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131.
The offset dependence of homonuclear Hartmann-Hahn transfer is markedly different if a given multiple-pulse sequence is applied to dipolar coupled spins or to isotropically coupled spins. The different offset dependence of the transfer efficiency is studied by numerical simulations of a multiple-pulse sequence and by the analytical treatment of a simple model experiment. 相似文献
132.
We study the pattern of soft parton radiation in the hard annihilation processes \(e^ + e^ - \to q\bar q\gamma \) and \(e^ + e^ - \to q\bar qg\) by explicit evaluation of the cross sections for \(e^ + e^ - \to q\bar q\gamma g\) and \(e^ + e^ - \to q\bar qgg + q\bar qq\bar q\) taken care of correct normalization. We find the coherence effects as observed experimentally and discuss why these effects are not present in the usual models based onO(α s 2 ) perturbation theory with subsequent independent fragmentation. 相似文献
133.
134.
S. Caroli M. Spagnoli G. Forte M. Alessandrelli R. Cresti S. D'Ilio J. Pauwels G. N. Kramer Gy. Zray 《Microchemical Journal》2000,67(1-3)
In the framework of the activities of the Community Reference Laboratory (CRL) for residues at the Istituto Superiore di Sanità (ISS) of Rome, a number of proficiency tests were performed in order to assess and improve, wherever necessary, the quality of regulatory residue analysis within the EU. In this context, a pilot study was undertaken with the purpose of ascertaining the feasibility of a project for the certification of a new reference material for trace elements in bovine muscle. On behalf of the ISS, approximately 70 kg of bovine muscle, collected at a slaughterhouse in Geel (Belgium), were freeze-dried, homogenized, stabilized and bottled under argon atmosphere by the Institute for Reference Materials and Measurements, Joint Research Centre, European Commission (IRMM-JRC-EC). Preliminary analyses were carried out with Quadrupole (Q) and High Resolution (HR) Inductively Coupled Plasma Mass Spectrometry (ICP-MS) to evaluate the content of As, Cd, Cu and Pb, whereas the Flow Injection Mercury System (FIMS) was used to quantify Hg. Digestion of the matrix was achieved by acid-assisted microwave irradiation. The mean values of experimentally obtained data were the following (in nanograms per gram): As, 24.2±1.2; Cd, 5.48±0.29; Cu, 4765±95; Hg, 3.37±0.73; and Pb, 184±7. Subsequently, 16 National Reference Laboratories (NRLs) for residues in the Member States plus the Norwegian one and eight Italian public laboratories were accepted to participate in the project and received one bottle of the freeze-dried bovine muscle. The laboratories were requested to perform three different analytical runs (in three different days), each consisting of three individual measurements. Preliminary results showed good agreement and fair evidence for homogeneity of the entire mass, thus setting the stage for the future certification of this candidate CRM. 相似文献
135.
A synthetic route towards surface modified, monodisperse, spherical particles is presented. The precursor particles exhibit epoxy‐functionalities which can be opened afterwards with an appropriate nucleophile. Via this route, dye labeled particles are obtained. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
136.
137.
We calculate branching ratios and the polarization in the decay ofB mesons to two vector mesons using heavy quark symmetries to evaluate the current matrix elements. 相似文献
138.
In [17] we proved a lower bound for the spectrum of the Dirac operator on quaternionic Kähler manifolds. In the present article we study the limiting case, i.e. manifolds where the lower bound is attained as an eigenvalue. We give an equivalent formulation in terms of a quaternionic Killing equation and show that the only symmetric quaternionic Kähler manifolds with smallest possible eigenvalue are the quaternionic projective spaces. 相似文献
139.
140.
Nanocelluloses: a new family of nature-based materials 总被引:2,自引:0,他引:2
Klemm D Kramer F Moritz S Lindström T Ankerfors M Gray D Dorris A 《Angewandte Chemie (International ed. in English)》2011,50(24):5438-5466
Cellulose fibrils with widths in the nanometer range are nature-based materials with unique and potentially useful features. Most importantly, these novel nanocelluloses open up the strongly expanding fields of sustainable materials and nanocomposites, as well as medical and life-science devices, to the natural polymer cellulose. The nanodimensions of the structural elements result in a high surface area and hence the powerful interaction of these celluloses with surrounding species, such as water, organic and polymeric compounds, nanoparticles, and living cells. This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants. 相似文献