全文获取类型
收费全文 | 857篇 |
免费 | 13篇 |
国内免费 | 2篇 |
专业分类
化学 | 629篇 |
晶体学 | 7篇 |
力学 | 6篇 |
数学 | 101篇 |
物理学 | 129篇 |
出版年
2021年 | 5篇 |
2019年 | 9篇 |
2018年 | 10篇 |
2017年 | 5篇 |
2016年 | 12篇 |
2015年 | 7篇 |
2014年 | 10篇 |
2013年 | 25篇 |
2012年 | 27篇 |
2011年 | 33篇 |
2010年 | 21篇 |
2009年 | 30篇 |
2008年 | 64篇 |
2007年 | 40篇 |
2006年 | 46篇 |
2005年 | 51篇 |
2004年 | 47篇 |
2003年 | 42篇 |
2002年 | 41篇 |
2001年 | 14篇 |
2000年 | 22篇 |
1999年 | 16篇 |
1998年 | 11篇 |
1997年 | 18篇 |
1996年 | 14篇 |
1995年 | 9篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 11篇 |
1989年 | 5篇 |
1987年 | 4篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 31篇 |
1983年 | 7篇 |
1982年 | 19篇 |
1981年 | 14篇 |
1980年 | 11篇 |
1979年 | 14篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1969年 | 4篇 |
1968年 | 6篇 |
1967年 | 6篇 |
排序方式: 共有872条查询结果,搜索用时 31 毫秒
71.
Tomoaki Matsugi Shin‐Ichi Kojoh Nobuo Kawahara Shingo Matsuo Hideyuki Kaneko Norio Kashiwa 《Journal of polymer science. Part A, Polymer chemistry》2003,41(24):3965-3973
Polyethylene‐block‐poly(methyl methacrylate) (PE‐b‐PMMA) was successfully synthesized through the combination of metallocene catalysis with living radical polymerization. Terminally hydroxylated polyethylene, prepared by ethylene/allyl alcohol copolymerization with a specific zirconium metallocene/methylaluminoxane/triethylaluminum catalyst system, was treated with 2‐bromoisobutyryl bromide to produce terminally esterified polyethylene (PE‐Br). With the resulting PE‐Br as an initiator for transition‐metal‐mediated living radical polymerization, methyl methacrylate polymerization was subsequently performed with CuBr or RuCl2(PPh3)3 as a catalyst. Then, PE‐b‐PMMA block copolymers of different poly(methyl methacrylate) (PMMA) contents were prepared. Transmission electron microscopy of the obtained block copolymers revealed unique morphological features that depended on the content of the PMMA segment. The block copolymer possessing 75 wt % PMMA contained 50–100‐nm spherical polyethylene lamellae uniformly dispersed in the PMMA matrix. Moreover, the PE‐b‐PMMA block copolymers effectively compatibilized homopolyethylene and homo‐PMMA at a nanometer level. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3965–3973, 2003 相似文献
72.
73.
Kakuta H Hirahara T Matsuda I Nagao T Hasegawa S Ueno N Sakamoto K 《Physical review letters》2007,98(24):247601
We report the energy dispersions of the highest occupied molecular orbitals (HOMO)-derived bands of a pentacene (Pn) thin film, whose in-plane structure resembles closely that of the ab plane of a low-density bulk Pn phase. Our present photoemission result indicates that the overlap of the pi-orbitals of adjacent Pn molecules is larger than what was expected from theoretical calculations. Further, of the two HOMO-derived bands, the large dispersion width of the band with higher binding energy suggests that this one mainly contributes to the bandlike charge transport in a Pn crystal. 相似文献
74.
75.
A novel amphiphilic Tb(3+) complex (TbL(+)) having anionic bis(pyridine) arms and a hydrophobic alkyl chain is developed. It spontaneously self-assembles in water and gives stable vesicles that show sensitized luminescence of Tb(3+) ions at neutral pH. This TbL(+) complex is designed to show coordinative unsaturation, i.e., water molecules occupy some of the first coordination spheres and are replaceable upon binding of phosphate ions. These features render TbL(+) self-assembling receptor molecules which show increase in the luminescence intensity upon binding of nucleotides. Upon addition of adenosine triphosphate (ATP), significant amplification of luminescent intensity was observed. On the other hand, ADP showed moderately increased luminescence and almost no enhancement was observed for AMP. Very interestingly, the increase in luminescence intensity observed for ATP and ADP showed sigmoidal dependence on the concentration of added nucleotides. It indicates positive cooperative binding of these nucleotides to TbL(+) complexes preorganized on the vesicle surface. Self-assembly of amphiphilic Tb(3+) receptor complexes provides nanointerfaces which selectively convert and amplify molecular information of high energy phosphates linked by phosphoanhydride bonds into luminescence intensity changes. 相似文献
76.
