全文获取类型
收费全文 | 149篇 |
免费 | 12篇 |
国内免费 | 2篇 |
专业分类
化学 | 139篇 |
晶体学 | 4篇 |
力学 | 1篇 |
数学 | 7篇 |
物理学 | 12篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 7篇 |
2019年 | 10篇 |
2018年 | 8篇 |
2017年 | 6篇 |
2016年 | 11篇 |
2015年 | 8篇 |
2014年 | 7篇 |
2013年 | 9篇 |
2012年 | 11篇 |
2011年 | 13篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1988年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1971年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有163条查询结果,搜索用时 328 毫秒
71.
Fluorinated monomers containing a benzoxazine moiety have been synthesized successfully by preparing the benzoxazines from fluorinated amines (4‐fluoroaniline, 2,4‐difluoroaniline, and 2,3,4‐trifluoroaniline). These monomers were polymerized by step curing process following a cure cycle of 100, 150, 200 and 250°C for 1 h at each temperature. The molecular structure of the monomers and their polymers was characterized by Fourier transform infrared and nuclear magnetic resonance techniques. The synthesized fluorinated polybenzoxazines were able to reduce the dielectric constant to 2.0 for polybenzoxazine from 2,3,4 trifluoroaniline (PTF)‐Bzo at a frequency of 1 MHz. Moreover, they possess high thermal stability and low moisture absorption, which makes it suitable for high‐temperature process of interlayer dielectrics. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
72.
4-(2,3,4-trimethoxyphenyl)-8-methoxy-2-oxo-1,2,5,6 tetrahydrobenzo [h] quinoline-3-carbonitrile (TMTQ) dye was synthesized by one-pot multicomponent reactions (MCRs) of 2,3,4 trimethoxybenzaldehyd, ethyl cyanoacetate, 6-methoxy-1,2,3,4-tetrahydro-naphthalin-1-one and ammonium acetate under microwave irradiation. The structures of the synthesized compound was established by spectroscopic (FT-IR, 1H–NMR, 13C–NMR, EI-MS) and elemental analysis. In addition, spectroscopic and physicochemical parameters, including electronic absorption, excitation coefficient, Stokes shift, oscillator strength, transition dipole moment and fluorescence quantum yield have investigated in order to explore the analytical potential of synthesized compounds. TMTQ dye undergoes solubilization in different micelles and may be used as a probe and quencher to determine the critical micelle concentration (CMC) of CTAB and SDS. In addition we extent of TMTQ anti-bacterial properties TMTQ was first tested in vitro by the disk diffusion assay against two Gram-positive and two Gram-negative bacteria, and then the minimum inhibitory concentration (MIC) was determined with the reference of standard drug Tetracycline. 相似文献
73.
Solid-state polymer electrolytes possess high conductivity and have advantages compared with their liquid counterparts. The polyethylene oxide (PEO)-based polymer is a good candidate for this purpose. The PEO/SnCl2/polyaniline composite (PSP composites) at different weight percentages were prepared in anhydrous acetonitrile media. Structural studies were carried out of the prepared composites by X-ray diffraction, Fourier transmission infrared spectroscopy, and surface morphology by scanning electron microscopy. The σ dc was carried out by a two-probe method, and it is found that the conductivity increases with an increase in temperature. The temperature-dependent conductivity of the composites exhibits a typical semi-conducting behavior and hence can be explained by the 1D variable range hopping model proposed by Mott. The electrochemical cell parameters for battery applications at room temperature have also been determined. The samples are fabricated for battery application in the configuration of Na: (PSP): (I2?+?C?+?sample), and their experimental data are measured using Wagner’s polarization technique. The cell parameters result in an open-circuit voltage of 0.83 V and a short-circuit current of 912 μA for PSP (70:30:10) composite. Hence, these composites can be used in polymer electrolyte studies. 相似文献
74.
75.
Novel molecular ecological techniques were used to study changes in microbial community structure and population during degradation of polylactide (PLA)/organically modified layered silicates (OMLS) nanocomposites. Cloned gene sequences belonging to members of the phyla Actinobacteria and Ascomycota comprized the most dominant groups of microorganisms during biodegradation of PLA/OMLS nanocomposites. Due to their numerical abundance, members of these microbial groups are likely to play an important role during biodegradation process. This paper presents new insights into the biodegradability of PLA/OMLS nanocomposites and highlights the importance of using novel molecular ecological techniques for in situ identification of new microorganisms involved in biodegradation of polymeric materials.
76.
