Selectively protected galactose derivatives for the synthesis of branched oligosaccharides

Synthesis and characterization of several new anomerically pure galactose derivatives, based on simple and effective protective group manipulations of benzyl β-d-galactopyranoside, are reported. The monosaccharides described contain selectively protected/deprotected hydroxyl functionalities at their 1,2,3,4- and 6-positions rendering them useful as building blocks for construction of branched oligosaccharides.     

Dynamics of moving interacting atoms in a laser radiation field and optical size resonances

The forces acting on interacting moving atoms exposed to resonant laser radiation are calculated. It is shown that the forces acting on the atoms include the radiation pressure forces as well as the external and internal bias forces. The dependences of the forces on the atomic spacing, polarization, and laser radiation frequency are given. It is found that the internal bias force associated with the interaction of atomic dipoles via the reemitted field may play an important role in the dynamics of dense atomic ensembles in a light field. It is shown that optical size resonances appear in the system of interacting atoms at frequencies differing substantially from transition frequencies in the spectrum of atoms. It is noted that optical size resonances as well as the Doppler frequency shift in the spectrum of interacting atoms play a significant role in the processes of laser-radiation-controlled motion of the atoms.     

MgO films grown on yttria-stabilized zirconia by molecular beam epitaxy

MgO films were grown on (0 0 1) yttria-stabilized zirconia (YSZ) substrates by molecular beam epitaxy (MBE). The crystalline structures of these films were investigated using X-ray diffraction and transmission electron microscopy. Growth temperature was varied from 350 to 550 °C, with crystalline quality being improved at higher temperatures. The MgO films had a domain structure: (1 1 1)[1 1 2¯]_MgO(0 0 1)[1 0 0]_YSZ with four twin variants related by a 90° in-plane rotation about the [1 1 1]_MgO axis. The observed epitaxial orientation was compared to previous reports of films grown by pulsed laser deposition and sputtering and explained as resulting in the lowest interface energy.     

ON THE UNIFORM DISSIPATIVITY OF SOME FIFTH-ORDER NON-LINEAR DIFFERENTIAL EQUATIONS

This paper studies the problem of uniformly dissipative solutions of somefifth order non-linear differential equations by the use of frequency domaintechnique. We use the generalized theorem of Yacubovich on dissipativity toobtain some new sufficient conditions of the existence of solutions that aredissipative for (1.1) and (1.2).     

Physical processes underlying the development of shear turbulence

A physical model of the development of turbulence in free shear flows is proposed. The model is based on the results of numerical simulations of turbulent flow development. The main ideas of the proposed theory of turbulence are stated as follows: the onset of turbulence begins with the formation of large vortices; spectral energy transfer involves both direct and inverse cascades; and the inertial range of the energy spectrum develops as a result of concurrent direct and inverse cascades. The dominant physical factors that determine the spectrum include Joukowski forces.