We study the survival probability and the growth rate for branching random walks in random environment (BRWRE). The particles
perform simple symmetric random walks on the d-dimensional integer lattice, while at each time unit, they split into independent copies according to time–space i.i.d. offspring
distributions. The BRWRE is naturally associated with the directed polymers in random environment (DPRE), for which the quantity
called the free energy is well studied. We discuss the survival probability (both global and local) for BRWRE and give a criterion
for its positivity in terms of the free energy of the associated DPRE. We also show that the global growth rate for the number
of particles in BRWRE is given by the free energy of the associated DPRE, though the local growth rate is given by the directional
free energy. 相似文献
77.
Ono Y Minami A Noike M Higuchi Y Toyomasu T Sassa T Kato N Dairi T 《Journal of the American Chemical Society》2011,133(8):2548-2555
Fusicoccin A and cotylenin A are structurally related diterpene glucosides and show a phytohormone-like activity. However, only cotylenin A induces the differentiation of human myeloid leukemia cells. Since the cotylenin A producer lost its ability to proliferate during preservation, a study on the relationship between structure and activity was carried out and a modified fusicoccin A with hydroxyl group at the 3-position showed a similar biological activity with that of cotylenin A. We then searched for an enzyme source that catalyzes the introduction of a hydroxyl group into the 3-position and found that brassicicene C, which is structurally related to fusicoccin A with hydroxyl group at the 3-position, was produced by Alternaria brassicicola ATCC96836. We recently cloned a brassicicene C biosynthetic gene cluster including the genes encoding fusicocca-2,10(14)-diene synthase and two cytochrome P450s, which were responsible for the formation of fusicocca-2,10(14)-diene-8β,16-diol. In this study, we report that a α-ketoglutarate dependent dioxygenase, the gene coding for which was located in the cluster, catalyzed a hydroxylation at the 3-position of fusicocca-2,10(14)-diene-8β,16-diol. On the other hand, a α-ketoglutarate-dependent dioxygenase, which had been identified in a fusicoccin A biosynthetic gene cluster, catalyzed the 16-oxidation of fusicocca-2,10(14)-diene-8β,16-diol to yield an aldehyde (8β-hydroxyfusicocca-1,10(14)-dien-16-al), although both dioxygenases had 51% amino acid sequence identity. These findings suggested that the dioxygenases played critical roles for the formation of the fusicoccin A-type and cotylenin A-/brassicicene C-type aglycons. Moreover, we showed that short-chain dehydrogenase/reductase located in the fusicoccin A biosynthetic gene cluster catalyzed the reduction of the aldehyde to yield fusicocca-1,10(14)-diene-8β,16-diol. 相似文献
78.
Noriaki Nishiguchi Takafumi Kinuta Yoko Nakano Dr. Takunori Harada Dr. Nobuo Tajima Tomohiro Sato Prof. Dr. Michiya Fujiki Prof. Dr. Reiko Kuroda Prof. Dr. Yoshio Matsubara Dr. Yoshitane Imai 《化学:亚洲杂志》2011,6(4):1092-1098
The solid‐state chiral optical properties of a 4‐(2‐arylethynyl)‐benzoic acid/amine supramolecular organic fluorophore can be controlled by changing the arylethynyl group of the achiral 4‐(2‐arylethynyl)‐benzoic acid component molecule rather than the chirality of the amine component molecule. 相似文献
79.
In systematic research on a series of new nonlinear organic materials, we found that Bis (4-nitrophenoxy) methane (BNPM) showed a large intensity of second harmonic light, which was 4.4 times as large as that of urea crystal by powder technique and easily crystallized from a solution. The crystal structure of BNPM, obtained by the X-ray diffraction method, was orthorhombic, space group P21212 (point group 222), with unit-sell dimension a = 10.205 Å; b = 12.854 Å; c = 4.8822 Å. In addition, we found that the absorption edge of BNPM was 430 nm with a 0.9-mm-thick crystal, and we observed the second harmonic light with BNPM single crystal at the wavelength of 1064 nm and in the range from 906 nm to 990 nm. 相似文献
80.
Friendly walkers is a stochastic model obtained from independent one-dimensional simple random walks {S
k
j
}
j≥0
, k=1,2,…,d by introducing ``non-crossing condition': and ``reward for collisions' characterized by parameters . Here, the reward for collisions is described as follows. If, at a given time n, a site in ℤ is occupied by exactly m≥2 walkers, then the site increases the probabilistic weight for the walkers by multiplicative factor exp (β
m
)≥1. We study the localization transition of this model in terms of the positivity of the free energy and describe the location
and the shape of the critical surface in the (d−1)-dimensional space for the parameters .
Received: 13 June 2002 / Revised version: 24 August 2002 Published online: 28 March 2003
Mathematics Subject Classification (2000): 82B41, 82B26, 82D60, 60G50
Key words or phrases: Random walks – Random surfaces – Lattice animals – Phase transitions – Polymers – Random walks 相似文献