Radiator design for detecting high-energy neutrons with a nuclear track detector

Subsequent to the proposal of a two-layer structured radiator for more efficient detection of high-energy neutrons with a plastic nuclear track detector (PNTD), its availability has been investigated both experimentally and theoretically. An inner deuterized hydrocarbon (CD₂) layer adjacent to PNTD should play the role of both a radiator of deuterons recoiled there and a degrader for energetic protons recoiled in the outer layer of a CH₂ material. It was found that the energy dependence of the efficiency was changed sensitively by the thickness of the CD₂ layer. A best combination of CH₂ and CD₂ thickness was estimated under a condition of a constant total thickness. For example, the sensitivity could be flattened within 20% between about 5 and 70 MeV by using -CD₂ and -CH₂.     

Electromagnetic Properties of Lanthanum Manganese Oxides Doped with Iron

The mechanism of GMR effects in La(Mn_1–x Fe _x )O₃ (x=0, 0.01, 0.03) oxides has been investigated by means of magnetic measurements, resistivity measurements in magnetic field and Mössbauer spectroscopy. For the x=0.01 sample, the GMR behavior is similar to that of the conventional (La, A)MnO₃ (A: divalent cations) oxides. For the x=0.03 sample, even though the temperature dependence of the Mössbauer spectra was similar to that of the x=0.01 sample, the mechanism for the occurrence of the GMR effect seems to be different. The x=0 sample shows a similar behavior to the x=0.03 sample. A thermal stabilization of spin fluctuation is proposed for the x=0 and x=0.03 sample.     

A charge-transfer host system composed of a chiral 1,1′-bi-2-naphthol cluster and benzylviologen

Chiral charge-transfer (CT) complexes composed of a chiral 1,1′-bi-2-naphthol cluster as the electron donor and 1,1′-dibenzyl-4,4′-bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest.     

Effects of low-LET radiations on CR-39 track detector

The effects of Co-60 gamma-rays and about 25-MeV pulsed electrons have been investigated on CR-39 plastic nuclear track detector. The bulk etch rate was measured as a function of the absorbed dose under three different irradiation conditions; gamma-ray exposure in air at the dose rate of 6 kGy/h, that in vacuum and electron shower in air at 126 kGy/h on average. It was found that the bulk etch rate (V) increased nearly exponentially with the dose (D); V=V₀exp(kD), and the characteristic parameter (k) was 35, 9 and 12 MGy⁻¹, respectively. It is considered that a lack of oxygen in damage formation processes could occur momentarily during a short electron pulse, just similarly to the vacuum effect of reduction in track etch rates in outgassed CR-39 plastic.     

Hydrogen bonding of urea-salicylic acid,U·SA

Urea (U) and salicylic acid (SA) crystallize from aqueous solution as a 11 adduct whose structure shows them to be linked via several weak and one strong hydrogen bonds. The ir spectra of the adduct and its deuterated counterpart have been analyzed and the stretching modes of the various hydrogen bonds identified. The¹H and¹³C nmr. spectra are also interpreted to show that discrete adducts of U·SA persist in solution. On heating, U·SA decarboxylates at a much lower temperature than SA itself.     

Stereoselective synthesis of vinylgermanes and their facile transformation into vinyl halides

Whereas iododegermylation of (Z)-1-triethylgermyl-1-dodecene gives (Z)-1-iodo-1-dodecene, bromodegermylation proves to give (E)-1-bromo-1-dodecene. Two general procedures for the preparation of vinylgermanes are also described.