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101.
Harries JR Sullivan JP Sternberg JB Obara S Suzuki T Hammond P Bozek J Berrah N Halka M Azuma Y 《Physical review letters》2003,90(13):133002
We report the first experimental measurements of the effect of an applied field on the photoexcitation and autoionization of doubly excited states of helium. Ground-state photoionization spectra have been measured in the region below the He+(N=2) threshold with static electric fields of up to 84.4 kV/cm across the interaction region. The results are compared to the theoretical calculations of Chung et al. [J. Phys. B 34, 165 (2001)]], which are the only calculations available in this regime. Transitions to several states in the N=2, n=6 manifold are assigned, and a wealth of new structure is observed. Our data show that many more series are mixed in by the field than those predicted by theory. 相似文献
102.
Nora Hartsfield 《Journal of Graph Theory》1987,11(4):537-538
A regular self-complementary graph is presented which has no complementing permutation consisting solely of cycles of length four. This answers one of Kotzig's questions. 相似文献
103.
Nora C. Hopkins Michael K. Kinyon 《Transactions of the American Mathematical Society》1999,351(11):4545-4559
Quadratic differential equations whose associated algebra has an automorphism of order two are studied. Under hypotheses that naturally generalize the cases where the even or odd part of the algebra is one dimensional, the following are examined: structure theory of the associated algebra (ideal structure, simplicity, solvability, and nilpotence), derivations and first integrals, trajectories given by derivations, and Floquet decompositions.
104.
Nora Ganter 《Advances in Mathematics》2006,205(1):84-133
We generalize the definition of orbifold elliptic genus and introduce orbifold genera of chromatic level h, using h-tuples rather than pairs of commuting elements. We show that our genera are in fact orbifold invariants, and we prove integrality results for them. If the genus arises from an H∞-map into the Morava-Lubin-Tate theory Eh, then we give a formula expressing the orbifold genus of the symmetric powers of a stably almost complex manifold M in terms of the genus of M itself. Our formula is the p-typical analogue of the Dijkgraaf-Moore-Verlinde-Verlinde formula for the orbifold elliptic genus [R. Dijkgraaf et al., Elliptic genera of symmetric products and second quantized strings Comm. Math. Phys. 185(1) (1997) 197-209]. It depends only on h and not on the genus. 相似文献
105.
Denys Naumenko Iuliia Naumenko Nora Grinceviciute Valentinas Snitka 《Journal of Raman spectroscopy : JRS》2015,46(1):94-99
In this work, a non‐covalent interaction of iron and metal‐free meso‐tetra (4‐sulfonatophenyl) porphines (FeTPPS and TPPS, respectively) with high‐quality single‐layer graphene is studied by Raman spectroscopy. Such a kind of graphene functionalization is promising for a development of novel optoelectronic devices and sensors. Our results show that the central metal atom of porphyrin macrocycle, iron particularly, plays an important role in the integrity of FeTPPS on graphene surface; however, the predicted Raman enhancement is not significant. The interaction of metal‐free TPPS with graphene leads to the deprotonation of TPPS molecules and higher Raman enhancement values. Moreover, initially deprotonated TPPS solutions after the adsorption onto the graphene surface demonstrate the appearance of new Raman bands and significantly enhanced Raman signals. We propose that a strong interaction between deprotonated TPPS and graphene is realized through pyrrole and desulfonated phenyl rings of closely located planar TPPS molecules on the graphene surface. The results show that both the protonation of porphyrin macrocycle and the existence of central metal atom are crucial for a formation of nanocomposites with defined electronic properties. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
106.
Etienne S. Gauthier Laura Abella Nora Hellou Benoît Darqui Elsa Caytan Thierry Roisnel Nicolas Vanthuyne Ludovic Favereau Monika Srebro‐Hooper J. A. Gareth Williams Jochen Autschbach Jeanne Crassous 《Angewandte Chemie (International ed. in English)》2020,59(22):8394-8400
The first enantiopure chiral‐at‐rhenium complexes of the form fac‐ReX(CO)3(:C^N) have been prepared, where :C^N is a helicene‐N‐heterocyclic carbene (NHC) ligand and X=Cl or I. These have complexes show strong changes in the emission characteristics, notably strongly enhanced phosphorescence lifetimes (reaching 0.7 ms) and increased circularly polarized emission (CPL) activity, as compared to their parent chiral models lacking the helicene unit. The halogen along with its position within the dissymmetric stereochemical environment strongly affect the photophysics of the complexes, particularly the phosphorescence quantum yield and lifetime. These results give fresh insight into fine tuning of photophysical and chiroptical properties of Re‐NHC systems. 相似文献
107.
