首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   635篇
  免费   20篇
  国内免费   10篇
化学   408篇
晶体学   6篇
力学   13篇
数学   36篇
物理学   202篇
  2023年   4篇
  2022年   9篇
  2021年   6篇
  2020年   10篇
  2019年   13篇
  2018年   9篇
  2017年   9篇
  2016年   24篇
  2015年   12篇
  2014年   20篇
  2013年   46篇
  2012年   29篇
  2011年   43篇
  2010年   25篇
  2009年   25篇
  2008年   32篇
  2007年   36篇
  2006年   38篇
  2005年   33篇
  2004年   28篇
  2003年   25篇
  2002年   14篇
  2001年   10篇
  2000年   8篇
  1999年   6篇
  1998年   9篇
  1997年   6篇
  1996年   10篇
  1995年   5篇
  1994年   11篇
  1993年   10篇
  1992年   9篇
  1991年   3篇
  1990年   3篇
  1988年   5篇
  1987年   10篇
  1986年   4篇
  1985年   3篇
  1984年   8篇
  1983年   7篇
  1982年   6篇
  1981年   6篇
  1980年   9篇
  1979年   4篇
  1978年   5篇
  1977年   4篇
  1975年   3篇
  1973年   2篇
  1967年   1篇
  1966年   1篇
排序方式: 共有665条查询结果,搜索用时 15 毫秒
71.
Mesoscopic nanomaterials with a size ranging from a few nanometers to hundreds of nanometers were generated on a metallic thin film by interfering femtosecond (fs) laser processing. Because the nanomaterials seemed to demonstrate liquid behavior, we named their structure nano water drop. The structure is considerably similar to that of a real water drop observed with a high-speed camera. Using the phase shift between interfering beams, a duplicate structure was generated. This is a new surface modification technique, using a top-down approach.  相似文献   
72.
In this paper, the synthesis and characterization of a series of latent polymeric bis(N‐heterocyclic carbene) (NHC) copper(I) complexes is reported, which can be activated for the copper(I)‐catalyzed azide/alkyne cycloaddition (CuAAC) via ultrasound. To prove the influence of chain length and nature of the polymer towards the activation, poly(isobutylene) (PIB), poly(styrene) (PS) and poly(tetrahydrofuran) (PTHF) are synthesized via living polymerization techniques (LCCP, ATRP, CROP) obtaining different chain lengths (from 2500 to 9000 g/mol), followed by quaternization with N‐methylimidazole, generating the corresponding N‐methylimidazolium‐telechelic polymers. The deprotonation of these macroligands via strong bases like sodium tert‐butoxide (NaOtBu) or potassium hexamethyldisilazide (KHMDS) yields the free N‐heterocyclic carbenes (NHCs), which are used to coordinate to tetrakis(acetonitrile)copper(I) hexafluorophosphate, forming the final polymer‐based mono‐ and bis(N‐methylimidazole‐2‐ylidene) copper(I)X complexes. The structural proof of these complexes is accomplished via 1H‐NMR spectroscopy, MALDI‐TOF‐MS and GPC‐techniques. The activation of the copper(I) biscarbene catalysts by ultrasound is studied by GPC, revealing the cleavage of one shielding NHC‐ligand. The initial catalytic latency and the via ultrasound introduced catalytic activation is successfully demonstrated monitoring a CuAAC “click” reaction of benzyl azide and phenylacetylene by in situ 1H‐NMR spectroscopy introducing thus “click” conversions up to 97%. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3893–3907  相似文献   
73.
74.
Summary An attempt is made to modify the plasticity theory for compressible materials and then to derive the upper bound theorem or the second extremum principle which incorporate normal velocity discontinuity; this discontinuity is considered to be a measure of fracture. The theorem is applied to predict the occurrence of fracture, central bursting in extrusion or drawing. The occurrence of fracture appears to depend on the value of the parameters in the theorem; these parameters may be related to ductility or workability of the material in question. The upper bound technique is then applied to multi-stage extrusion of a carbon steel for which the values of the parameters are given with some assumptions. It is thus shown that the stage at which central bursting occurs agrees with experimental results and that it apparently depends on the extrusion condition.
