several cyclic olefins, β-pinene, allylbenzene, and estragole with palladium(II) salt in acetic acid in the presence of t-butyl hydroperoxide and tellurium(IV) oxide afforded mainly the corresponding allylic acetates. The reaction proceeded catalytically with palladium(II) salt, t-BuOOH working as a reoxidizing agent. 相似文献
67.
68.
Advances in Data Analysis and Classification - 相似文献
69.
Akinori Nishino Yasushi Komori Hideaki Ujino Miki Wadati 《Studies in Applied Mathematics》2002,108(4):399-425
We study the Macdonald polynomials that give eigenstates of some quantum many-body system with long-range interactions. Scalar products of the nonsymmetric Macdonald polynomials are algebraically evaluated through their Rodrigues-type formulas. We present a new proof of Macdonald's inner product identities without recourse to the shift operators; that is, we calculate square norms of the Macdonald polynomials through Weyl-symmetrization of those of the nonsymmetric Macdonald polynomials. 相似文献
70.
Takeshi Okano 《Proceedings of the American Mathematical Society》2002,130(6):1603-1605