Stefania Merighi Pier Andrea Borea Katia Varani Fabrizio Vincenzi Alessia Travagli Manuela Nigro Silvia Pasquini R. Rama Suresh Sung Won Kim Nora D. Volkow Kenneth A. Jacobson Stefania Gessi 《Molecules (Basel, Switzerland)》2022,27(9)
The A2A adenosine receptor is a protein belonging to a family of four GPCR adenosine receptors. It is involved in the regulation of several pathophysiological conditions in both the central nervous system and periphery. In the brain, its localization at pre- and postsynaptic level in striatum, cortex, hippocampus and its effects on glutamate release, microglia and astrocyte activation account for a crucial role in neurodegenerative diseases, including Alzheimer’s disease (AD). This ailment is considered the main form of dementia and is expected to exponentially increase in coming years. The pathological tracts of AD include amyloid peptide-β extracellular accumulation and tau hyperphosphorylation, causing neuronal cell death, cognitive deficit, and memory loss. Interestingly, in vitro and in vivo studies have demonstrated that A2A adenosine receptor antagonists may counteract each of these clinical signs, representing an important new strategy to fight a disease for which unfortunately only symptomatic drugs are available. This review offers a brief overview of the biological effects mediated by A2A adenosine receptors in AD animal and human studies and reports the state of the art of A2A adenosine receptor antagonists currently in clinical trials. As an original approach, it focuses on the crucial role of pharmacokinetics and ability to pass the blood–brain barrier in the discovery of new agents for treating CNS disorders. Considering that A2A receptor antagonist istradefylline is already commercially available for Parkinson’s disease treatment, if the proof of concept of these ligands in AD is confirmed and reinforced, it will be easier to offer a new hope for AD patients. 相似文献
108.
Isaac dos S. Nunes Carlos Schnorr Daniele Perondi Marcelo Godinho Julia C. Diel Lauren M. M. Machado Fabíola B. Dalla Nora Luis F. O. Silva Guilherme L. Dotto 《Molecules (Basel, Switzerland)》2022,27(21)
This work valorizes butiá pomace (Butia capitata) using pyrolysis to prepare CO2 adsorbents. Different fractions of the pomace, like fibers, endocarps, almonds, and deoiled almonds, were characterized and later pyrolyzed at 700 °C. Gas, bio-oil, and biochar fractions were collected and characterized. The results revealed that biochar, bio-oil, and gas yields depended on the type of pomace fraction (fibers, endocarps, almonds, and deoiled almonds). The higher biochar yield was obtained by endocarps (31.9%wt.). Furthermore, the gas fraction generated at 700 °C presented an H2 content higher than 80%vol regardless of the butiá fraction used as raw material. The biochars presented specific surface areas reaching 220.4 m2 g−1. Additionally, the endocarp-derived biochar presented a CO2 adsorption capacity of 66.43 mg g−1 at 25 °C and 1 bar, showing that this material could be an effective adsorbent to capture this greenhouse gas. Moreover, this capacity was maintained for 5 cycles. Biochars produced from butiá precursors without activation resulted in a higher surface area and better performance than some activated carbons reported in the literature. The results highlighted that pyrolysis could provide a green solution for butiá agro-industrial wastes, generating H2 and an adsorbent for CO2. 相似文献
109.
110.
Benjamin F. Hohlfeld Dr. Burkhard Gitter Dr. Christopher J. Kingsbury Dr. Keith J. Flanagan Dorika Steen Dr. Gerhard D. Wieland Prof. Dr. Nora Kulak Prof. Dr. Mathias O. Senge Dr. Arno Wiehe 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(21):6440-6459
The generation of bio-targetable photosensitizers is of utmost importance to the emerging field of photodynamic therapy and antimicrobial (photo-)therapy. A synthetic strategy is presented in which chelating dipyrrin moieties are used to enhance the known photoactivity of iridium(III) metal complexes. Formed complexes can thus be functionalized in a facile manner with a range of targeting groups at their chemically active reaction sites. Dipyrrins with N- and O-substituents afforded (dipy)iridium(III) complexes via complexation with the respective Cp*-iridium(III) and ppy-iridium(III) precursors (dipy=dipyrrinato, Cp*=pentamethyl-η5-cyclopentadienyl, ppy=2-phenylpyridyl). Similarly, electron-deficient [IrIII(dipy)(ppy)2] complexes could be used for post-functionalization, forming alkenyl, alkynyl and glyco-appended iridium(III) complexes. The phototoxic activity of these complexes has been assessed in cellular and bacterial assays with and without light; the [IrIII(Cl)(Cp*)(dipy)] complexes and the glyco-substituted iridium(III) complexes showing particular promise as photomedicine candidates. Representative crystal structures of the complexes are also presented. 相似文献