An experimental investigation on isoclinic parameters in viscoelastoplastic materials under cyclic stresses

Photovisco-elastoplasticity has been developed and applied to various problems in nonlinear stress analysis as an extension of photoelasticity into nonlinear photomechanics. In photoelasticity, because stress is simply related to strain, isochromatics are proportional to either the principal stress difference or the principal strain difference and isoclinics indicate the directions of either principal stresses or principal strains separately. However, in photovisco-elastoplasticity, these optical responses are nonlinearly related to both stress and strain state simultaneously. Thus isochromatics are related nonlinearly with both the principal stress and strain differences. Isoclinics depend on the direction of principal strain as well as that of principal stress. Concerning now isoclinic parameter: according to the results of experiments performed by us for the deformation state where the directions of principal stress and strain do not coincide with one another, it has been found that isoclinic parameter moves gradually from the direction of principal stress to that of principal strain with increasing viscous deformation under constant stress. In the present research, extending our previous investigations, the behavior of isoclinic parameter has been examined experimentally under cyclic stressing, where the direction of principal stress changes alternately. In the course of an experiment, the variation of isoclinic parameter in relation to the number of cycles was measured together with the corresponding strain state on the thin-walled tubular specimen of celluloid softened by heating, subjected to combined loading conditions consisting of constant axial tension and cyclic torsion. The results obtained may be summarized as follows.

1. The cyclic-variation phase of isoclinic parameter lags behind the cyclic-variation phase of the direction of principal stress. The phase difference between these cyclic variations remains constant regardless of the number of cycles.
2. Isoclinic parameter has a value close to the direction of the principal stress within a range of a small number of cycles and decreases with an increase in the number of cycles. However, it does not approach the direction of principal strain but a value between the direction of the principal stress and that of the principal strain, with a certain constant ratio to them.

     

Czochralski-growth of germanium crystals containing high concentrations of oxygen impurities

Oxygen-containing germanium (Ge) single crystals with low density of grown-in dislocations were grown by the Czochralski (CZ) technique from a Ge melt, both with and without a covering by boron oxide (B₂O₃) liquid. Interstitially dissolved oxygen concentrations in the crystals were determined by the absorption peak at 855 cm⁻¹ in the infrared absorption spectra at room temperature. It was found that oxygen concentration in a Ge crystal grown from melt partially or fully covered with B₂O₃ liquid was about 10¹⁶ cm⁻³ and was almost the same as that in a Ge crystal grown without B₂O₃. Oxygen concentration in a Ge crystal was enhanced to be greater than 10¹⁷ cm⁻³ by growing a crystal from a melt fully covered with B₂O₃; with the addition of germanium oxide powder, the maximum oxygen concentration achieved was 5.5×10¹⁷ cm⁻³. The effective segregation coefficients of oxygen in the present Ge crystal growth were roughly estimated to be between 1.0 and 1.4.     

Geometrically necessary dislocation structure organization in FCC bicrystal subjected to cyclic plasticity

Crystal plasticity finite element analysis of cyclic deformation of compatible type FCC bicrystals are performed. The model specimen used in the analysis is a virtual FCC bicrystal with an isotropic elastic property; therefore, the effect of constraint due to elastic incompatibility does not appear. The results of the analysis show the strain-amplitude-dependence of both the organization of the GND structure and the stress–strain behavior. The calculated stress–strain curve with the largest strain amplitude shows additional cyclic hardening. The microscopic mechanisms of the strain-amplitude-dependent organization of the GND structure and additional cyclic hardening behavior are discussed in terms of the activation of secondary slip system(s). Finally, the effects of the elastic anisotropy, the lattice friction stress and the interaction between dislocations are also argued.     

Efficient construction of the hexacyclic ring core of palau'amine: the pKa concept for proceeding with unfavorable equilibrium reactions

Palau''amine has received a great deal of attention as an attractive synthetic target due to its intriguing molecular architecture and significant immunosuppressive activity, and we achieved its total synthesis in 2015. However, the synthesized palau''amine has not been readily applicable to the mechanistic study of immunosuppressive activity, because it requires 45 longest linear steps from a commercially available compound. Here, we report the short-step construction of the ABCDEF hexacyclic ring core of palau''amine. The construction of the CDE tricyclic ring core in a single step is achieved by our pK_a concept for proceeding with unfavorable equilibrium reactions, and a palau''amine analog without the aminomethyl and chloride groups is synthesized in 20 longest linear steps from the same starting material. The palau''amine analog is confirmed to retain the immunosuppressive activity. The present synthetic approach for a palau''amine analog has the potential for use in the development of palau''amine probes for mechanistic elucidation.

A palau''amine analog (2) was synthesized from 2-cyclopentenone in 20 steps. The construction of the CDE tricyclic ring core in a single step is achieved by our pK_a concept for proceeding with the unfavorable equilibrium reactions.