Synthesis of (E)-2,5-disubstituted 1,3,4-thiadiazolyl-2,3-diphenylpropenones from alkenylidene-hydrazinecarbothioamides

Conjugated alkenylidene-hydrazinecarbothioamides react in high yield with 2,3-diphenylcyclopropenone to give a series of (E)-2,5-disubstituted 1,3,4-thiadiazolyl-2,3-diphenylpropenones.     

Construction and performance characteristics of new ion selective electrodes based on carbon nanotubes for determination of meclofenoxate hydrochloride

This work offers construction and comparative evaluation the performance characteristics of conventional polymer (I), carbon paste (II) and carbon nanotubes chemically modified carbon paste ion selective electrodes (III) for meclofenoxate hydrochloride are described. These electrodes depend mainly on the incorporation of the ion pair of meclofenoxate hydrochloride with phosphomolybdic acid (PMA) or phosphotungestic acid (PTA). They showed near Nernestian responses over usable concentration range 1.0 × 10⁻⁵ to 1.0 × 10⁻² M with slopes in the range 55.15–59.74 mV (concentration decade)⁻¹. These developed electrodes were fully characterized in terms of their composition, response time, working concentration range, life span, usable pH and temperature range. The electrodes showed a very good selectivity for Meclo with respect to a large number of inorganic cations, sugars and in the presence of the degradation product of the drug (p-chloro phenoxy acetic acid). The standard additions method was applied to the determination of MecloCl in pure solution, pharmaceutical preparations and biological samples. Dissolution testing was also applied using the proposed sensors.     

Synchronization of different dimensional chaotic systems with time varying parameters, disturbances and input nonlinearities

In this paper, the problems of robust exponential generalized and robust exponential Q-S chaos synchronization are investigated between different dimensional chaotic systems. We consider the more practical and realistic cases when unknown time varying parameters with uncertainties, environmental disturbances, and nonlinearity of input control signals are present. The adaptive technique is employed to design the appropriate controllers and the validity of the proposed controllers are proved using Lyapunov stability theorem. Furthermore, numerical simulations are performed to show the efficiency of the presented scheme.     

Resonance Raman study of the polyiodide complex formed in the reaction of iodine with the polysulphur cyclic base 1,4,7,10,13,16-hexathiacyclooctadecane

Resonance Raman spectroscopy has been used to study the reaction of iodine with the interesting polysulphur cyclic base, 1,4,7,10,13,16,-haxathiacyclootadecane (HTCOD). The results indicate that the complex [(HTCOD)2]+ x I5- is formed. The I5- unit exists in the form of distorted I2 linked to I3- unit which has two unequivalent I-I bonds. The v(I-I) for I2 occurs at 194 cm(-1) while for I-I, inner and outer bonds in I3- at 143 and 160 cm(-1), respectively.     

Preparation and infrared spectrum of the novel isocyanato complex [Ni2(NCO)2(H2O)4]Cl2 formed by the reaction of urea with NiCl2

Summary The novel bridged diisocyanato complex [Ni₂(NCO)₂(H₂O)₄]Cl₂ was obtained by reaction of aqueous solutions of NiCl₂·6H₂O and urea atca. 80° C. The i.r. spectrum of the product clearly indicates the absence of the bands of urea, but shows the characteristic bands of coordinated isocyanate ions and coordinated water. A general mechanism describing the formation of the isocyanato complex is suggested.     

Consolidation Statistics Investigation via Thin Layer Method Analysis

In this paper, the Thin Layer Method (TLM) is adapted for solving one-dimensional primary consolidation problems. It is also combined with a stochastic formulation integrating Monte Carlo simulations to investigate primary consolidation of a random heterogeneous soil profile. This latter is modeled as a set of superposed layers extending horizontally to infinity, and having random properties. Spatial variability of soil properties is considered in the vertical direction only. Soil properties of interest are elastic modulus and soil permeability, modeled herein as spatially random fields. Lognormal distribution is chosen because it is suitable for strictly non-negative random variables, and enables analyzing the large variability of such properties. The statistics regarding final settlement and its corresponding time are investigated by performing a parametric study, which integrates the influence of variation coefficient of both elastic modulus and soil permeability, and vertical correlation length. Obtained results indicate that heterogeneity significantly influences primary consolidation of the soil profile, generating a quite different way of soil grain rearrangement and water pressure dissipation in comparison to the homogeneous case, and causing a delay in the consolidation process.     

Theoretical and Numerical Analysis of a Class of Nonlinear Elliptic Equations

In this paper we show the existence of weak solutions for a nonlinear elliptic equation with arbitrary growth of the non linearity and data measure. A numerical algorithm to compute a numerical approximation of the weak solution is described and analyzed. In a first step a super-solution is computed using a domain decomposition method. Numerical examples are presented and commented. This work was supported by the French Grant “Action Intégrée MA/02/33”.     

Validated Densitometric TLC Method for Analysis of (R)- and (S)-Bupivacaine,Using Cyclodextrin Derivatives as Chiral Selectors

JPC – Journal of Planar Chromatography – Modern TLC - Anovel economic procedure for stereospecific separation and analysis of (R)-and (S)-bupivacaine has been developed and validated....     

The state constrained bilateral minimal time function

We generalize, to the bilateral case (that is, with variable initial and end points), the main results of Nour and Stern [C. Nour, R.J. Stern, Regularity of the state constrained minimal time function, Nonlinear Anal. 66 (1) (2007) 62–72] and Stern [R.J. Stern, Characterization of the state constrained minimal time function, SIAM J. Control Optim. 43 (2004) 697–707], where the regularity and Hamilton–Jacobi characterization of the state constrained (unilateral) minimal time function were studied.