Influence of Macro-pores on DNAPL Migration in Double-Porosity Soil Using Light Transmission Visualization Method

Double porosity is a substantial microstructure characteristic in a wide range of geomaterials. It is a natural phenomenon that can be found in many types of soil, and it can result from biological, chemical or mechanical damage. In this paper, the influence of macro-pores on dense non-aqueous phase liquid (DNAPL) migration in double-porosity medium was investigated using light transmission visualization technique. Three experiments were carried out in two-dimensional flow chambers filled with a double-porosity medium composed of a mixture of local sand and sintered kaolin clay spheres arranged in a periodic manner. In each experiment, a different volumetric fraction of macro-pores and micropores was used. Tetrachloroethylene (PCE) was used to simulate DNAPL, and it was dyed using Oil-Red-O for better visualization. A predetermined amount of PCE was injected into the flow chambers and this amount was re-calculated using image analysis. A very strong correlation was found between the PCE amount injected and the amount calculated from image analysis in each experiment. The experiment was repeated by filling the flow chamber with silica sand to represent single-porosity medium. The results show that the macro-pores have a considerable effect on the PCE migration in double-porosity soil as the PCE movement was the fastest in the third experiment which contained the largest macro-pores volume. The accuracy of the method was validated using statistical analysis. The results show a slight difference between the means of the three experiments, indicating that the method is viable for monitoring NAPL migration in double-porosity medium under different volumetric fractions of macro-pores and micropores.     

Surface Functionalization of Face Masks with Cold Plasma and Its Effect in Anchoring Polyphenols Extracted from Agri-Food

To improve the capability of non-woven polypropylene-based fabric (NWF-PP) used for face mask production to retain active biomolecules such as polyphenols, the surface functionalization of NWF-PP–directly cut from face masks–was carried out by employing cold plasma with oxygen. The nature/structure of the functional groups, as well as the degree of functionalization, were evaluated by ATR-FTIR and XPS by varying the experimental conditions (generator power, treatment time, and oxygen flow). The effects of plasma activation on mechanical and morphological characteristics were evaluated by stress–strain measurements and SEM analysis. The ability of functionalized NWF-PP to firmly anchor polyphenols extracted from cloves was estimated by ATR-FTIR analysis, IR imaging, extractions in physiological solution, and OIT analysis (before and after extraction), as well as by SEM analysis. All the results obtained converge in showing that, although the plasma treatment causes changes–not only on the surface–with certain detriment to the mechanical performance of the NWF-PP, the incorporated functionalities are able to retain/anchor the active molecules extracted from the cloves, thus stabilizing the treated surfaces against thermo-oxidation even after prolonged extraction.     

MHD mixed convection flow near the stagnation-point on a vertical permeable surface

The steady magnetohydrodynamic (MHD) mixed convection boundary layer flow of a viscous and electrically conducting fluid near the stagnation-point on a vertical permeable surface is investigated in this study. The velocity of the external flow and the temperature of the plate surface are assumed to vary linearly with the distance from the stagnation-point. The governing partial differential equations are first transformed into ordinary differential equations, before being solved numerically by a finite-difference method. The features of the flow and heat transfer characteristics for different values of the governing parameters are analyzed and discussed. Both assisting and opposing flows are considered. It is found that dual solutions exist for both cases, and the range of the mixed convection parameter for which the solution exists increases with suction.     

Lower bounds for heights in cyclotomic extensions

We show that the height of a nonzero algebraic number α that lies in an abelian extension of the rationals and is not a root of unity must satisfy h(α)>0.155097.     

Similarity solutions for flow and heat transfer over a permeable surface with convective boundary condition

The steady laminar boundary layer flow over a permeable flat plate in a uniform free stream, with the bottom surface of the plate is heated by convection from a hot fluid is considered. Similarity solutions for the flow and thermal fields are possible if the mass transpiration rate at the surface and the convective heat transfer from the hot fluid on the lower surface of the plate vary like x^−1/2, where x is the distance from the leading edge of the solid surface. The governing partial differential equations are first transformed into ordinary differential equations, before being solved numerically. The effects of the governing parameters on the flow and thermal fields are thoroughly examined and discussed.     

MHD stagnation point flow towards a stretching sheet

The steady two-dimensional MHD stagnation point flow towards a stretching sheet with variable surface temperature is investigated. The governing system of partial differential equations are transformed into ordinary differential equations, which are then solved numerically using a finite-difference scheme known as the Keller-box method. The effects of the governing parameters on the flow field and heat transfer characteristics are obtained and discussed. It is found that the heat transfer rate at the surface increases with the magnetic parameter when the free stream velocity exceeds the stretching velocity, i.e. ε>1, and the opposite is observed when ε<1.