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961.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1341–1342, July, 1994. 相似文献
962.
Sulfonyldiazene-N-oxides2 and3 were obtained by treatment of sulfamide with nitroso compounds1 in the presence of 1,3-dibromoisocyanurate (DBI) in neutral and acid media.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 681–683, April, 1994. 相似文献
963.
964.
Reduced charge montmorillonites (RCM) were prepared by the thermal treatment of lithiumsaturated montmorillonite. Samples prepared by mild thermal treatment with lithium contained more water sorbed than the original montmorrilonite. When RCMs were prepared, part of the lithium cations reacted with hydroxyl groups in the octahedral sheet and released protons, which reacted with the structure. Acid treatment probably enhanced the surface area. which was reflected in the amount of water sorbed. Deprotonation of hydroxyl groups was proved by the measurements of the ignition loss. The heating of lithium saturated montmorillonite at higher temperatures brough about the collapse of the interlayers and a decrease in the amount of water sorbed. 相似文献
965.
E. K. Merabet H. K. Yuen W. A. Grote K. L. Deppermann 《Journal of Thermal Analysis and Calorimetry》1994,42(5):895-906
A new sensitive isothermal titration microcalorimeter using polyvinylidene difluoride (PVDF) as detector has been developed. Heat pulses of less than 0.4 μJ can be detected and the baseline noise level (p-p) is 40 nW. The calorimeter is constructed with one reaction cell (0.7 ml) insulated by several radiation shields inside a vacuum chamber. The performance of the instrument was examined by measuring the heat of protonation of Tris with HCl. The enthalpy of reaction was found to be ?49±1 kJ·mol?1, in good agreement with the reported value of ?47.5 kJ·mol?1. 相似文献
966.
The thermal dehydration of copper(II) acetate hydrate has been studied between 353 and 406 K, over a range of humidities.
The dehydration is controlled by nucleation-and-growth kinetics at low temperatures, with an activation energy of 154 kJ·mol−1, which changes to contracting-disc kinetics at higher temperatures with a lower activation energy of 76 kJ·mol−1. Frequency factors have also been derived; the value for the high temperature process is low (107s−1) and that for the low temperature step is high (1017s−1). Optical microscopy has been used to clarify the bulk kinetics; there is evidence for a reactive layer at the surface of
the decomposing solid.
In celebration of the 60th birthday of Dr Andrew K. Galwey 相似文献
967.
A. S. Sidorenko L. R. Tagirov A. N. Rossolenko N. S. Sidorov V. I. Zdravkov V. V. Ryazanov M. Klemm S. Horn R. Tidecks 《JETP Letters》2002,76(1):17-20
According to the crystal structure of MgB2 and band structure calculations, quasi-two-dimensional (2D) boron planes are responsible for the superconductivity. We report on critical-field and resistance measurements of 5.6-μm-thick MgB2 films grown on a sapphire single-crystal substrate. Resistivity measurements yield a temperature dependence of the fluctuation conductivity above the critical temperature, which agrees with the Aslamazov-Larkin and Maki-Thompson theory of fluctuations in layered superconductors, indicating a quasi-two-dimensional nucleation of superconductivity in MgB2. 相似文献
968.
969.
J. M. Godoy M. L. Godoy Z. L. Carvalho D. C. Lauria 《Journal of Radioanalytical and Nuclear Chemistry》1994,183(1):19-26
A short overview of HPLC column packings is presented. The properties of chromatographic carriers and the possibilities to combine the solid matrices with organic polymeric stationary phases are elucidated in detail. The latest achievements and anticipated future developments in the area are outlined. 相似文献
970.
O. Kindel F. J. Herrmann L. Schmidt 《Journal of Radioanalytical and Nuclear Chemistry》1994,183(2):219-224
By simulation experiments with a 10–5 mol/l solution of iodododecane labeled with131I in n-dodecane the influence of various materials and conditions, which are possible in nuclear fuel reprocessing, has been investigated. The formation of decomposition products was detected via HPLC with a radioactivity monitor. By means of252Cf plasma-desorption mass spectrometry (PDMS) the decomposition products were identified. It was found that a temperature of 100°C favored the formation of iodoalkanes with chain lengths of C1 to C11. The presence of TBP(tri-n-butyl-phosphate) accelerated the decomposition of iodododecane. In pure TBP only iodobutane was formed as a decomposition product. 相似文献