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51.
Kesra Hantawong William S. Murphy Noel Russell Derek R. Boyd 《Tetrahedron letters》1984,25(9):999-1000
The epimeric indenones (3) and (4) are readily synthesised and rapidly formed by treating bis(p-methoxyphenylcyclopropyl) ketone (2) with stannic chloride in nitromethane. The structure of (3) was determined by X-ray crystallography and that of (4) by NOEDS. 相似文献
52.
The kinetics of acetone evaporation from films obtained by casting solutions of cellulose diacetate-acetone-water-inorganic additive have been analysed. Three successive regimes of evaporation have been identified. The first two are exponential and end, respectively, at critical times t1 and t2. Casting solution compositions have been determined both at the instant of phase separation (cloud point) and upon complete gelation. Also, the period of evaporation required to produce total film opacification has been measured for certain systems. These measurements have shown that time t1 corresponds to polymer precipitation at the film surface, and that time t2 corresponds to complete gelation of the medium. The results illustrate the effects of film thickness, casting temperature and “swelling” or “gelling” characteristics of the inorganic additive on times t1 and t2. 相似文献
53.
Noel D Uri 《Applied Mathematical Modelling》1982,6(2):119-123
This paper endeavours to estimate the cummulative level of discovery and production of crude oil in the United States where the importance of price and technological change is considered. Two separate functional specifications for the cumulative level are hypothesized and estimated. The results suggest that between 170 and 180 billion barrels will be ultimately recoverable of which 117 billion barrels have been produced through the end of 1989. 相似文献
54.
Microwave spectra of 1,3-dithiole-2-one show that the molecule has a planar equilibrium conformation. IR and Raman spectra are analysed to give the normal modes of vibration. 相似文献
55.
A. Fraefel J. Seibl Noel W. Davies John C. Bignall Ross W. Lincolne Jaime Espinosa Gonzalez Hans-Friedrich Grützmacher C. Lifshitz M. Goldenberg Y. Malinovich M. Peres Gerhard Holzmann Gernot Frenking Bernd Steiner Gary Caldwell John E. Bartmess Klaus Eckart Helmut Schwarz Shinjiro Kobayashi Hiroshi Taniguchi Helmut Schwarz Klaus Eckart Lester C. E. Taylor 《Journal of mass spectrometry : JMS》1982,17(9):448-460
56.
57.
Geraint I. L. Jones David G. Lister Noel L. Owen Michael C. L. Gerry Paolo Palmieri 《Journal of Molecular Spectroscopy》1976,60(1-3)
The microwave spectrum (41-10 GHz) and the infrared spectrum (4000-50 cm−1) of methyl thiolformate have been obtained and analyzed. The spectra are consistent with a single molecular conformation having a planar array of heavy atoms and with the alkyl group cis to the carbonyl group. The measured rotational constants are: A, 11042.22 MHz; B, 5118.27 MHz; C, 3562.03 MHz (κ = −0.5839). No internal rotation doublets were observed in the microwave spectrum for the ground vibrational state, which implies that the barrier hindering internal rotation of the methyl group is either much larger or much smaller than the corresponding value for methyl formate. If the former is true then a lower limit of 10.5 kJ mol−1 may be placed on the barrier height.The dipole moment of methyl thiolformate was measured using the Stark effect to be 1.58 ± 0.05 Debyes (μA = 1.52 D; μB = 0.43 D) for the vapor, and for dilute solutions in benzene at 295 K the value of 1.6 ± 0.1 D was found from capacitance measurements.SCF computations using minimal basis sets of STO/3G atomic orbitals and extended basis sets of STO/4.31G atomic orbitals have been carried out for methyl thiolformate and methyl formate. Energy differences between rotational isomers and estimates of barrier heights are given together with the calculated dipole moments. 相似文献
58.
59.
C. Allan Guymon Erik N. Hogga David M. Walba Noel A. Clark Christopher N. Bowman 《Liquid crystals》1995,19(6):719-727
The effects of adding a diacrylate monomer or its polymerized network to a ferroelectric liquid crystal have been characterized. The monomer lowers the temperatures of transition to the more ordered phases, whereas the polymer network phase separates into polymer rich and LC rich phases and has little effect on the LC phase behaviour. Ferroelectric polarization decreases comparably in both monomer and networked systems. As the network concentration increases, the size of LC domains decreases considerably. With low concentrations of polymer and, thus large LC domains, optical response and tilt angle remain fairly independent of polymer concentration, but as the polymer concentration increases, switching speed and tilt angle decrease dramatically. Polymerization rate maxima increase with monomer concentration until saturation of monomer in the liquid crystal is reached. The rate maxima then decrease as monomer must diffuse from monomer rich droplets. Double bond conversion during the polymerization is comparable for all monomer concentrations below 50 per cent. 相似文献
60.
Poly(5-hydroxy-1,4-naphthoquinone-co-5-hydroxy-3-thioacetic acid-1,4-naphthoquinone)-modified electrode is used for the direct electrochemical detection of oligonucleotide hybridization. The polymer film presents well-defined electroactivity in the cathodic potential domain (between 0 and -0.8 V/SCE), due to the quinone group embedded into the polymer structure. The detection can be performed simply by square wave voltammetry. This sensor is a "signal-on" device and works with different oligonucleotide lengths, from 10 to 30 bases. Quantitative results from fluorescence are consistent with electrochemical data. It is confirmed that the signal increase in square wave voltammetry is unambiguously due to hybridization. The biosensor presents a detection limit of target of ca. 25 nM and is highly selective as it can discriminate single mismatch base. 相似文献