全文获取类型
收费全文 | 1326613篇 |
免费 | 25772篇 |
国内免费 | 7768篇 |
专业分类
化学 | 655389篇 |
晶体学 | 20539篇 |
力学 | 74777篇 |
综合类 | 108篇 |
数学 | 241116篇 |
物理学 | 368224篇 |
出版年
2021年 | 13500篇 |
2020年 | 15908篇 |
2019年 | 16025篇 |
2018年 | 13667篇 |
2016年 | 28205篇 |
2015年 | 20872篇 |
2014年 | 30358篇 |
2013年 | 74198篇 |
2012年 | 37001篇 |
2011年 | 33837篇 |
2010年 | 37438篇 |
2009年 | 40029篇 |
2008年 | 33425篇 |
2007年 | 29149篇 |
2006年 | 33969篇 |
2005年 | 27647篇 |
2004年 | 28639篇 |
2003年 | 27079篇 |
2002年 | 28017篇 |
2001年 | 26534篇 |
2000年 | 23528篇 |
1999年 | 21902篇 |
1998年 | 20792篇 |
1997年 | 20807篇 |
1996年 | 20993篇 |
1995年 | 19099篇 |
1994年 | 18550篇 |
1993年 | 18060篇 |
1992年 | 17830篇 |
1991年 | 18130篇 |
1990年 | 17371篇 |
1989年 | 17435篇 |
1988年 | 17012篇 |
1987年 | 17029篇 |
1986年 | 15927篇 |
1985年 | 22363篇 |
1984年 | 23675篇 |
1983年 | 19891篇 |
1982年 | 21598篇 |
1981年 | 20824篇 |
1980年 | 20179篇 |
1979年 | 20270篇 |
1978年 | 21634篇 |
1977年 | 21228篇 |
1976年 | 20881篇 |
1975年 | 19569篇 |
1974年 | 19220篇 |
1973年 | 19670篇 |
1972年 | 14163篇 |
1967年 | 12422篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
951.
M. V. Veselovskaya S. V. Shilin M. M. Garazd V. P. Khilya 《Chemistry of Natural Compounds》2003,39(2):177-181
Furocoumarins modified by amino acids were prepared by condensation of the N-hydroxysuccinimide ester of 3-(2,3,5-trimethyl-7-oxofuro[3,2-g]chromen-6-yl)propanoic acid with amino acids. 相似文献
952.
B. Saha S. Bhattacharyya T. K. Mukherjee P. K. Mukherjee 《International journal of quantum chemistry》2003,92(5):413-418
In the framework of nonrelativistic variational formalism a new type of basis set is proposed, to estimate separately the effect of radial and angular correlations on the ground‐state energy for helium isoelectronic sequence H? to Ar16+. Effect of radial correlation is incorporated by using multiexponential functions arising from product basis sets suitably formed out of Slater‐type one‐particle orbitals. The angular correlation can be switched on by incorporating an expansion in terms of basis involving interparticle coordinates. With a set of six‐term Slater‐type one‐particle basis and five‐term interparticle expansion, the ground‐state energy of helium is estimated as ?2.9037236 (a.u.) compared with the multiterm variational estimates ?2.9037244 (a.u.) due to Pekeris and Thakkar and Smith and Drake. Matrix elements of different operators in the ground state have been calculated and found to be in good agreement with available accurate results. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2003 相似文献
953.
Ab initio calculations showed that the tetrachlorodibenzo-para-dioxin radical cations (TCDD RCs) with a planar structure have two steady states with asymmetric dioxin cycles. The activation barriers between these states are up to 2 kcal/mole, so that the RCs may be regarded as being structurally nonrigid within the dioxin cycle. The 2,3,7,8-TCDD RC is more stable than the 1,4,6,9-TCDD RC, the energy difference being 5.2 kcal/mole. The adiabatic ionization potential of 2,3,7,8-TCDD (7.54 eV) is 0.1 eV smaller than the corresponding potential of 1,4,6,9-TCDD. These factors account for the increased hemoproteide affinity and hence increased biological activity of 2,3,7,8-TCDD. 相似文献
954.
955.
E.Ann Hallinan Clifford R. DornWilliam M. Moore Gina M. JeromePamela T. Manning Barnett S. Pitzele 《Tetrahedron letters》2003,44(39):7345-7347
Described is a method of introducing trifluoroalkyl groups at C-6 of lysine. This chemistry has the potential to introduce a variety of functionality at C-6 of lysine. 相似文献
956.
Shirin J. Handjani 《Journal of Theoretical Probability》2003,16(2):325-338
We establish conditions for survival and extinction of types of one-dimensional voter models, and show that increasing the flip rates at a finite number of sites typically does not affect survival, unless the flipping mechanism is altered. We provide an example of a modified voter model that does not survive but can be made to survive simply by altering the flip mechanism at one site. We also show that a rather general class of such models have clustering behavior. 相似文献
957.
Grishin D. F. Semyonycheva L. L. Telegina E. V. Smirnov A. S. Nevodchikov V. I. 《Russian Chemical Bulletin》2003,52(2):505-507
Organometallic compounds Cp2TiCl2, (EtC5H4)2NbCl2, and (PriC5H4)2WCl2 were assessed as additives that control polymer chain growth in the polymerization of methyl methacrylate. In the presence of compounds mentioned in amounts comparable with that of the initiator, a uniform process with no gel-effect occured and respective linear increase in the molecular weight of the polymer up to high degrees of the monomer conversion was observed. 相似文献
958.
The Sample Average Approximation Method Applied to Stochastic Routing Problems: A Computational Study 总被引:1,自引:0,他引:1
Bram Verweij Shabbir Ahmed Anton J. Kleywegt George Nemhauser Alexander Shapiro 《Computational Optimization and Applications》2003,24(2-3):289-333
The sample average approximation (SAA) method is an approach for solving stochastic optimization problems by using Monte Carlo simulation. In this technique the expected objective function of the stochastic problem is approximated by a sample average estimate derived from a random sample. The resulting sample average approximating problem is then solved by deterministic optimization techniques. The process is repeated with different samples to obtain candidate solutions along with statistical estimates of their optimality gaps.We present a detailed computational study of the application of the SAA method to solve three classes of stochastic routing problems. These stochastic problems involve an extremely large number of scenarios and first-stage integer variables. For each of the three problem classes, we use decomposition and branch-and-cut to solve the approximating problem within the SAA scheme. Our computational results indicate that the proposed method is successful in solving problems with up to 21694 scenarios to within an estimated 1.0% of optimality. Furthermore, a surprising observation is that the number of optimality cuts required to solve the approximating problem to optimality does not significantly increase with the size of the sample. Therefore, the observed computation times needed to find optimal solutions to the approximating problems grow only linearly with the sample size. As a result, we are able to find provably near-optimal solutions to these difficult stochastic programs using only a moderate amount of computation time. 相似文献
959.
An Application of Branch and Cut to Open Pit Mine Scheduling 总被引:5,自引:0,他引:5
The economic viability of the modern day mine is highly dependent upon careful planning and management. Declining trends in average ore grades, increasing mining costs and environmental considerations will ensure that this situation will remain in the foreseeable future. The operation and management of a large open pit mine having a life of several years is an enormous and complex task. Though a number of optimization techniques have been successfully applied to resolve some important problems, the problem of determining an optimal production schedule over the life of the deposit is still very much unresolved. In this paper we will critically examine the techniques that are being used in the mining industry for production scheduling indicating their limitations. In addition, we present a mixed integer linear programming model for the scheduling problems along with a Branch and Cut solution strategy. Computational results for practical sized problems are discussed. 相似文献
960.