Mechanistic study on adsorptive removal of tert-butanethiol on Ag-Y zeolite under ambient conditions

The dynamics and surface chemistry of tert-butanethiol (TBT) adsorptive removal over silver-exchanged Y zeolite (Ag-Y) were studied under ambient conditions. Saturation uptake on Ag-Y was higher than that on H-Y and Na-Y. The structural analyses by a combination of X-ray diffraction, Ag K-edge X-ray absorption near-edge structure (XANES)/extended X-ray absorption fine structures (EXAFS), Ag L(III)-edge XANES, S K-edge XANES, and in situ UV-vis show that the AgSH molecule, Ag(2)S monomer, and Ag(4)S(2) cluster are the dominant silver species in TBT-saturated Ag-Y. Dynamic changes in adsorbed intermediates, gas-phase products, and the silver sulfides were followed by in situ FTIR, mass spectroscopy and in situ UV-vis, respectively. The results show the following reaction mechanism: (1) formation of iso-butene and adsorbed H(2)S on the Ag(+) site via C-S cleavage of hydrogen-bonded TBT initially adsorbed on the Ag(+) site; (2) conversion of the adsorbed H(2)S to AgSH and H(+) on zeolite; (3) the reaction of two Ag-SH species to yield Ag(2)S and H(+) on zeolite.     

Ab initio study of the molecular vibrations and electronic structure of the X,B, D and F2Σ+ states of AlO

Molecular vibrations and electronic structure of the X²Σ⁺, B²Σ⁺, D²Σ⁺, and F²Σ⁺ states of AlO are studied by carrying out ab initio configuration interaction calculations and molecular vibration calculations using accurate potential energy functions. An avoided crossing between the D²Σ⁺ and F²Σ⁺ potential energy curves occurs in the neighborhood of 4.0 a₀ and results in irregular vibrational levels of the D and F²Σ⁺ states. The vibrational constants for the F²Σ⁺ state are predicted from the vibrational levels not involved in the irregularity. Configuration mixing is important in describing the B, D, and F²Σ⁺ states. The F²Σ⁺ state at and around its well minimum and the D and F²Σ⁺ states in the avoided crossing region are characterized in terms of their main configurations and dipole moment functions.     

A variational problem for pullback metrics

Let (M, g) and (N, h) be Riemannian manifolds without boundary and let f : M → N be a smooth map. Let ||f^*h||{\|f^*h\|} denote the norm of the pullback metric of h by f. In this paper, we consider the functional F(f) = ò_M ||f^*h||² dv_g{{\Phi (f) = \int_M \|f^*h\|^2 dv_g}}. We prove the existence of minimizers of the functional Φ in each 3-homotopy class of maps, where maps f ₁ and f ₂ are 3-homotopic if they are homotopic on the three dimensional skeltons of a triangulation of M. Furthermore, we give a monotonicity formula and a Bochner type formula.     

Biharmonic hypersurfaces in a Riemannian manifold with non-positive Ricci curvature

In this article, we show that, for a biharmonic hypersurface (M, g) of a Riemannian manifold (N, h) of non-positive Ricci curvature, if ò_M|H|² v_g < ￥{\int_M\vert H\vert^2 v_g<\infty}, where H is the mean curvature of (M, g) in (N, h), then (M, g) is minimal in (N, h). Thus, for a counter example (M, g) in the case of hypersurfaces to the generalized Chen’s conjecture (cf. Sect. 1), it holds that ò_M|H|² v_g=￥{\int_M\vert H\vert^2 v_g=\infty} .     

Evaluation of electrodeposited gold nanostructures for applications in QCM sensing

The electrodeposition of gold nanostructures increases the surface area of a biosensor, which brings an enhancement of the sensitivity by increasing the amount of analyte binding to the surface. To evaluate the relationship among the surface structure, the area and the analyte binding, we quantitatively analyzed them for quartz crystal microbalance (QCM) sensing by scanning electron microscopy and cyclic voltammetry measurements. The results indicate a several-times increase of analyte bindings, and also the limitation of the sensing performance.     

Simple and sensitive method for determination of glycoalkaloids in potato tubers by high-performance liquid chromatography with chemiluminescence detection

A novel, simple and sensitive high-performance liquid chromatographic method for the determination of the potato glycoalkaloids, alpha-solanine and alpha-chaconine, based on the chemiluminescent reaction of tris(2,2'-bipyridine)ruthenium(III) has been developed. The calibration graph was linear in the range of 5 ng/ml-10 microg/ml for both alpha-solanine and alpha-chaconine. The detection limits of alpha-solanine and alpha-chaconine were 1.2 and 1.3 ng/ml, respectively. This method was successfully applied to a potato tuber sample without cleanup, pre-concentration, and derivatization steps. The recoveries (mean +/- standard deviation, %) of alpha-solanine and alpha-chaconine spiked in tuber pith at 10 microg/g (n = 6) were 101.0 +/- 4.4% and 103.6 +/- 7.1%, respectively.     

On the Existence of n-Harmonic Spheres

Using the bubbling argument of Sacks and Uhlenbeck, we prove the existence of n-harmonic maps from the n-sphere to Riemannian manifolds. An application is made to a problem concerning manifolds with strongly pth moment stable stochastic dynamical systems.     

Rotationally symmetric symphonic maps

Annals of Global Analysis and Geometry - We consider a functional of pullbacks of metrics on the space of maps f between Riemannian manifolds. Harmonic maps are stationary points of the energy...