Effect of mechanical activation on the hydrogen reduction kinetics of magnetite concentrate

The combined thermal analysis techniques thermal expansion: and differential scanning calorimetry were used to characterize various phase transitions that exist in the solid solutions of PbZr_1?xSn_xO₃. Using thermodynamic quantities, i.e., thermal expansion and specific heat to distinguish first-order transitions from second-order ones, we demonstrate that some perovskite antiferroelectrics can exhibit continuous transition at their Curie temperature T _C. We observed such a transition in antiferroelectric crystals of solid solutions based on PbZrO₃. Although pure PbZrO₃ is a classical example of antiferroelectric crystal with a first-order transition at T _C, the solid solutions of PbZr_1?xSn_xO₃ in the range of composition of x > 0.25 seem to exhibit a second-order phase transition.     

Chemical Compounds and Biologic Activities: A Review of Cedrela Genus

The genus Cedrela P. Browne, which belongs to the Meliaceae family, has eighteen species. Trees of this genus are of economic interest due to wood quality, as well as being the focus of studies because of relevant biologic activities as in other Meliaceae species. These activities are mainly related to limonoids, a characteristic class of compounds in this family. Therefore, the aim of this review is to perform a survey of the citations in the literature on the Cedrela genus species. Articles were found on quantitative and qualitative phytochemical studies of the Cedrela species, revealing the chemical compounds identified, such as aliphatics acid and alcohol, flavonoids, tocopherol, monoterpenes, sesquiterpenes, triterpenes, cycloartanes, steroids, and limonoids. Although some activities were tested, the majority of studies focused on the insecticidal, antifeedant, or insect growth inhibitor activities of this genus. Nonetheless, the most promising activities were related to their antimalarial and antitripanocidal effects, although further investigations are still needed.     

A local monotonicity formula for an inhomogenous singular perturbation problem and applications

In this paper we prove a local monotonicity formula for solutions to an inhomogeneous singularly perturbed diffusion problem of interest in combustion. This type of monotonicity formula has proved to be very useful for the study of the regularity of limits u of solutions of the singular perturbation problem and of ∂{u > 0}, in the global homogeneous case. As a consequence of this formula we prove that u has an asymptotic development at every point in ∂{u > 0} where there is a nonhorizontal tangent ball. These kind of developments have been essential for the proof of the regularity of ∂{u > 0} for Bernoulli and Stefan free boundary problems. We also present applications of our results to the study of the regularity of ∂{u > 0} in the stationary case including, in particular, its regularity in the case of energy minimizers. We present as well a regularity result for traveling waves of a combustion model that relies on our monotonicity formula and its consequences.The fact that our results hold for the inhomogeneous problem allows a very wide applicability. Indeed, they may be applied to problems with nonlocal diffusion and/or transport. The research of the authors was partially supported by Fundación Antorchas Project 13900-5, Universidad de Buenos Aires grant X052, ANPCyT PICT No 03-13719, CONICET PIP 5478. The authors are members of CONICET.     

Antihypertensive Activity of the Alkaloid Aspidocarpine in Normotensive Wistar Rats

The alkaloid Aspidocarpine was isolated from the bark of Aspidosperma desmanthum. Its structure was elucidated by the spectral data of ¹H and ¹³C-NMR (1D and 2D) and high-resolution mass spectrometry (HRESIMS). The antihypertensive activity was investigated by intravenous infusion in Wistar rats. This alkaloid significantly reduced (p < 0.05) the systolic, median, and diastolic blood pressures of rodents, without causing motor incoordination and imbalance in the rotarod test. The results indicate that the alkaloid Aspidocarpine exerts its antihypertensive activity without causing sedation or the impairment of motor functions.     

The Energetics of Surfactant‐Templating of Zeolites

Mesoporosity can be conveniently introduced into zeolites by treating them in basic surfactant solutions. The apparent activation energy involved in the formation of mesopores in USY by surfactant‐templating was determined using a combination of in situ synchrotron X‐ray diffraction and ex situ gas adsorption. Additionally, techniques such as pH measurement and thermogravimetry/differential thermal analysis were employed to determine OH^? evolution and cetyltrimethylammonium ion (CTA⁺) uptake during the development of mesoporosity, thereby providing information about the different steps involved. The combination of both in situ and ex situ techniques has allowed determination of the apparent activation energies of the different processes involved in the mesostructuring of USY zeolites for the first time. Apparent activation energies are of the same order of magnitude (30–65 kJ mol^?1) as those involved in the crystallization of zeolites. Hence, important mechanistic insight into the surfactant‐templating method was obtained.     

