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排序方式: 共有241条查询结果,搜索用时 171 毫秒
51.
M Tada S Zhang S Malwadkar N Ishiguro J Soga Y Nagai K Tezuka H Imoto S Otsuka-Yao-Matsuo S Ohkoshi Y Iwasawa 《Angewandte Chemie (International ed. in English)》2012,51(37):9361-9365
Breaking news: A unique discontinuous property and an active phase of Ni/ordered Ce(2) Zr(2) O(x) (x=7-8) solid-solution catalysts were observed during methane steam reforming. The catalytic performance of Ni/Ce(2) Zr(2) O(x) strongly depended on the phase and oxygen content of the Ce(2) Zr(2) O(x) support. 相似文献
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53.
In this work, bifurcation control using a piezoelectric actuator isimplemented to stabilize the parametric resonance induced in acantilever beam. The piezoelectric actuator is attached to the surfaceof the beam to produce a bending moment in the beam. The dimensionlessequation of motion for the beam with the piezoelectric actuator on itssurface is derived and the modulation equations for the complexamplitude of an approximate solution are obtained using the method ofmultiple scales. We then acquire the bifurcation set that expresses theboundary of the stable and unstable regions. The bifurcation set ischaracterized by the modulation equations. Next, we determine the orderof feedback gains to modify these modulation equations. By actuating thepiezoelectric actuator under the appropriate feedback, bifurcationcontrol is carried out resulting in the shift of the bifurcation set andthe expansion of the stable region. The main characteristic of thestabilization method introduced above is that the work done by thepiezoelectric actuator is zero in the state where the parametricresonance is stabilized. Thus zero power control is realized in such astate. Experimental results show the validity of the proposedstabilization method for the parametric resonance induced in thecantilever beam. 相似文献
54.
For the purpose of utilizing ESDIAD as a real-time probe for surface processes, we have developed an instrument which can measure ESDIAD images and time of flight (TOF) spectra of desorbing ions in temperature-programmed surface processes. TOF measurements are carried out to identify the mass and to determine the kinetic energy distribution of the desorbed ions. This temperature-programmed (TP-) ESDIAD/TOF system was used to observe coadsorption layers of methylamine and CO on Ru(001) which have been previously studied by our group using LEED, TPD and HREELS, also drawing upon a comparison of findings with the coadsorption system of CO and ammonia. ESDIAD images acquired for temperature-programmed surface processes in real time were found to provide new insight into the dynamic behaviour of the coadsorption layers. As to the pure adsorption of ammonia and methylamine, the second and the first (chemisorbed) layers can be easily discriminated in their different ESD detection efficiency due to the difference in neutralization rate. The intensity change of H+ ions with temperature shows the process of the decomposition of methylamine to be dependent on CO coverage. The intensity of O+ originating from CO changes due to the change of CO adsorption site in the reaction process. The angular distribution of H+ ions which correspond to CH2=NH…Ru species appears at 250–300 K in the presence of high CO pre-coverage. 相似文献
55.
Dr. Kosuke Ono Shunsuke Shimo Dr. Kohei Takahashi Dr. Nobuhiro Yasuda Dr. Hidehiro Uekusa Prof. Nobuharu Iwasawa 《Angewandte Chemie (International ed. in English)》2018,57(12):3113-3117
Dynamic interconversion between large covalent organic cages was achieved simply by heating or acid/base treatment. A mixture of the boroxine cages 12‐mer and 15‐mer was cleanly converted into a pyridine adduct of the 9‐mer boroxine cage upon treatment with pyridine, and the geometry of N‐coordinated boron atoms changed from trigonal to tetrahedral. The reverse reaction was achieved by heating or acid treatment. In this process, the larger boroxine cages 12‐mer and 15‐mer were found to be entropically favored owing to the release of free pyridine molecules from 9‐mer ?6 Py. 相似文献
56.
Utilization of Donor–Acceptor Interactions for the Catalytic Acceleration of Nucleophilic Additions to Aromatic Carbonyl Compounds
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Tatsuhiro Uchikura Dr. Kosuke Ono Dr. Kohei Takahashi Prof. Nobuharu Iwasawa 《Angewandte Chemie (International ed. in English)》2018,57(8):2130-2133
A conceptually new method for the catalytic electrophilic activation of aromatic carbonyl substrates, by utilizing donor–acceptor interactions between an electron‐deficient macrocyclic boronic ester host ( [2+2] BTH‐F ) and an aromatic carbonyl guest substrate, was realized. In the presence of a catalytic amount of [2+2] BTH‐F , dramatic acceleration of the nucleophilic addition of a ketene silyl acetal towards either electron‐rich aromatic aldehydes or ketones was achieved. Several control experiments confirmed that inclusion of the aromatic substrates within [2+2] BTH‐F , through efficient donor–acceptor interactions, is essential for the acceleration of the reaction. 相似文献
57.
[reaction: see text] Oligomerization of Pd(OAc)2(L)2 (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis. 相似文献
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59.
Tetsuo Iwasawa 《Tetrahedron letters》2008,49(36):5244-5246
A straightforward route to functionalized pentaarylbenzene derivatives is described, involving the effective lithiation method of 1-iodo-2,3,4,5,6-pentaarylbenzene. The activated pentaarylbenzene is a potential synton for producing organic materials. 相似文献
60.
Dr. Naoyuki Toriumi Kazuya Yamashita Prof. Dr. Nobuharu Iwasawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(49):12635-12641
A metal-free photoredox-catalyzed hydrodefluorination of fluoroarenes was achieved by using N,N,N’,N’-tetramethyl-para-phenylenediamine ( 1 ) as a strong photoreduction catalyst. This reaction was applicable not only to electron-rich monofluoroarenes but also to polyfluoroarenes to afford non-fluorinated arenes. The experimental mechanistic studies indicated that the amide solvent NMP plays an important role for regeneration of the photocatalyst, enabling additive-free photoreduction catalysis. 相似文献