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21.
Yan Yin Otoo Yamada Shunsuke Hayashi Kazuhiro Tanaka Hidetoshi Kita Ken‐Ichi Okamoto 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3751-3762
A series of branched/crosslinked sulfonated polyimide (B/C‐SPI) membranes were prepared and evaluated as proton‐conducting ionomers based on the new concept of in situ crosslinking from sulfonated polyimide (SPI) oligomers and triamine monomers. Chemical branching and crosslinking in SPI oligomers with 1,3,5‐tris(4‐aminophenoxy)benzene as a crosslinker gave the polymer membranes very good water stability and mechanical properties under an accelerated aging treatment in water at 130 °C, despite their high ion‐exchange capacity (2.2–2.6 mequiv g?1). The resulting polymer electrolytes displayed high proton conductivities of 0.2–0.3 S cm?1 at 120 °C in water and reasonably high conductivities of 0.02–0.03 S cm?1 at 50% relative humidity. In a single H2/O2 fuel‐cell system at 90 °C, they exhibited high fuel‐cell performances comparable to those of Nafion 112. The B/C‐SPI membranes also displayed good performances in a direct methanol fuel cell with methanol concentrations as high as 50 wt % that were superior to those of Nafion 112. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3751–3762, 2006 相似文献
22.
Yutaka Miura Toshifumi Satoh Atsushi Narumi Osamu Nishizawa Yoshio Okamoto Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(4):1436-1446
The copper‐mediated atom transfer radical polymerization of methyl methacrylate (MMA) in 1,1,1,3,3,3‐hexafluoro‐2‐propanol (HFIP) was studied to simultaneously control the molecular weight and tacticity. The polymerization using tris[2‐(dimethylamino)ethyl]amine (Me6TREN) as a ligand was performed even at ?78°C with a number‐average molecular weight (Mn) of 13,400 and a polydispersity (weight‐average molecular weight/number‐average molecular weight) of 1.31, although the measured Mn's were much higher than the theoretical ones. The addition of copper(II) bromide (CuBr2) apparently affected the early stage of the polymerization; that is, the polymerization could proceed in a controlled manner under the condition of [MMA]0/[methyl α‐bromoisobutyrate]0/[CuBr]0/[CuBr2]0/[Me6TREN]0 = 200/1/1/0.2/1.2 at ?20°C with an MMA/HFIP ratio of 1/4 (v/v). For the field desorption mass spectrum of CuIBr/Me6TREN in HFIP, there were [Cu(Me6TREN)Br]+ and [Cu(Me6TREN)OCH(CF3)2]+, indicating that HFIP should coordinate to the CuI/Me6TREN complex. The syndiotacticity of the obtained poly(methyl methacrylate)s increased with the decreasing polymerization temperature; the racemo content was 84% for ?78°C, 77% for ?30°C, 75% for ?20°C, and 63% for 30°C. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1436–1446, 2006 相似文献
23.
Zhi-Hui Su Munehiro Okamoto Osamu Tominaga Katsumi Akita Noboru Kashiwai Y?ki Imura Tooru Ojika Yoshiyuki Nagahata Syozo Osawa 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2006,82(7):232-250
An approach to deduce the mechanism of stabilization of the hybrid-derived populations in the Ohomopterus ground beetles has been made by comparative studies on the phylogenetic trees of the mitochondrial and nuclear DNA. A phylogenetic tree based on the internal transcribed spacer (ITS) of nuclear ribosomal gene roughly reflects the relations of morphological species group, while mitochondrial NADH dehydrogenase subunit 5 (ND5) gene shows a considerable different topology on the tree; there exist several geographically-linked lineages, most of which consist of more than one species. These results suggest that the replacement of mitochondria has occurred widely in the Ohomopterus species. In most cases, hybridization is unidirectional, i.e., the species A (♂) hybridized with another species B (♀) and not vice versa, with accompanied replacement of mitochondria of A by those of B. The results also suggest that partial or complete occupation of the distribution territory by a hybrid-derived morphological species. The morphological appearance of the resultant hybrid-derivatives are recognized as that of the original species A. Emergence of a morphological new species from a hybrid-derived population has been exemplified. 相似文献
24.