A hybrid approach has been adopted by using a combination of colloidal graphite (CG) as a conducting filler, 5‐lithium sulfoisophthalic (LiSIPA) acid as a dopant, and polyaniline (PANI) as a matrix to prepare LiSIPA doped PANI–CG composites. The thermal stability (~300°C) and electrical conductivity (67.4 S/cm at 17.4% CG content) have been improved significantly as compared to PANI doped with conventional inorganic dopants like HCl or H2SO4 (130–150°C). The maximum shielding effectiveness value was found to be ?39.7 dB. X‐ray diffraction and infrared spectroscopy showed a systematic shifting of the characteristic peaks and bands with increase in the amount of CG, which indicates significant interaction exists between CG and PANI. The UV–Vis spectra showed the characteristic bands of PANI, with a shift to shorter wavelength with increase in the CG content. The interaction mechanism between doped PANI and CG in the resultant composites has been proposed. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
77.
Abdul Wajid Khan Saleem Jan Shaista Parveen Rahmat Ali Khan Asma Saeed Abdul Jabbar Tanveer Anwar Ali Shad 《Chemistry Central journal》2012,6(1):1-6
Background
Nickel ferrite, a kind of soft magnetic materials is one of the most attracting class of materials due to its interesting and important properties and has many technical applications, such as in catalysis, sensors and so on. In this paper the synthesis of NiFe2O4 nanoparticles by the hydrothermal method is reported and the inhibition of surfactant (Glycerol or Sodium dodecyl sulfate) on the particles growth is investigated.Methods
For investigation of the inhibition effect of surfactant on NiFe2O4 particles growth, the samples were prepared in presence of Glycerol and Sodium dodecyl sulfate. The X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM) and inductively coupled plasma atomic emission spectrometer (ICP-AES) techniques were used to characterize the samples.Results
The results of XRD and ICP-AES show that the products were pure NiFe2O4 and also nanoparticles grow with increasing the temperature, while surfactant prevents the particle growth under the same condition. The average particle size was determined from the Scherrer's equation and TEM micrographs and found to be in the range of 50-60 nm that decreased up to 10-15 nm in presence of surfactant. The FT-IR results show two absorption bands near to 603 and 490 cm-1 for the tetrahedral and octahedral sites respectively. Furthermore, the saturated magnetization and coercivity of NiFe2O4 nanoparticles were in the range of 39.60 emu/g and 15.67 Qe that decreased for samples prepared in presence of surfactant. As well as, the nanoparticles exhibited a superparamagnetic behavior at room temperature.Conclusions
Nanosized nickel ferrite particles were synthesized with and without surfactant assisted hydrothermal methods. The results show that with increasing of temperature, the crystallinity of nanoparticles is increased. In the presence of surfactants, the crystallinity of NiFe2O4 nanoparticles decreased in comparison with surfactant- free prepared samples. All of the nickel ferrite nanoparticles were superparamagnetic at room temperature.Graphical abstract
相似文献78.
Polyaniline (PANI) and polypyrrole (PPY) were grafted over cotton fabrics by in situ polymerization. FTIR spectra show systematic shifting of bands corroborating surface grafting of conducting polymers on cotton fabric. SEM images revealed that the surface coating of PANI was smoother than PPY. However, better control over coating thickness and uniformity was achieved in PPY fabric. The probable formation mechanism of grated fabrics has also been proposed. The good thermal stability and acceptable electronic conductivity values indicate that these fabrics could be used for electrostatic charge dissipation and microwave absorption. The antistatic studies have shown complete charge dissipation (decay time <0.01 sec). The microwave absorption studies of the conducting fabrics in X‐band (8.2–12.4 GHz) show absorption dominated total shielding effectiveness in the range ?11.3 to ?11.7 dB (>92% attenuation) and ?9.2 to ?9.6 dB (>88% attenuation) for fabrics grafted with PPY and PANI, respectively. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
79.
Projective synchronization of time‒delayed chaotic systems with unknown parameters using adaptive control method 下载免费PDF全文
The present article aims to study the projective synchronization between two identical and non?identical time?delayed chaotic systems with fully unknown parameters. Here the asymptotical and global synchronization are achieved by means of adaptive control approach based on Lyapunov–Krasovskii functional theory. The proposed technique is successfully applied to investigate the projective synchronization for the pairs of time?delayed chaotic systems amongst advanced Lorenz system as drive system with multiple delay Rössler system and time?delayed Chua's oscillator as response system. An adaptive controller and parameter update laws for unknown parameters are designed so that the drive system is controlled to be the response system. Numerical simulation results, depicted graphically, are carried out using Runge–Kutta Method for delay?differential equations, showing that the design of controller and the adaptive parameter laws are very effective and reliable and can be applied for synchronization of time?delayed chaotic systems. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
80.
Mehtab Parveen Raza Murad Ghalib Mahboob Alam Monika Singh 《Journal of Saudi Chemical Society》2013,17(3):303-305
The phenanthren skeleton, named as Peltophorin was isolated from methanolic extraction of the leaves of Peltophorum vogelianum. The structure was elucidated on the basis of chemical and physical evidence (IR, UV, 1H NMR, 13C NMR) and further confirmed X-ray analysis. 相似文献