The importance of centralities in dark network value chains

This paper introduces three novel centrality measures based on the nodes’ role in the operation of a joint task, i.e., their position in a criminal network value chain. For this, we consider networks where nodes have attributes describing their “capabilities” or “colors”, i.e., the possible roles they may play in a value chain. A value chain here is understood as a series of tasks to be performed in a specific order, each requiring a specific capability. The first centrality notion measures how many value chain instances a given node participates in. The other two assess the costs of replacing a node in the value chain in case the given node is no longer available to perform the task. The first of them considers the direct distance (shortest path length) between the node in question and its nearest replacement, while the second evaluates the actual replacement process, assuming that preceding and following nodes in the network should each be able to find and contact the replacement. In this report, we demonstrate the properties of the new centrality measures using a few toy examples and compare them to classic centralities, such as betweenness, closeness and degree centrality. We also apply the new measures to randomly colored empirical networks. We find that the newly introduced centralities differ sufficiently from the classic measures, pointing towards different aspects of the network. Our results also pinpoint the difference between having a replacement node in the network and being able to find one. This is the reason why “introduction distance” often has a noticeable correlation with betweenness. Our studies show that projecting value chains over networks may significantly alter the nodes’ perceived importance. These insights might have important implications for the way law enforcement or intelligence agencies look at the effectiveness of dark network disruption strategies over time.     

One-pot direct conversion of 2,3-epoxy alcohols into enantiomerically pure 4-hydroxy-4,5-dihydroisoxazole 2-oxides

[structure: see text]. A new methodology for the one-pot direct conversion of 2,3-epoxy alcohols into enantiomerically pure 4-hydroxy-4,5-dihydroisoxazole 2-oxides 1 has been found. The reaction works at room temperature and can be run at the 5-10 g scale. The mixture of 4,5-cis and 4,5-trans isomers obtained can be separated as such or as the bis-TDS ethers. A preliminary example of reductive cleavage of 1 to the corresponding amino polyol is also reported.     

CeCl(3) x 7H(2)O-NaI catalyzed hydrooxacyclization of unsaturated 3-hydroxy esters

[reaction: see text] Cerium(III) chloride heptahydrate and sodium iodide in boiling acetonitrile promote cyclization of 3-hydroxyalkenoic acids esters giving 5-substituted tetrahydrofuranacetic acid esters and 6-substituted tetrahydropyranacetic acid esters in fair to good yield and with complete retention of the absolute configuration of the starting 3-hydroxy ester.     

A rheological modelling and microscopic analysis of bigels

Bigels are two-phase systems in which each phase (organic or aqueous) is structured using a specific gelator. Currently, these systems are widely investigated, mainly as matrices for controlled drug delivery, because they possess the advantages of both organogels and hydrogels and are very stable owing to the structuration of the dispersing phase. A deeper knowledge of the relationship between macroscopic properties and microscopic parameters seems necessary to aim at designing materials with specific rheological properties and suitable for specific uses. From a rheological point of view, bigels can be considered as composite materials in which a structured system (organogel or hydrogel, according to the desired use) is dispersed in a gelled continuous phase. In the present paper, a number of rheological models, already proposed in literature for composite systems, were used to relate the bigel complex modulus to the rheological properties of dispersed and continuous phase and to their volumetric ratio. It was observed that these models are not able to describe properly bigel behaviour, probably owing to some theoretical assumptions such as the uniform distribution of spherical particles. An empirical modification of a literature model, proposed to take into account some peculiarities of bigels, yields an improvement of fitting even if further investigations are necessary to better understand the effects of particle size distribution and morphology on observed properties.     

A two phase elliptic singular perturbation problem with a forcing term

We study the following two phase elliptic singular perturbation problem:

Δu^ε=β_ε(u^ε)+f^ε,