Hirotaka Okamoto Tadashi Inoue Kunihiro Osaki 《Journal of Polymer Science.Polymer Physics》1995,33(3):417-424
The complex Young's modulus, E*(ω), and the complex strain-optical coefficient, O*(ω), which is the ratio of the birefringence to the strain, were measured for polyisoprene (PIP) over a frequency range of 1 ~ 130 Hz and a temperature range of 22 ~ ?100°C. The imaginary part of O*, O″, was positive at low frequencies and negative at high frequencies. The real part, O′, was always positive and showed a maximum. The complicated behavior of O* could be understood by the assumption that E* = ER* + EG* and O* = CRER* + CGEG*, where ER* and EG* were complex quantities and CR and CG were constants. The CR value, equal to the ordinary stress-optical coefficient measured in the rubbery plateau zone, was 2.0 × 10?9 Pa?1. The CG value, defined as the ratio O″/E″ in the glassy zone, was ?1.1 × 10?11 Pa?1. The EG*, which was the major component of E* in the glassy zone, showed almost the same frequency dependence as that of polystyrene and polycarbonate. The ER*, which was dominant in the rubbery zone, was described well by the bead-spring theory. The temperature dependence of the EG* was stronger than that of the ER*. This difference caused the breakdown of the thermorheological simplicity for E* and O* around the glass-to-rubber transition zone. © 1995 John Wiley & Sons, Inc. 相似文献
25.
26.
Imamura K Mimura T Okamoto M Sakiyama T Nakanishi K 《Journal of colloid and interface science》2000,229(1):237-246
The adsorption behavior of various amino acids on a stainless steel surface was investigated at 30 degrees C and over a pH range of 3-10. Acidic and basic amino acids except histidine adsorbed remarkably at pH 3-4 and 7-10, respectively, and showed Langmuir-type adsorption isotherms. The effects of pH and ionic strength on the adsorption isotherms were investigated to analyze the interactions between amino acids and adsorption sites on the stainless steel. Hydrophobic amino acids and glycine showed only small adsorbed amounts at all pHs tested. For the acidic and basic amino acids, reversibility of the absorption and the influence of the ionic strength on the adsorption behavior were examined. The adsorption isotherms of the derivatives of aspartic acid were also measured in order to examine the contribution of the carboxylic groups of acidic amino acids to the adsorption. Furthermore, a Fourier-transform infrared spectroscopic analysis and semiempirical molecular orbital calculation were carried out to analyze the ionization states and the configuration of the amino acids adsorbed on a stainless steel surface. These investigations suggest that the acidic and basic amino acids adsorb through two electrostatic interactions of two ionized groups in the amino acid with a stainless steel surface. Copyright 2000 Academic Press. 相似文献
27.
Two synthetic approaches to a new indolocarbazole antitumor antibiotic, rebeccamycin, were developed. The absolute configuration of rebeccamycin was determined by a total synthesis. 相似文献
28.
Nishida H Miyazaki Y Kitamura Y Ohashi M Matsusue T Okamoto A Hosaka Y Ohnishi S Mochizuki H 《Chemical & pharmaceutical bulletin》2001,49(10):1237-1244
Intravascular clot formation is an important factor in a number of cardiovascular diseases. Therefore, the prevention of blood coagulation has become a major target for new therapeutic agents. One attractive approach is the inhibition of factor Xa (FXa), which is a key enzyme in coagulation cascade responsible for the generation of thrombin by limited proteolysis of its zymogen, prothrombin. We have investigated 1-arylsulfonyl-3-piperazinone derivatives, containing a 4-(piperidino)pyridine group in place of guanidino and/or amidino groups, and discovered compound M55113 (30a: 4-[(6-Chloro-2-naphthalenyl)sulfonyl]-1-[[1-(4-pyridinyl)-4-piperidinyl]methyl]piperazinone), as a potent inhibitor of FXa (IC50=0.06 microM) with high selectivity for FXa over trypsin and thrombin. 相似文献
29.
Resolution of enantiomers by HPLC on cellulose derivatives 总被引:4,自引:0,他引:4
Summary Various polysaccharide derivatives, particularly cellulose derivatives, were synthesized and used as chiral stationary phases
for optical resolution by HPLC after being adsorbed on macroporous silica gel. Cellulose triacetate (CTA-II), which was synthesized
under homogeneous conditions, showed a chiral recognition ability for many racemates. Other cellulose derivatives such as
cellulose tribenzoate (OB), cellulose-trisphenylcarbamate (OC), cellulose tribenzyl ether (OE), and cellulose tricinnamate
(OK) also showed unique chiral recognition. Among other polysaccharide derivatives, curdlan triacetate was also exhibited
an effective chiral recognition.
Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984 相似文献
30.