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131.
This note extends Clarke's decoupling technique to systems with varying time delays in the state variable. We show how it can be used to derive the usual necessary conditions for such problems. 相似文献
132.
133.
Electron impact mass spectra of some per-O-benzoyl-alditols and -aldobiitols are reported and the major fragmentation pathways are discussed. 相似文献
134.
135.
Hussin N Mondello L Costa R Dugo P Yusoff NI Yarmo MA AbWahab A Said M 《Natural product communications》2012,7(7):927-930
Patchouli essential oil can be obtained from fresh, dried and fermented plant material. It is a highly valuable product in the fragrance industry and its quality changes depending upon raw material age and oil storage. In this work, patchouli essential oils derived from different treatments have been subjected to GC-FID quantitative analysis using an internal standard (ISTD) method with response factors (RF). Samples were obtained from i) fresh plants; ii) hydrodistillation of one year mature and fermented plants; iii) hydrodistillation of one year mature plants; iv) commercial products from Indonesia and Malaysia. Linear Retention Indices (LRI) for both polar and non-polar GC-MS analyses were also measured as a tool for qualitative analysis towards a homologous series of C7-C30 n-alkanes. The results obtained confirmed that, in all samples, patchouli alcohol was the main volatile constituent, with higher amount in lab-scale produced oils, compared with commercial samples. Other major compounds, in lab oils and commercial samples respectively, were: delta-guaiene, alpha-guaiene, pogostol, seychellene and alpha-patchoulene. Another 36 compounds were also found. 相似文献
136.
We study the effects of institutional constraints on stability and efficiency in the “one-way flow” model of network formation. In this model the information that flows through a link between two players runs only towards the player that initiates and supports the link, so in order for it to flow in both directions, both players must pay whatever the unit cost of a directional link is. We assume that an exogenous “societal cover” consisting of a collection of possibly overlapping subsets covering the set of players specifies the social organization in different groups or “societies,” so that a player may initiate links only with players that belong to at least one society that he/she also belongs to, thus restricting the feasible strategies and networks. In this setting, we examine the impact of such societal constraints on stable/efficient architectures and on dynamics. 相似文献
137.
Norma N. Buceta Diego Ruiz Gustavo P. Romanelli Juan C. Autino Helmut Duddeck Reinaldo Pis Diez Jorge L. Jios 《Journal of Physical Organic Chemistry》2014,27(2):106-113
The experimental 1H and 13C NMR spectra of 13 phenyl cinnamates and four 4‐methylcoumarins were investigated and their chemical shifts assigned on the basis of the two‐dimensional spectra. For the unsubstituted cinnamic acid phenyl ester, optimized molecular structures were calculated at a B3LYP/6‐311++G(d,p) level of theory. 1H and 13C NMR chemical shifts were also calculated with the GIAO method at the B3LYP/6‐311 + G(2d,p) level of theory. The comparison between experimental and calculated NMR chemical shift suggests that the experimental spectra are formed from the superposition spectra of the two lowest energy conformers of the compound in solution. The most stable s‐cis configuration found in our studies is also the conformation adopted for a related phenyl cinnamate in solid state. The experimental results were analyzed in terms of the substituent effects. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
138.
Riccardo Ruggerone Norma Negrete Herrera Jan-Anders E. Månson 《European Polymer Journal》2009,45(3):621-4784
Polystyrene-based nanocomposite films containing up to 20 wt% laponite clay have been prepared by emulsion polymerization. Significant increases in the storage and tensile moduli were observed in both the glassy and rubbery state on laponite addition. However, whereas in the glassy state these increases were correlated with the extent of exfoliation of the laponite, in the rubbery state they were more dependent on the overall laponite content. These results are discussed in terms of the observed morphologies and micromechanical models for the reinforcing effect of rigid nano-sized filler particles. 相似文献
139.
Shashi K. Mishra Norma G. Rueda 《Journal of Mathematical Analysis and Applications》2003,284(1):250-265
Under F-convexity, F-concavity/F-pseudoconvexity, F-pseudoconcavity, appropriate duality results for a pair of Wolfe and Mond-Weir type symmetric dual nonlinear programming problems in complex spaces are established. These results are then used to develop second order F-convexity, F-concavity, second order F-pseudoconvexity, F-pseudoconcavity, and appropriate second order symmetric dual nonlinear programming problems in complex spaces. 相似文献
140.
Bratoeff E Ramírez E Flores E Valencia N Sánchez M Heuze I Cabeza M 《Chemical & pharmaceutical bulletin》2003,51(10):1132-1136
The in vitro inhibitory activity of five new progesterone derivatives: 17alpha-hydroxy-16beta-methylpregna-1,4,6-triene-3,20-dione 1; 16beta-methyl-17alpha-toluoyloxypregna-1,4,6-triene-3,20-dione 2; 17alpha-hydroxy-6-methylenepregn-4-ene-3,20-dione 3; 6-methylene-17alpha-toluoyloxypregn-4ene-3,20-dione 4 and 17alpha-(p-bromobenzoyloxy)-6-methylenepregn-4-ene-3,20-dione 5 was determined. These compounds were evaluated as 5alpha-reductase inhibitors as well as antagonists for the androgen receptor. Compounds 1, 2, 3, 4 and 5 showed the following inhibitory activity for the 5alpha-reductase enzyme with IC(50) values of: 1 (1.65 microM), 2 (10 microM), 3 (19 nM), 4 (100 nM) and 5 (100 nM). The results of this study also showed the effect of increasing concentrations of the novel steroids upon [(3)H]dihydrotestosterone binding to androgen receptors from male hamster prostate. The K(i) values for compounds 1, 2, 3, 4, 5 and dihydrotestosterone showed the following order of affinity for the androgen receptor: 4>5>dihydrotestosterone>2>3>1. The overall data indicated that all synthesized compounds 1, 2, 3, 4 and 5 are inhibitors of the 5alpha-reductase enzyme present in the hamster prostate. In addition compounds 1, 2, 3, 4 and 5 also presented an affinity for the androgen receptor. 相似文献