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排序方式: 共有108条查询结果,搜索用时 15 毫秒
91.
Tatsuyoshi Ito Prof. Dr. Nobuharu Iwasawa Dr. Jun Takaya 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):12011-12015
An unprecedented photo-promoted skeletal rearrangement reaction of phosphine–borane frustrated Lewis pairs, o-(borylaryl)phosphines, involving cleavage of an unstrained sp2C–sp3C σ-bond is reported. The reaction realizes an efficient synthesis of cyclic phosphonium borate compounds. The reaction mechanism via a boranorcaradiene intermediate is proposed based on theoretical calculations. This work sheds light on the new photoreactivity of phosphine–borane FLPs. 相似文献
92.
Nobuharu Hisano Hiroo Iwata Yuji Teramura Hao Chen Yoshito Ikada 《Journal of polymer science. Part A, Polymer chemistry》2011,49(3):671-679
Kinetic analyses were carried out for formation of disulfide crosslinkages between thiol groups on linear polymers, poly(acrylamide‐co‐N‐acrylcysteamine) (P‐SH). Disulfide crosslinkages were formed by auto‐oxidation of pendant thiol groups or through the thiol‐disulfide exchange reaction induced by addition of disulfide compounds gluthathione. In the auto‐oxidation reaction, the rate constant for disulfide formation highly depended on pH values of the reaction mixtures and the P‐SH concentrations. Gelation rate is too slow to enclose living cells into hydrogel under physiological pH 7.4. The hydrogel formation rate can be accelerated by addition of disulfides, such as oxidized glutathione. In the later case, oxygen in the reaction mixture is not consumed. The thiol‐disulfide exchange reaction is much more suitable for the cell encapsulation than the thiol auto‐oxidation reaction. These findings give a basis for enclosure of living cells in a hydrogel. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
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94.
Iwasawa N Otsuka M Yamashita S Aoki M Takaya J 《Journal of the American Chemical Society》2008,130(20):6328-6329
Synthesis of naphthalyne-Co2(CO)6 complexes, the first example of the aryne-Co2(CO)6 complex, was achieved via cyclization of acyclic alkyne-Co2(CO)6 complex precursors containing an allylsilane and an aldehyde moiety followed by dehydration. Unique reactivities of the complexes toward oxygen to give carboxylic acid derivatives and toward alkynes to give cyclopentadienone derivatives were also disclosed. 相似文献
95.
Noniterative phase retrieval from a single diffraction intensity pattern by use of an aperture array
Nakajima N 《Physical review letters》2007,98(22):223901
A noniterative method for retrieving the phase of a wave field from a diffraction intensity measurement in a coherent wave field is proposed. In this method, the phase can be calculated from analytic equations based on the properties of entire functions by use of Fourier transforms. This method requires only a single measurement of the intensity of a diffracted wave through an array filter of rectangular apertures and then does not need to use any lens systems and coherent reference waves. Therefore, it provides a potentially useful means for coherent imaging in a wide class of wave fields such as optical, x ray, electron, and atomic waves. 相似文献
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[STRUCTURE: SEE TEXT] Intermolecular 1,5-dipolar cycloaddition reaction of tungsten-containing vinylazomethine ylide, generated from o-(alk-3-en-1-ynyl)phenylbenzaldimines and tungsten carbonyl complex, with ketene acetals proceeds efficiently to give azepino[1,2-a]indole derivatives in good yield. Formation of [5+2] or [3+2] cycloadducts can be controlled by an appropriate choice of dipolarophile. 相似文献
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100.
Yamabe H Mizuno A Kusama H Iwasawa N 《Journal of the American Chemical Society》2005,127(10):3248-3249
A highly useful method for the construction of cyclopentanone derivatives fused with aromatic ring based on hydrorhodation-1,4-rhodium migration sequence is achieved. Treatment of 1-aryl-prop-2-yn-1-ols, which are easily accessible via an addition of acetylides to the corresponding aryl aldehydes, with a catalytic amount of [Rh(cod)2]2(BF4) and P(p-tolyl)3 in the presence of a base gives cyclopentanone derivatives in moderate to good yield. 相似文献