首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   396篇
  免费   10篇
  国内免费   2篇
化学   341篇
晶体学   3篇
力学   2篇
数学   23篇
物理学   39篇
  2023年   3篇
  2022年   3篇
  2021年   6篇
  2020年   5篇
  2019年   10篇
  2018年   3篇
  2017年   3篇
  2016年   7篇
  2015年   11篇
  2014年   10篇
  2013年   23篇
  2012年   34篇
  2011年   27篇
  2010年   18篇
  2009年   13篇
  2008年   29篇
  2007年   35篇
  2006年   23篇
  2005年   12篇
  2004年   20篇
  2003年   16篇
  2002年   11篇
  2001年   7篇
  2000年   3篇
  1998年   2篇
  1997年   8篇
  1996年   3篇
  1995年   5篇
  1993年   2篇
  1992年   4篇
  1989年   2篇
  1986年   2篇
  1983年   3篇
  1982年   2篇
  1979年   1篇
  1978年   1篇
  1977年   5篇
  1976年   5篇
  1975年   2篇
  1974年   6篇
  1973年   3篇
  1972年   2篇
  1971年   2篇
  1970年   1篇
  1966年   1篇
  1954年   1篇
  1932年   2篇
  1927年   1篇
  1923年   1篇
  1915年   1篇
排序方式: 共有408条查询结果,搜索用时 15 毫秒
271.
Double differential cross sections for the inclusive reaction 4He(π, π′)X have been measured for six pion energies between 90 and 320 MeV and an angular range from 30° to 135°. The data are interpreted in terms of the Δ-hole formalism. Medium corrections to the free π-nucleon scattering operator are important for a quantitative understanding of our results. Total inelastic cross sections are obtained and estimates for the absorption cross section are given.  相似文献   
272.
We have measured 12C-13C elastic cross sections at 12 MeV between 40°–140° in 1° steps to ±1%. The observed oscillatory interference between Coulomb scattering and the neutron transfer process is analyzed using exact finite-range DWBA, and a model-independent value of C2 = 2.55±0.10 for the asymptotic normalization of the 1p12 neutron wave function in 13C is obtained. Using radial wave functions determined by elastic electron scattering the spectroscopic factor is found to be S = 0.81±0.04.  相似文献   
273.
274.
275.
276.
In this paper, we propose a new approach to deal with the non-zero slacks in data envelopment analysis (DEA) assessments that is based on restricting the multipliers in the dual multiplier formulation of the used DEA model. It guarantees strictly positive weights, which ensures reference points on the Pareto-efficient frontier, and consequently, zero slacks. We follow a two-step procedure which, after specifying some weight bounds, results in an “Assurance Region”-type model that will be used in the assessment of the efficiency. The specification of these bounds is based on a selection criterion among the optimal solutions for the multipliers of the unbounded DEA models that tries to avoid the extreme dissimilarity between the weights that is often found in DEA applications. The models developed do not have infeasibility problems and we do not have problems with the alternate optima in the choice of weights that is made. To use our multiplier bound approach we do not need a priori information about substitutions between inputs and outputs, and it is not required the existence of full dimensional efficient facets on the frontier either, as is the case of other existing approaches that address this problem.  相似文献   
277.
Gramicidin A, a polypeptide antibiotic forming transmembrane ion channels, has been incorporated into a Langmuir monolayer formed by a semifluorinated alkane (SFA). In this work, partially fluorinated tetracosane, perfluorohexyloctadecane (F6H18), has been applied, aiming at finding a suitable matrix for gramicidin A to be transferred onto solid support for a biosensor design. For this purpose, the physiological conditions were of special interest (mixed monolayers containing low gramicidin proportion and the surface pressure of 30 mN/m). Mixed monolayers of gramicidin and SFA were found to be miscible within the whole range of mole fractions. A very significant increase of the stability of SFA monolayer has been found in the presence of gramicidin, even at such a low proportion as X(gramicidin) = 0.1, which is reflected in a 3.5-fold increase of the collapse pressure value of mixed monolayer as compared to the film from pure SFA. This interesting phenomenon has been interpreted as being due to the existence of a strong dipole-dipole interaction between both film-forming molecules. Opposite sign of the measured electric surface potential for gramicidin and SFA, resulting from different directions of the dipole moment vectors in both film molecules, implies that the ordered, antiparallel orientation of the dipole moments in the mixed gramicidin/SFA system can be responsible for its extremely high stability.  相似文献   
278.
We describe a facile procedure for the synthesis at low temperature (120 °C) of water-dispersible uniform YF3:Yb,Er up-conversion nanophosphors of various morphologies (rhombic and spheroidal) by homogeneous precipitation in polyol solutions containing different lanthanide salts and an ionic liquid (1-butyl, 2-methylimidazolium tetrafluoroborate) as fluoride source. It is shown that the shape of the obtained nanoparticles is mainly determined by the nature of both, the polyol and the lanthanide precursors, which also affects to their colloidal stability in water suspensions. These morphological differences are explained on the basis of a different mechanism of particle formation. The efficiency of the up-conversion processes in the synthesized rhombic and spheroidal nanoparticles is also comparatively analyzed and the observed differences are justified on the basis of the different impurities incorporated to the nanophosphors during their synthesis process.  相似文献   
279.
This paper presents several experiments on sound source localization. They are based on monaural click presented at different interclick intervals (ICI), from 10 to 100 ms. Trains of clicks were presented to 10 healthy subjects. At short interclick intervals the clicks were perceived as a blur of clicks having a buzzy quality. Moreover, it was proven that the accurateness in the response improves with the increase of the length of ICI. The present results imply the usefulness of the interclick interval in estimating the perceptual accuracy. An important benefit of this task is that this enables a careful examination of the sound source perception threshold. This allows detecting, localizing and dividing with a high accuracy the sounds in the environment. The text was submitted by the authors in English.  相似文献   
280.
A NAD+-analog was coimmobilized with lactate dehydrogenase (LDH) on reticulated vitreous carbon (RVC) to give an amperometric lactate biosensor. Both LDH and the NAD+ -analog were bound covalently with carbodiimide to the surface of the porous RVC-material. The electrode was operated in a FIA-arrangement in the presence or absence of a soluble mediator. Meldola Blue. The stability was poor when the electrode was operated at +400 mV (vs. Ag/AgCl) in the absence of mediator but improved most significantly in the presence of 5 μM mediator, so that 65% of the original activity remained after 16 days. The amperometric currents were smaller with regeneration by mediator at −100 mV than with direct electrochemical oxidation at +400 mV, indicating that the additional steps slow down the reaction rate. Linear calibration plots were obtained from the detection limit, 1 μM, to 500 μM lactate with 5 μM mediator, reoxidized at −100 mV. The sample throughput was about 60 h−1.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号