Analysis of 17β-Estadiol from Sewage in Coastal Marine Environment by Surface Plasmon Resonance Technique

In this study, surface plasmon resonance(SPR) for monitoring 17β-eatradiol( E2 ) was developed. The small molecule E2 was immobilized on a CM5 sensor chip for an indirect competitive immunoassay to detect F2. The SPR response based on the antigen-antibody reaction was measured by injecting the sample solution into the flow system.The limitation of detection was 0.445 μg/L. The developed SPE-SPR system was applied to analyze the seawater samples. Recovery of E2 was 91.6%-93.1%. Relative standard deviations(RSD) for the E2 assay were between 10.9%-15.1% ( n = 3). The range of determination of E2 samples from the sewage in the coastal marine environment was between ND(lower than detection limit) and ca. 11.78 ng/L.     

黄瓜(Cucumis sativus L.)子叶发育过程中谷氨酰胺合成酶同工酶的变化

采用Native-PAGE和活性染色的方法检测黄瓜种子萌发和子叶发育过程中GS同工酶的类型和活性，以期了解同工酶在子叶发育过程中的作用，在下种子中，只观察到一种不同于GS1和GS2形式的同工酶随着发育过程迅速消失，在种子萌发和子叶发育过程中，子叶GS1活性先于GS2出现，而且两者活性均很快升高；子叶绿化后GS2是主要的，外源氮素能硅著增强它的活性；子叶发育后期这两种同工酶活性逐步下降，在真叶发育中，同样观察到两种GS同工酶，以GS2为主．在暗转光后，GS2明显被诱导；而当光／暗转换后，GS1活性在子叶和真叶中均显著增加．GS同工酶活性随发育以及环境条件的变化而改变的现象与它们在代谢上的功能需要是一致的。     

Synthesis,Crystal Structure and Fungicidal Activity of （E）-2-[（4-tert-Butyl-5-（4-methoxybenzyl）thlazol-2 yhmino）methyl]phenol

The title compound （E）-2-[（4-tert-butyl-5-（4-methoxybenzyl）thiazol-2-ylimino）methyl]phenol was synthesized by the reaction of 5-（4-methoxybenzyl）-4-tert- butylthiazol-2-amine with salicylaldehyde, and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21/c with a = 5.9362（8）, b = 11.5070（15）, c = 29.460（4）A, β= 97.326（3）°, V = 1995.9（5） A^3, Z = 4, F（000） = 808, C22H24N2O2S, Mr= 380.49, De= 1.266 g/cm^3, S = 1.031,μ = 0.181 mm^-1, the final R = 0.0474 and wR = 0.1441 for 4327 observed reflections （I 〉 2σ（I））. Intramolecular O-H…N hydrogen bond is observed in the crystal. The preliminary bioassay showed that the title compound exhibits 95% inhibition rate against Rhizoctonia solani at the test concentration of 500 mg/L.     

矩阵奇异值分解理论在中文文本分类中的应用

用改进的截断与转换的矩阵奇异值分解算法,设计实现了基于字频特征的中文文本分类器.理论分析与实验结果表明,采用的方法提高了数值计算精度,降低了文本集特征空间的维数,简化了文本分类算法的时间复杂度,提高了文本分类准确率.     

小麦花粉植株的诱导及其后代的观察

用补加生长素、加或不加激动索的Ms培养基培养普通小麦(Triticum aestivum)的花药,成功地诱导小麦花粉通过形成愈伤组织发育为完整植株。研究表明:处于单核中期阶段的花粉最适合于诱导形成愈伤组织;补加水解乳蛋白和适当提高蔗糖浓度,对促进花粉形成愈伤组织有一定效果。用不同材料(品种或杂交组合)的花药进行培养,结果有较大差异。杂种花粉植株的种子后代表现整齐一致,没有分离,说明将这种方法用于育种是有希望的。     

小麦花药诱导单倍体植株的减数分裂分析

本文研究了由花药诱导的72株小麦单倍体的减数分裂过程。阐述了减数分裂各期染色体的行为,特别是二价体和单价体在中期Ⅰ和中期Ⅱ的分布。根据单倍体花粉母细胞减数分裂染色体行为的特点,讨论了同源染色体间的交换、染色体向赤道面排列的机制和次级联会的原因等问题。     

亚毫微秒脉宽激光等离子体研究

本文阐述了亚毫微秒脉宽激光加热与压缩等离子体的研究结果,并初步探索了激光等离子体非线性相互作用与爆炸-推进型压缩。     

向列相液晶中光学相位共轭技术的研究进展

对向列相液晶中光学相位共轭技术的研究进展进行了介绍,分析总结了向列相液晶中光学相位共轭过程的机理与实验方法,并对向列相液晶中的光学相位共轭技术的应用前景进行了展望。     

新型含苯并磷杂环戊二烯结构荧光分子的合成及性能

以三苯胺、咔唑为电子给体, 苯并磷杂环戊二烯氧化物为电子受体, 设计合成了一类新颖的D-A-D 型荧光分子, 其结构经¹H NMR, ¹³C NMR, ³¹P NMR, IR和MS确认。通过紫外可见吸收光谱和荧光光谱系统研究了不同给体和受体单元对荧光分子的紫外吸收、液体荧光、固体荧光、溶致变色及聚集诱导发光等光物理性能的影响。结果表明：合成的三种分子具有良好的液体和固体荧光性能;化合物TBN-EPIO具有显著的溶致变色效应, 在四氢呋喃-水二元溶剂体系中, 具有聚集诱导发光(AIE)效应。此外, 利用密度泛函理论计算了分子的几何构型及前线分子轨道电子云。      

Biharmonic Maps from Tori into a 2-Sphere

Biharmonic maps are generalizations of harmonic maps. A well-known result on harmonic maps between surfaces shows that there exists no harmonic map from a torus into a sphere(whatever the metrics chosen) in the homotopy class of maps of Brower degree±1. It would be interesting to know if there exists any biharmonic map in that homotopy class of maps. The authors obtain some classifications on biharmonic maps from a torus into a sphere, where the torus is provided with a flat or a class of non-flat metrics whilst the sphere is provided with the standard metric. The results in this paper show that there exists no proper biharmonic maps of degree±1 in a large family of maps from a torus into a sphere.