GC-MS测定桔子皮中的挥发性成分

桔子皮经水蒸汽蒸馏,乙醚萃取挥发性成分。通过气－质联用（ＧＣ－ＭＳ）测定,发现桔子皮中含有３８个组分,确定了其中２３个组分的结构。     

Double folding model calculation applied to fusion reactions

The interaction potential between a spherical and a deformed nucleus is calculated within the double-folding model for deformed nuclei.We solve the double folding potential numerically by using the truncated multipole expansion method.The shape,separation and orientation dependence of the interaction potential,fusion cross section and barrier distribution of the system 16O+154Sm are investigated by considering the quadrupole and hexadecapole deformations of 154Sm.It is shown that the height and the position of the barrier depend strongly on the deformation and the orientation angles of the deformed nucleus.These are quite important quantities for heavy-ion fusion reactions,and hence produce great effects on the fusion cross section and barrier distribution.     

Periodic Motion of Atoms Near a Charged Wire

We study the classical motion of an atom in the vicinity of an infinite straight wire which carries an oscillating uniform charge. This system has been proposed as a mechanism for trapping cold neutral atoms. The parameters of the problem are the magnitude Q and frequency of oscillation of the charge, the mass M and polarizability of the atom, and the angular momentum L of the atom about the wire. For 0 and 2MQ ² greater than, but close to, L ², we prove that the atom's radial motion is periodic (with period 2/), and that the atom moves in a helical path around the wire. For 2MQ ² L ² we prove that the atom must either collide with the wire or else escape to infinity in the radial direction.     

Double folding model calculation applied to fusion reactions

The interaction potential between a spherical and a deformed nucleus is calculated within the double-folding model for deformed nuclei. We solve the double folding potential numerically by using the truncated multipole expansion method. The shape, separation and orientation dependence of the interaction potential, fusion cross section and barrier distribution of the system ¹⁶O+¹⁵⁴Sm are investigated by considering the quadrupole and hexadecapole deformations of ¹⁵⁴Sm. It is shown that the height and the position of the barrier depend strongly on the deformation and the orientation angles of the deformed nucleus. These are quite important quantities for heavy-ion fusion reactions, and hence produce great effects on the fusion cross section and barrier distribution.     

双时间步方法的应用分析

对双时间步方法隐式迭代的稳定性、启动问题、子迭代初值和收敛性准则进行分析.一般认为,双时间步的真实时间步长是基于精度,而不是稳定性的基础上给定,因此真实时间步长可以取得很大,但对VonNeumann稳定性分析表明,对于子迭代采用隐式的算法,稳定性的要求对真实时间步有限制.并通过对Sod激波管问题的计算,验证该分析.     

多次改变聚焦强度法测量束流发射度

就“多次改变聚焦强度法测量束流发射度”,讨论了测量技术和测量装置的优化,包括薄透镜近似的合理采用,多点最小二乘拟合,截面测量靶轴向位置的优化选择,和测量软件系统的改进等,以提高发射度测量的准确性和可靠性.已将上述优化技术,应用于BEPC直线加速器上新建和改建的发射度测量装置,获得了满意的测量结果     

中药掺伪的二维相关红外光谱法分析

旨在建立基于二维相关红外光谱(2D IR spectra)的分析技术,以进行中药中是否掺杂化学药物的判别。以减肥药盐酸芬氟拉明(fenfluramine hydrochloride, FH)、盐酸西布曲明(sibutramine hydrochloride, SH)为待检化合物,确定二者同步相关谱中的特征相关峰。首先通过比较掺杂中药与盐酸芬氟拉明的同步谱中特征相关峰的相似性,初步对掺杂化合物盐酸芬氟拉明进行判定,而后利用掺杂中药异步谱能确认相关峰来源的特性,进一步确证盐酸芬氟拉明的存在;此外,根据掺杂中药同步谱中未出现与盐酸西布曲明同步谱相似的特征相关峰,可以直接判别其中未掺杂盐酸西布曲明。实验所建立的方法无需样品分离,速度快,成本低,为快速简便地进行复杂体系中是否存在化学药物的判别提供了一种新的可能的方法。     

测定树木中总氮和总磷的新方法

本文采用过硫酸盐氧化树样中的总氮为硝态氮、总磷为磷酸盐,用分光光度法测定总氮量和总磷量,测得结果表明,本法所得精密度和准确度是比较好的,本方法能批量处理样品;省时、省电、省试剂、环境污染少。本法适用于树木中总氮总磷的测量。     

Theoretical study of the CH3 + NS and related reactions: mechanism of HCN formation

More than thirty equilibrium and transition structures on the [CH₃NS] potential energy surface have been located using the B3LYP/6-311 + + G(d,p) method. Thioformaldoxime (3) turns out to be the most stable isomer followed by thionitrone (2), a three-membered ring, thionitrosyl methane (1) and thiazyl methane. These isomers are connected to each other by 1,2H and 1,3H shifts and ring—chain rearrangement, but the associated energy barriers are rather high, making most of them stable with respect to unimolecular transformations. Starting from CH₃ + NS, a possible initial atmospheric reaction, HCN formation appears to be the most favoured process through a cascade involvement of 1, 2 and 3. The standard heats of formation, ΔH ⁰ _f,298 are calculated to be: 3, 149kJmol^?1; and 1, 218kJmol^?1; using the CCSD(T)/6-311+ +G(3df,2p) method, with an error of ±10kJ mol^?1.     

数学建模教学模式的研究与实践

探讨工科数学教学中数学建模课的多个层次和开设数学建模课的几种方式 ,并且介绍我们的一些具体做法