Untersuchung der verdickung von latex-dispersionen durch ethylacrylat-methacrylsäure-copolymere

Zusammenfassung Es wurden dynamische and stationdre Scherversuche durchgeführt, um den Verdickungseinfluß von Copolymeren aus Ethylacrylat and 15, 40 bzw. 65 Gew. % Methacrylsdure auf Latex-Dispersionen aus Ethylacrylat mit 0 bzw. 1 Gew. % Acrylsaure zu untersuchen. Nach Überschreiten eines Schwellwertes der Verdickungsmittelkonzentration, welche mit dem Sauregehalt im Verdickungsmittel und im Latex abnahm, wurde ein starker Anstieg des Speicher-und Verlust-Moduls (G and G) sowie der Fließgrenze und der Thixotropie beobachtet. Gleichzeitig wurde ein Überwiegen der viskosen Eigenschaften sowie eine zunehmende Flockulationsfähigkeit des Verdickungsmittels festgestellt. Bei größerem Säuregehalt im Latex überwogen die elastischen Eigenschaften, gleichzeitig erhöhte sich die Bestandigkeit gegen Flockulation. Die Verdickungswirkung der unterschiedlich zusammengesetzen Systeme wird durch die Ausbildung einer Raumnetzstruktur erklärt. Das Flockulationsverhalten wird auf Änderungen der Ladung und des freien Volumens zurückgeführt.

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The thickening effect of latices of ethylacrylate-methacrylic acid copolymers (15, 40, and 65 wt. % of the acid) on latices of ethylacrylate-acrylic acid copolymers (0 and 1 wt. % of the acid) was studied by using dynamic and steady shear flow measurement. It was found that beyond a certain concentration of the thickener the storage modulus G, the loss modulus G, the yield stress values, and thixotropic behavior rapidly increased. At the same time, viscous properties and the flocculation ability of the thickeners prevailed. On the contrary, an increase in acid content in the latex made the elastic properties and flocculation resistance of the system more pronounced. The thickening effect is explained by the formation of an ordered structure. The flocculation behavior is explained by changes of the electrical charge and the free volume.

Teilweise vorgetragen an der Jahrestagung der Deutschen Rheologischen Gesellschaft, 13.–15. Mai 1991, Berlin.     

Influence of second-order boundary layer effects in hypersonic flow over slender blunt cones

The aim of this study is to determine the influence of second-order effects in the aggregate on supersonic axisymmetric flow over slender blunt cones and also to determine the region of applicability of approximate methods of taking into account the strongest of these second-order effects — entropy layer absorption. A system of complete viscous shock layer equations containing all the terms of the gas dynamic Euler equations and all the second-order terms of asymptotic boundary layer theory is chosen as the gas-dynamic model. Within the calculation domain the problem is solved in a unified manner.Translated from Izvestiya Rossiiskoi Akademii Nauk, Meknanika Zhidkosti i Gaza, No.4, pp. 129–134, July–August, 1992.     

Experimental determination of transverse vibration modes of thin I-shaped plates

The natural frequencies and the corresponding mode shapes of clamped thin I-shaped plates were experimentally determined by time-averaged holographic interferometry. The test plate was shaped as shown in Fig. 1, and eight kinds of plates were tested by taking a dimensionless length parameter ξ as a parameter. The natural-vibration modes exceeding 200 were identified using the real-time method. The corresponding natural frequencies ranged from 172 to 5606 Hz. In addition, in the case of a rectangular plate, the experimental results were shown to be good agreement with the theoretical ones.     

Theory of inverted pendulum with follower force revisited

The effect of the type of springs on the equilibrium states of an inverted pendulum is examined. The angular and linear eccentricities of the follower force are taken into account __________ Translated from Prikladnaya Mekhanika, Vol. 43, No. 6, pp. 126–137, June 2007.     

Bubbly flow undergoing a steep pressure gradient

The effects of a steep pressure gradient on bubbly flow were studied to determine the cause of noise emanating from components of a piping system. We used an orifice to generate a local pressure difference. The behavior of bubbles passing through the orifice was observed by using a video camera, and the noise was measured by a condenser microphone outside the pipe. It was found that the sound pressure level of noise generated by a bubbly flow was proportional to the pressure difference. An empirical formula for estimating noise level is proposed. The changes in size and number of bubbles passing through an orifice were found related to the breakup, which is affected by pressure difference rather than airflow rate. The breakup of a single bubble undergoing a steep pressure difference was observed to determine the mechanism of sound generation. It was found that a bubble was broken by impingement of an inward protrusion in the bubble. The growth rate of the protrusion depended on the pressure difference.     

Bénard-Marangoni instability in a viscoelastic Jeffreys' fluid layer

Coupled buoyancy (Bénard) and thermocapillary (Marangoni) convection in a thin fluid layer of a viscoelastic fluid are studied. The viscoelastic fluid is modeled by Jeffreys' constitutive equation. The lower surface of the layer is in contact with a rigid heat-conducting plate while its upper surface is subject to a temperature-dependent surface tension. The critical temperature difference between both boundaries corresponding to the onset of convection is calculated. The role of the various viscometric coefficients is discussed. In the appendix it is shown that Jeffreys' constitutive relation is easily derived from thermodynamic considerations based on extended irreversible thermodynamics.     

Effective widths of rectangular slabs stiffened along two opposite edges by prestressed edge beams

The present analysis is an attempt to determine the portion of a rectangular slab that is acting with its two parallel stiffening edge beams, through which prestressing loads are applied to the entire section, in resisting load. Employing the well known theories of bending of plates and beams, the constitutive equations governing the behaviour of this type of composite system are presented. In particular, the equation of compatibility of strains between the slab edges and the stiffening edge beams at their junctions is formulated. In doing this, the biaxial nature of the bending of the edge beams, ignored in earlier formulations [1], has been incorporated. The results of the present analysis show that, under transverse loading, the portion of the slab, called the effectiv width, that can be considered effective as a part of each of the stiffening edge beams in determining stresses and deflexions is not significantly different from that obtained for an unprestressed section or a simply reinforced section. The effective width of the slab when such a section is subjected to only prestressing loads however shows a significant difference. We conclude from this that a single table of effective widths could be adopted for design purposes when considering transverse bending of this type of composite system whether the section is prestressed or not. Typical stress distributions due to (i) prestress alone, (ii) transverse loading alone and (ii) combined prestress and transverse loading are presented to demonstrate that the present formulation is versatile enough to solve problems involving prestressed edge beams in this type of composite assembly.     

An extension of the concept of material symmetry

Summary The nature of a material is in large part described by its symmetry group. It is proposed to extend this concept to a more general type of symmetry transformation, and the use of such an extension is illustrated by using it to define several classes of materials and presenting the corresponding representation theorems.

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Sommario La natura di un materiale è in gran parte descritta dal suo gruppo di simmetria. Si propone di estendere questo concetto a un tipo più generale di trasformazione simmetrica, e l'uso di questa estensione è illustrato nel definire parecchie classi di materiali e nel formulare i corrispondenti teoremi di rappresentazione.