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71.
Taniguchi J Yamaguchi A Ishimoto H Ikegami H Matsushita T Wada N Gatica SM Cole MW Ancilotto F Inagaki S Fukushima Y 《Physical review letters》2005,94(6):065301
Heat capacity measurements have been made down to 5 mK for 3He fluid films adsorbed in one-dimensional (1D) nanometer-scale pores, 28 A in diameter, preplated with 4He of 1.47 atomic layers. At low 3He density, the heat capacity shows a density-dependent, Schottky-like peak near 150 mK asymptoting to the value corresponding to a 2D Boltzmann gas at high temperatures. The peak behavior is attributed to the crossover from a 2D gas to a 1D state at low temperatures. The degenerate state of the 1D 3He fluid is indicated by a predominantly linear temperature dependence below about 30 mK. 相似文献
72.
We study a square-lattice three-state Potts antiferromagnet with a staggered polarization field at finite temperature. Numerically treating the transfer matrices, we determine two phase boundaries separating the model-parameter space into three parts. We confirm that one of them belongs to the ferromagnetic three-state Potts criticality, which is in accord with a recent prediction, and another to the Ising-type; these are both corresponding to the massless renormalization-group flows stemming from the Gaussian fixed points. We also discuss a field theory to describe the latter Ising transition. 相似文献
73.
An equilateral-triangular shape of three alpha clusters surrounded by excess neutrons is suggested for 14C, based on the molecular-orbit model. It is found that the attractive interaction between an excess neutron and an alpha particle stabilizes the K(pi)=0(+) and 3(-) rotational bands, which demonstrates an equilateral-triangular symmetry. This K(pi)=3(-) band at 3 MeV below the 10Be+alpha threshold energy corresponds to the experimentally observed band built on top of the second 3(-) state. A positive-parity rotational band (0(+), 2(+), 4(+)) arises similarly. These two bands suggest a molecular 3-alpha structure stabilized by the excess neutrons and can be viewed as a realization of the alpha crystallization in the dilute nuclear medium. 相似文献
74.
Effects of disorder on the two competing phases, i.e., the ferromagnetic metal and the commensurate charge/lattice ordered insulator, are studied by Monte Carlo simulation. The disorder suppresses the charge/lattice ordering more strongly than the ferromagnetic order, driving the commensurate insulator to the ferromagnetic metal near the phase boundary in the pure case. Above the ferromagnetic transition temperature, on the contrary, the disorder makes the system more insulating, which might cause an enhanced colossal magnetoresistance as observed in the half-doped or Cr-substituted manganites. No indication of the percolation or the cluster formation is found, and there remains the charge/lattice fluctuations instead which are enhanced toward the transition temperature. 相似文献
75.
Alexander Čeklovský Juraj Bujdák Adriana Czímerová Nobuo Iyi 《Central European Journal of Physics》2007,5(2):236-243
Tetracationic porphyrin dyes TMPyP and ZnPyP were intercalated into hydrophobized layered silicate films of three smectites.
The smectites represented the layered silicate specimens of high (Fluorohectorite, Corning; FHT), medium (Kunipia F montmorillonite;
KF) and low layer charge (Laponite, Laporte; LAP). The molecular orientations of the dye cations were studied by means of
linearly-polarized ultraviolet-visible (UV-VIS) spectroscopy. The spectral analysis and consequent calculations of tilting
angles of the transition moments at the wavelengths of Soret band transitions were in the range of 25°-35°. The determined
angles indicated molecular orientation of the dye cations being almost parallel to the surface of the silicates. Slightly
higher values (above 35°), determined for a FHT film, indicated either a slightly tilted orientation of the dye cations or
the change of molecular comformation after the intercalation of the dye.
Presented at 5-th International Conference Solid State Surfaces and Interfaces, November 19–24, 2006, Smolenice Castle, Slovakia 相似文献
76.
We have developed the mechanically controllable break junction setup with an electrochemical cell (EC-MCBJ) to measure the electric conductance of metal nanowires under electrochemical potential control. The electric conductance of Au nanowires was investigated in 0.1 M Na2SO4 solution using EC-MCBJ. The conductance of the Au nanowires was quantized in units of G0 (=2e2/h), showing clear features in the conductance histogram. The atomic contact with a specific conductance value was kept for >5 s, indicating the relatively high stability of the present EC-MCBJ system. 相似文献
77.
Kuniharu Fujii Satoshi Kera Mika Oiwa Koji K. Okudaira Kazuyuki Sakamoto Nobuo Ueno 《Surface science》2007,601(18):3765-3768
We have investigated the relation between the intramolecular vibrational modes of pentacene and the charge redistribution at the pentacene-graphite interface by using high-resolution electron-energy-loss-spectroscopy. The three main vibrational peaks shift to lower energies as the pentacene film thickness decreases. In order to discuss this energy shift, we have calculated the vibrational energies of a free pentacene molecule by changing its charge state. We have also calculated the vibrational energies of a pentacene molecule adsorbed on a graphite sheet by changing the pentacene-graphite distance. Taking the experimental and calculation results into account, we conclude that the observed energy shifts result from an intramolecular charge redistribution. The present results indicate that the effect of an intramolecular charge redistribution is essential to discuss the origin of an energy shift observed in a vibrational study of an organic molecule/substrate interface. 相似文献
78.
79.
Yasutaka Shimada Kazumasa Usuda Hirokazu Okabe Tsuguru Suzuki Kazutsugu Matsumoto 《Tetrahedron: Asymmetry》2009,20(24):2802-2808
The deracemization of 1,2-diol monotosylate derivatives is achieved by the sequential combination of enzymatic hydrolysis and Mitsunobu inversion using a polymer-bound triphenylphosphine. After the lipase-catalysed hydrolysis of the racemic 2-acetoxyhexyl tosylate, the subsequent Mitsunobu reaction without separation causes an inversion of the resulting (R)-alcohol to give the (S)-enantiomer of the acetate as a single product. In particular, the reaction using the polymer-bound triphenylphosphine also proceeds smoothly, and the product is easily separated by filtration from the polymer-bound reagent and its by-products. This deracemization process is applicable to the preparation of several optically active 1,2-diol monotosylates. 相似文献
80.