Recyclization of 2,3-Disubstituted 5-Arylamino-2,5-dihydro-1,2,4-thiadiazoles and Related Salts into Benzothiazole Derivatives

Russian Journal of General Chemistry -     

Norm Series in High-Dimensional Local Fields

In the present paper, the notion of norm series with respect to the norm residue symbol is generalized to high-dimensional local fields. Necessary and sufficient conditions for the existence of norm series are obtained. Bibliography: 12 titles.__________Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 305, 2003, pp. 60–83.     

Optical limiters and diffraction elements based on a COANP-fullerene system: Nonlinear optical properties and quantum-chemical simulation

The results of optical study and quantum-chemical simulation of a conjugated organic system, 2-cyclooctylamino-5-nitropyridine (COANP)-fullerene, performed to determine its potential for application as a limiter of visible and near-IR laser radiation and as a material for diffraction elements in systems for reversible recording of optical information, are presented. Complexation between a COANP molecule and fullerene is considered as one of the main mechanisms responsible for the corresponding properties of this system. For the first time, nonlinear optical characteristics of COANP-C₆₀ and COANP-C₇₀ systems are comparatively studied and the intermolecular interaction between a COANP molecule and fullerene is analyzed on the quantum-chemical level.     

Approximation Properties AP s and p-Nuclear Operators (the Case 0 < s ≤ 1)

We investigate Banach spaces possessing (or not possessing) the approximation properties AP _s, 0 < s ≤ 1, in connection with the following known question in the geometric theory of operators: under which conditions on Banach spaces X and Y and on positive numbers r and p does the p-nuclearity of the second adjoint of a continuous operator T from X to Y imply the p-nuclearity of T? Actually, we give necessary and sufficient conditions under which this question is answered affirmatively. In addition, the corresponding counterexamples are obtained in the maximally strong form. For instance, it is shown (and this statement is a significant strengthening of the previous results of that sort) that there exists a pair of separable Banach spaces Z and W such that the spaces Z ^** and W have Schauder bases, while for every p, 1 ≤ p < 2, there is a non-p-nuclear operator from W to Z with a p-nuclear second adjoint. Earlier, in similar examples, the corresponding spaces did not possess even the Grothendieck approximation property. The technique developed in this paper does not allow us to treat the case p > 2. That case will be studied in a forthcoming paper of the author. Bibliography: 11 titles.     

Rovibrational analysis of the absorption spectrum of H2O around 1.02 μm by ICLAS-VECSEL

The very weak water vapor absorption spectrum has been investigated between 9520 and 10 010 cm⁻¹ by intracavity laser absorption spectroscopy based on a vertical external cavity surface emitting laser. The rovibrational assignment performed on the basis of the ab initio calculations of Schwenke and Partridge has allowed for determining 156 new energy levels belonging to a total of 13 vibrational states. The assignment process is detailed. The results are compared with the available databases and discussed in regard of recent investigations by Fourier transform spectroscopy.     

Appearance of anomalous phase in <Superscript>4</Superscript>He crystal in the presence of small <Superscript>3</Superscript>He impurity

The kinetics of formation of an anomalous phase from a solution with a small ³He impurity was studied in the temperature range 0.2–0.7 K up to a supersaturation of ～30 mbar. The phase diagram was determined for normal and anomalous growths. It is found that, in the presence of impurities, the formation of a fast-growing state is retarded. This experimental fact indicates that the dissipative processes in fluids have an appreciable effect on the phase formation kinetics. The retardation is, possibly, caused by the direct interaction of an impurity with the crystal surface.     

Recyclization of Products Formed by Addition of 5-Hydrazino-2-phenyl-1,3-oxazoles Functionally Substituted in 4-Position to Aryl Isothiocyanates

Russian Journal of General Chemistry -