Complexes of Nitrilotriacetic Acid with Amines. Molecular Structures of 2-Ammonioethanol Nitrilotriacetate and Bis{2-Ammonio-2-(Hydroxymethyl)propane-1,3-Diol} Nitrilotriacetate

Crystallography Reports - Reactions of nitrilotriacetic acid with 2-aminoethanol, 2-amino-2-(hydroxymethyl)propane-1,3-diol, and 2,2'-(ethylenedioxy)bis(ethylamine) afford the following salts...     

X-ray diffraction topography and diffuse scattering techniques applied to study the defect structure of plastically deformed al single crystals

X-ray diffraction topography and diffuse scattering techniques were used to study the defect structure formation of plastically deformed Al single crystals. The investigated X-ray scattering has been found out materially to depend upon the character of the dislocation structure (upon the geometry of the dislocation distribution). This dependence is manifested in different distribution of the intensity and in the changed form of the isointensity curves of diffuse and regular (Laue) reflections. In spite of the fact that the distribution of the internal stresses acting in different glide systems under conditions of uniaxial stretching is of complicated character, it is possible to trace the development of the glide process in the body of a sample and to obtain satisfactory interference patterns both of regular reflexions (on topograms) and of diffuse ones (on Laue photographs) up to severe deformations of a crystal at 300, 4.2, and 1.6 K. The following diffuse effects connected with structural changes in deformed crystals have been ascertained on the X-ray photographs:

• —diffuse regions are elongated in the reciprocal lattice space along the glide directions or other crystallographic directions;
• —these diffuse regions are split into separate areas along the directions of the said elongations;
• —the diffuse regions are changed in length: the diffuse reflexes are diffused or condensed;
• —the diffuse scattering isointensity curves are “zigzag”-shaped.

     

Interaction of PdCl 42- with L-cystine in hydrochloric acid solutions

The effect of acidity and equilibrium chloride ion concentration on the interaction of PdCl₄ ^2- with cystine (H₂CySS) in hydrochloric acid solutions was studied. Pd(H₄CySS)Cl₃+ complex was found to form at [Cl^–] = 1.0, 0.5, or 0.25 mol/Linthe [H⁺] range from 0.10 to 1.00 mol/L; the relevant equilibrium constant was determined. Monodentate coordination of cystine to palladium(II) through the sulfur atom was proposed on the basis of analysis of conditional stability constants as functions of [Cl^–] and [H⁺].     

The Banach-Saks index of some sequence spaces

We construct an example of a Rademacher subspace without the Banach-Saks property and study the relationship between the Banach-Saks indices of a space with a symmetric basis and its dual.     

Reactions of aromatic and heteroaromatic compounds having electron-acceptor substituents

The chloromethylation of 2-acetothienone and 2-formylthiophene with , -bischloromethyl ether in 60–100% sulfuric acid was studied. An increase in the acidity of the medium promotes the formation of 4-substituted products, which, as in nitration and bromination, is explained by protonation of the carbonyl group, leading to intensification of its electron-acceptor capacity.See [1] for communication VI.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1353–1357, October, 1971.     

Synthesis of O-maltosides and O-melibiosides of serine derivatives

Conclusions We synthesized the O-maltosides and O-melibiosides of N-carbobenzoxy-L-serine methylamide and L-serine methylamide.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2509–2514, November, 1969.     

Polarizability anisotropy of maleic and phthalic anhydrides

Conclusions The polarizability ellipsoids of the maleic and phthalic anhydride molecules are characterized by substantial nonadditivity.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2154–2156, September, 1977.