Transformations of cobalt trimethylacetate complexes with pyrazole upon oxidation by air in THF

Synthetic routes to oxidation of cobalt atoms in cobalt trimethylacetate complexes containing coordinated pyrazole molecules have been considered.     

Periodic solutions of second-order quasilinear hyperbolic equations

We study a periodic boundary-value problem for a quasilinear equation with the d'Alembert operator on the left-hand side and a nonlinear operator on the right-hand side and establish conditions under which the solution of the indicated problem is unique.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 47, No. 10, pp. 1370–1375, October, 1995.     

Application of the variation principle for the problem of buckling of a nonlinearly elastic ring nonuniform along its thickness

There has been considerable recent attention given to the stressed and buckled states of items with complicated configuration made of different nonlinearly elastic materials joined by complete adhesion. However, effective analytical solutions for such problems have been hindered by mathematical difficulties. Approximate methods have thus been developed for such problems. A variational combined principle has been formulated in this communication. A nonlinear geometrical approach has been used for formulating a mixed-type functional with physical relationships given by Euler equations, nonlinear equilibrium equations, and nonlinear boundary conditions for a piecewise-nonuniform nonlinearly elastic body composed of finite elements (particles). As an example, buckling along the nonuniform thickness of nonlinearly elastic rings was analyzed hypothetically assuming plane cross-sections. Options for two-, three-, four-, five-, and six-layered rings in a periodical structure have been reviewed. The critical buckling forces for an even number of layers have been found to be equal to each other. The ratios of the critical forces, elasticity moduli, and proportionality levels were determined for all five variants by the Runge-Kutta method.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October, 1995).Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 2, pp. 262–268, March–April, 1995.     

On the mechanism of phenol ozonolysis

The mechanisms of liquid-phase phenol ozonation are revised. A new mechanism in which a significant role is played by free-radical reactions is suggested for this process.     

Band structures in73Se

Excited states of⁷³Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the⁷⁰Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2⁺ band is likely to correspond to an oblate deformation while the 5/2⁺ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2⁺. The 3/2^? band is a strongly coupled band built on the [301] 3/2^} configuration.Nuclear reactions:⁷⁰Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE _γ,I _γ,σ(E _γ,θ),γγ-coin, linear polarization, DSA,γ(t).⁷⁵Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors.     

Charm production in two-photon collisions: Calculation of the leading nonperturbative contribution in QCD

The leading nonperturbative contribution to the cross section of charm production in two-photon collisions is calculated in QCD. Operator expansion is used and the c-quark interaction with vacuum gluon condensate is taken into account. As a result, the moments of the charm contribution to the photon structure function are obtained. The moments with sufficiently high numbers turn out to be sensitive to the gluon condensate.     

Structural analysis of the non-dialysable urinary glucoconjugates of normal men.

Enzymic methods were employed to analyse the structure of the non-dialysable urinary glucoconjugates of ten healthy males. The excretion of the urinary glucoconjugates was determined from the glucosyl:galactosyl ratio after acid hydrolysis, and a mean value of 0.27 was obtained. The results of the specific actions of alpha- and beta-glucosidases showed that the non-dialysable urinary glucoconjugates contain a branched alpha-glucan fraction with 1,4- and 1,6-glucosidic bonds, and a beta-glucan fraction containing 1,4-glucosidic bonds.     

Copper-D-penicillamine complex as potential contrast agent for MRI.

In vitro and in vivo proton T1 data are reported that demonstrate that the paramagnetic copper-D-penicillamine complex can be applied as a potential contrast agent to magnetic resonance imaging.