Determination of boron and hydrogen in materials for multicrystalline solar cell production with prompt gamma activation analysis

Journal of Radioanalytical and Nuclear Chemistry - For the optimization of the manufacturing process of multicrystalline silicon (mc-Si) for solar cells in order to reduce energy consumption and...     

Making Use of the Direct Process Residue: Synthesis of Bifunctional Monosilanes

The industrial production of monosilanes Me_nSiCl_4−n (n=1–3) through the Müller–Rochow Direct Process generates disilanes Me_nSi₂Cl_6−n (n=2–6) as unwanted byproducts (“Direct Process Residue”, DPR) by the thousands of tons annually, large quantities of which are usually disposed of by incineration. Herein we report a surprisingly facile and highly effective protocol for conversion of the DPR: hydrogenation with complex metal hydrides followed by Si−Si bond cleavage with HCl/ether solutions gives (mostly bifunctional) monosilanes in excellent yields. Competing side reactions are efficiently suppressed by the appropriate choice of reaction conditions.     

Spectroscopy of highly excited states in29Si

Particleγ-ray coincidences have been measured in the²⁸Si (d,pγ) reaction at 6.5 and 7 MeV bombarding energy, in the²⁶Mg (α,nγ) reaction at 12, 14 and 15 MeV, and in the²⁷A1 (τ,pγ) reaction at 9 MeV. Theγ-decay has been observed for all bound states of²⁹Si and for 56 unbound states up to 12,960 KeV excitation energy. Particleγ-ray angular correlations were measured in the²⁸Si (d,pγ) reaction at 6.5 MeV and in the²⁶Mg (α,nγ) reaction at 12 MeV. Spin (-parity) assignments or restrictions were obtained for nearly all bound states and some high-spin states above the binding energy. The assignment of mirror levels in²⁹Si and²⁹P has been extended to 8.2 MeV excitation energy. The excitation energies of 41 positive-parity states are reproduced by shell model calculations. The possible existence of aK ^π=5/2⁺ band with prolate deformation is discussed.     

Robust Adaptive Identification of Fuzzy Systems with Uncertain Data

This study presents a method of adaptive identification of parameters describing Sugeno fuzzy inference system in presence of bounded disturbances while maintaining the readability and interpretability of the fuzzy model during and after identification. This method do not require any a priori knowledge of a bound on the disturbance and noise and of a bound on the unknown parameters values. The method can be used for the robust and adaptive identification of slowly time varying nonlinear systems using fuzzy inference systems. The suggested method was used to build a fuzzy expert system that approximates the functional relationship between physical fitness and some of the measurable physiological parameters by their real measurements and opinion (human-experiences) of a medical expert.     

On automorphisms of infinite graphs with forbidden subgraphs

LexX be anm-connected infinite graph without subgraphs homeomorphic toKm, n, for somen, and let α be an automorphism ofX with at least one cycle of infinite length. We characterize the structure of α and use this characterization to extend a known result about orientation-preserving automorphisms of finite plane graphs to infinite plane graphs. In the last section we investigate the action of α on the ends ofX and show that α fixes at most two ends (Theorem 3.2).     

Multi-Faithful Spanning Trees of Infinite Graphs

For an end and a tree T of a graph G we denote respectively by m() and m _T () the maximum numbers of pairwise disjoint rays of G and T belonging to , and we define tm() := min{m _T(): T is a spanning tree of G}. In this paper we give partial answers — affirmative and negative ones — to the general problem of determining if, for a function f mapping every end of G to a cardinal f() such that tm() f() m(), there exists a spanning tree T of G such that m _T () = f() for every end of G.     

Unexpected dimerization of 1,3‐dimethyl‐5‐methylenebarbituric acid revealed by a combined experimental and computational study

A comparison of experimental and calculated ¹³C‐nuclear magnetic resonance chemical shifts reveals the molecular structure of a dimer that was obtained by an unexpected dimerization of 1,3‐dimethyl‐5‐methylenebarbituric acid. Furthermore, the puckering angle of the cyclobutane unit linking the six‐membered rings is discussed in detail. The influence of substituents on 1,3‐position of the cyclobutane ring on the puckering angle is demonstrated based on 1,1,3,3‐tetramethylcyclobutane. Copyright © 2015 John Wiley & Sons, Ltd.     

Conjugate gradient method for dual-dual mixed formulations

We deal with the iterative solution of linear systems arising from so-called dual-dual mixed finite element formulations. The linear systems are of a two-fold saddle point structure; they are indefinite and ill-conditioned. We define a special inner product that makes matrices of the two-fold saddle point structure, after a specific transformation, symmetric and positive definite. Therefore, the conjugate gradient method with this special inner product can be used as iterative solver. For a model problem, we propose a preconditioner which leads to a bounded number of CG-iterations. Numerical experiments for our model problem confirming the theoretical results are also reported.

     

Torelli Theorem for the Deligne–Hitchin Moduli Space

Fix integers g ≥ 3 and r ≥ 2, with r ≥ 3 if g = 3. Given a compact connected Riemann surface X of genus g, let denote the corresponding Deligne–Hitchin moduli space. We prove that the complex analytic space determines (up to an isomorphism) the unordered pair , where is the Riemann surface defined by the opposite almost complex structure on X.