全文获取类型
收费全文 | 578篇 |
免费 | 35篇 |
国内免费 | 6篇 |
专业分类
化学 | 515篇 |
晶体学 | 5篇 |
力学 | 4篇 |
数学 | 29篇 |
物理学 | 66篇 |
出版年
2023年 | 5篇 |
2022年 | 3篇 |
2021年 | 10篇 |
2020年 | 8篇 |
2019年 | 19篇 |
2018年 | 10篇 |
2017年 | 6篇 |
2016年 | 18篇 |
2015年 | 11篇 |
2014年 | 19篇 |
2013年 | 30篇 |
2012年 | 33篇 |
2011年 | 37篇 |
2010年 | 15篇 |
2009年 | 15篇 |
2008年 | 34篇 |
2007年 | 39篇 |
2006年 | 36篇 |
2005年 | 34篇 |
2004年 | 28篇 |
2003年 | 30篇 |
2002年 | 18篇 |
2001年 | 10篇 |
2000年 | 9篇 |
1999年 | 8篇 |
1998年 | 12篇 |
1997年 | 7篇 |
1996年 | 13篇 |
1995年 | 3篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1989年 | 2篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1973年 | 2篇 |
1971年 | 1篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1966年 | 1篇 |
排序方式: 共有619条查询结果,搜索用时 15 毫秒
21.
Oki Michinori Toyofuku Yoshitaka Sakaue Tatsuya Hirose Takanori Asakura Mitsuhiro Morita Nobuhiro Toyota Shinji 《Russian Journal of Organic Chemistry》2003,39(4):542-553
X-ray crystallography of the ap-form of the 1-(9-fluorenyl)-2-(2-methyl-2-oxiranyl)naphthalene has revealed that the carbon atom of the oxirane which is connected to the naphthyl group in this compound is almost planar. The specific structural features of the epoxy ring in this compound are caused by sterical effects and by the presence of a -system in the immediate vicinity of the oxirane ring. Certain differences have been found also in reactivity of rotational isomers of 2-X-substituted 1-[1-(9-fluorenyl)-2-naphthyl]ethyl cations (X = O, S, Se). At X = O arose more deprotonation product from the -position of the oxygen than in reactions of sulfur and selenium-containing analogs. Reactions of epoxides with zinc chloride almost exclusively gave the corresponding aldehydes. 相似文献
22.
Yoshiyuki Mizuhata Nobuhiro Takeda Norihiro Tokitoh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):947-948
The reductive debromination of an very crowded bis(bromodiaryl- silyl)butadiyne 2 was performed with potassium graphite to give the corresponding 2-allenyl-1-benzosilole 3 was isolated as a main product. 相似文献
23.
24.
General acid‐catalyzed reaction can be enhanced by the addition of base. Self‐catalyzed esterification of benzoic acid and octan‐1‐ol was enhanced by the addition of certain base such as imidazole. The rate of the esterification was accelerated as the concentration of imidazole increased. Trans‐esterification of 4‐nitrophenyl acetate was promoted in chloroform by the mixture of benzoic acid and imidazole, but not by benzoic acid or imidazole alone. 相似文献
25.
26.
27.
Masayuki Kirihara Takuya Noguchi Nobuhiro Okajima Sayuri Naito Yuki Ishizuka Aiko Harano Hiroyuki Tsukiji Ryu Takizawa 《Tetrahedron》2012,68(5):1515-1520
The reaction of dithioacetals with 30% hydrogen peroxide in the presence of catalytic amounts of tantalum(V) and iodide ion effectively produced carbonyl compounds in high yields. Dithioacetals also can be deprotected using the niobium(V) catalyzed oxidation of iodide ion by hydrogen peroxide under mild conditions. 相似文献
28.
29.
Nobuhiro Takeda Norihiro Tokitoh Renji Okazaki 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):633-636
The first rotational isomers of stable selenoaldehydes are synthesized by deselenation of cyclic polyselenides having an efficient steric protection group, 2, 4, 6-tris[bis(trimetylsilyl)methyl]phenyl (Tbt). Reactions of these selenoaldehydes with W(CO)5.THF gives the corresponding η1-selenoaldehyde tungsten complexes, the structures of which are established by X-ray crystallography. 相似文献
30.
Fumiko Fujisaki Sachi Hiromatsu Yumiko Matsumura Aki Fukami Nobuhiro Kashige Fumio Miake Kunihiro Sumoto 《Journal of heterocyclic chemistry》2013,50(2):417-424
In connection with our studies on antibacterial active compounds in the class of new oxazolidinones against Gram‐positive (Staphylococcus aureus) and Gram‐negative (Escherichia coli) strains, some molecular modifications were attempted. In this study, molecular modifications of 4‐aminomethyloxazolidin‐2‐ones ( 3a ) to the corresponding 4‐acylaminomethyloxazolidin‐2‐one derivatives ( 3c–d ) and preparations of the represented twin‐drug type molecules ( 10–14 ) were investigated. Some additional 4‐dialkylaminomethyloxazolidin‐2‐ones ( 2 ) were also synthesized. The synthesized compounds were evaluated for antibacterial activity with Gram‐positive (S. aureus) and Gram‐negative (E. coli) strains. 相似文献