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491.
We investigated temperature dependent optical spectra of the one-dimensional chain compound Sr2CuO3. The charge transfer transition polarized along the chain direction shows a strongly asymmetric line shape as expected in one-dimensional extended Hubbard model. At low temperature, the charge transfer peak shows a large blueshift and reveals additional sharp peaks at the gap. Even though many spectroscopic studies suggest that this material cannot have a bound exciton based on the one-dimensional extended Hubbard model, we attribute the additional sharp peaks to excitons, which come to exist due to the long-range Coulomb interaction. 相似文献
492.
Su Jung Noh 《Journal of magnetism and magnetic materials》2010,322(21):3601-3604
We report micromagnetic modeling results of current induced domain wall (DW) motion in magnetic devices with perpendicular magnetic anisotropy by solving the Landau-Lifschitz-Gilbert equation including adiabatic and non-adiabatic terms. A nanostripe model system with dimensions of 500 nm (L)×25 nm (W)×5 nm (H) was selected for calculating the DW motion and its width, as a function of various parameters such as non-adiabatic contribution, anisotropy constant (Ku), saturation magnetization (Ms), and temperature (T). The DW velocity was found to increase when the values of Ku and T were increased and the Ms value decreased. In addition, a reduction of the domain wall width could be achieved by increasing Ku and lowering Ms values regardless of the non-adiabatic constant value. 相似文献
493.
By assuming that a dark component (dark energy) in the universe strictly obeys the holographic principle, that is, its entropy is one fourth of the apparent horizon, we find that the existence of the other dark component (dark matter) is compulsory, as a compensation of dark energy, based on the first law of thermodynamics. By using the method of dynamical system analysis, we find that there exists a stable dark energy-dark matter scaling solution at late time, which is helpful to solve the coincidence problem. For reasonable parameters, the deceleration parameter is well consistent with current observations. 相似文献
494.
Recently, with the rise of deep learning, text classification techniques have developed rapidly. However, the existing work usually takes the entire text as the modeling object and pays less attention to the hierarchical structure within the text, ignoring the internal connection between the upper and lower sentences. To address these issues, this paper proposes a Bert-based hierarchical graph attention network model (BHGAttN) based on a large-scale pretrained model and graph attention network to model the hierarchical relationship of texts. During modeling, the semantic features are enhanced by the output of the intermediate layer of BERT, and the multilevel hierarchical graph network corresponding to each layer of BERT is constructed by using the dependencies between the whole sentence and the subsentence. This model pays attention to the layer-by-layer semantic information and the hierarchical relationship within the text. The experimental results show that the BHGAttN model exhibits significant competitive advantages compared with the current state-of-the-art baseline models. 相似文献
495.
Young Ji Son Hungu Kang Sicheon Seong Seulki Han Nam-Suk Lee Jaegeun Noh 《Molecules (Basel, Switzerland)》2022,27(17)
To probe the effects of deposition temperature on the formation and structural order of self-assembled monolayers (SAMs) on Au(111) prepared by vapor deposition of 2-(2-methoxyethoxy)ethanethiol (CH3O(CH2)2O(CH2)2SH, EG2) for 24 h, we examined the surface structure and electrochemical behavior of the resulting EG2 SAMs using scanning tunneling microscopy (STM) and cyclic voltammetry (CV). STM observations clearly revealed that EG2 SAMs vapor-deposited on Au(111) at 298 K were composed of a disordered phase on the entire Au surface, whereas those formed at 323 K showed improved structural order, showing a mixed phase of ordered and disordered phases. Moreover, at 348 K, uniform and highly ordered EG2 SAMs on Au(111) were formed with a (2 × 3√3) packing structure. CV measurements showed sharp reductive desorption (RD) peaks at −0.818, −0.861, and −0.880 V for EG2 SAM-modified Au electrodes formed at 298, 323, and 348 K, respectively. More negative potential shifts of RD peaks with increasing deposition temperature are attributed to an increase in van der Waals interactions between EG2 molecular backbones resulting from the improved structural quality of EG2 SAMs. Our results obtained herein provide new insights into the formation and thermally driven structural order of oligo(ethylene glycol)-terminated SAMs vapor-deposited on Au(111). 相似文献
496.
Gi Hoon Ko Chanyoung Maeng Haneal Jeong Sang Hoon Han Gi Uk Han Kyungsup Lee Hee Chan Noh Prof. Dr. Phil Ho Lee 《化学:亚洲杂志》2021,16(20):3179-3187
An efficient synthetic method for structurally various isochromenoindolones has been demonstrated through Rh(III)-catalyzed C−H activation followed by a cyclization reaction of N-methoxyarylamides with 3-diazooxindoles. The sequential reaction involves the streamlined formation of C−C and C−O bonds in one pot. The present method provides a broad range of isochromenoindolones as a new privileged scaffold in moderate to good yields with the release of methoxyamine and molecular nitrogen and has the benefits of a broad substrate scope and good functional group tolerance. 相似文献
497.
Dr. Ying Wang Ara Cho Dr. Guangri Jia Prof. Xiaoqiang Cui Junhyeop Shin Prof. Inho Nam Kyung-Jong Noh Byoung Joon Park Rui Huang Prof. Jeong Woo Han 《Angewandte Chemie (International ed. in English)》2023,62(15):e202300119
Single-atom nanozymes (SAzymes) are promising in next-generation nanozymes, nevertheless, how to rationally modulate the microenvironment of SAzymes with controllable multi-enzyme properties is still challenging. Herein, we systematically investigate the relationship between atomic configuration and multi-enzymatic performances. The constructed MnSA−N3-coordinated SAzymes (MnSA−N3−C) exhibits much more remarkable oxidase-, peroxidase-, and glutathione oxidase-like activities than that of MnSA−N4−C. Based on experimental and theoretical results, these multi-enzyme-like behaviors are highly dependent on the coordination number of single atomic Mn sites by local charge polarization. As a consequence, a series of colorimetric biosensing platforms based on MnSA−N3−C SAzymes is successfully built for specific recognition of biological molecules. These findings provide atomic-level insight into the microenvironment of nanozymes, promoting rational design of other demanding biocatalysts. 相似文献
498.
499.
Dong-ho Lee Keun-byung Yoon Eok-hyung Lee Seok-kyun Noh Chul-soo Lee Wan-soo Huh 《Macromolecular rapid communications》1996,17(5):325-331
The disiloxane-bridged zirconocene complexes, tetramethyldisiloxanediylbis (cyclopentadienyl)zirconium dichloride and tetramethyldisiloxanediylbis(cyclopentadienyl) dimethylzirconium initiate the homopolymerization of ethene as well as the copolymerization of ethene and α-olefin with a modified methylaluminoxane as cocatalyst. The catalyst systems give resonable activity but the molecular weight of polyethene decreases drastically with increasing polymerization temperature. 相似文献
500.