Ein obere-schranken-konzept zur bestimmung von bruchvorgängen bei der umformung von metallen
Übersicht Es wird der Versuch unternommen, mit einer modifizierten Plastizitätstheorie für kompressible Werkstoffe den Obere-Schrankensatz bzw. das zweite Extremum-Prinzip herzuleiten, wenn die Normalgeschwindigkeit auf Sprungflächen unstetig ist. Diese Unstetigkeit wird als Indikator von Bruchvorgängen angesehen. Angewandt wird diese Hypothese auf die Vorhersage des Bruchs, d. h. der Materialtrennung im Kern beim Durchdrück- bzw. Durchziehverfahren. Das Auftreten von Brüchen erweist sich als abhängig von den Parametern des Ansatzes. Diese Parameter lassen sich mit der Umformbarkeit des Materials in Zusammenhang bringen. Angewandt wird das Obere-Schranken-Konzept auf das mehrstufige Durchpressen eines Kohlenstoff-Stahls, für den die Parameterwerte mit Hilfe einiger Parameterwerte festgelegt werden. Davon ausgehend wird gezeigt, daß die Preßstufe bei Materialtrennung mit experimentellen Ergebnissen übereinstimmt und offensichtlich von den Durchpreßbedingungen abhängt.
  相似文献   
75.
76.
Fe-pillared bentonite clay-based nanoadsorbent was synthesized by the thermal aging technique. The characteristics of the nanocomposite were detected by X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), thermal gravimetric analysis (TGA), scanning electron microscope (SEM), electron dispersive X-ray spectrometer (EDX), reflectance spectrophotometer (RS), and electromagnetic transition instrument (ETI). The TGA result demonstrated that the Fe particles generated on the clay surface can significantly improve the thermal stability of clay particles. The SEM and EDX results showed the presence of chemical elements of Fe, Al, and Si on the surface of clay. In this research, the successful synthesis of Fe-pillared clay nanocomposite can be concluded from the FTIR spectra.  相似文献   
77.
An efficient procedure for the synthesis of N‐alkyl‐2,5‐diaryl‐1,3‐dioxol‐4‐amines 3 via a one‐pot reaction of aromatic aldehydes 2 and alkyl isocyanides 1 at room temperature in good yields is described (Scheme 1, Table).  相似文献   
78.
Some new 4‐(aryl)‐2,6‐di‐2‐naphthylpyridines and 4‐(aryl)‐2,6‐di‐2‐thienylpyridines have been prepared through three‐component condensation of 2‐acetylnaphthalene or 2‐acetylthiophene, aromatic aldehydes, and ammonium acetate in presence of 1‐(4‐sulfonylbutyl) pyridinium hydrogensulfate [(CH2)4SO3HPy][HSO4], a Brønsted acidic ionic liquid as a green and reusable catalyst in solvent‐free conditions. Also some new 4,4'‐(1,4‐phenylene)‐bis‐(2,6‐di‐aryl pyridine) was prepared. J. Heterocyclic Chem., (2011).  相似文献   
79.
The synthesis of the 3'-deoxyapionucleoside 3'-triphosphates (apioNTPs) having the four natural nucleobases and their enzymatic incorporation into a DNA-DNA primer-template have been tried. Therminator DNA polymerase was shown to incorporate these apioNTPs effectively giving 43mer DNA-apioNA chimera.  相似文献   
80.
The solid‐state chiral optical properties of a 4‐(2‐arylethynyl)‐benzoic acid/amine supramolecular organic fluorophore can be controlled by changing the arylethynyl group of the achiral 4‐(2‐arylethynyl)‐benzoic acid component molecule rather than the chirality of the amine component molecule.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号