Micro flow injection analysis combined with a separation technique for the urinary glucose assay.

A urinary glucose assay has been investigated, employing a micro flow injection analysis (microFIA) combined with a separation technique of glucose from the analyte. The adsorption part using activated alumina for the glucose in the analyte can be successively integrated onto a microFI chip. The selective adsorption-desorption of glucose in the artificial urine can progress on the adsorption part. Along with this selective preconcentration of glucose, the typical FI peak of glucose can be obtained just by feeding the sample and deionized water as an elutant sandwiched with the reagent on the carrier stream. The glucose concentration in artificial urine can be quantitatively determined with the present microFIA system, while the interference of other components coexisting in urine occurs in the case of the conventional FIA system without any separation part. The described method serves as a template for improving the selectivity for the analyte in the multi-component system.     

Electron beam-induced decomposition of graphite fluoride

Irradiation of graphite fluoride with electron beams has been carried out on a electron probe microanalyzer. Radiation-induced decomposition took place predominantly instead of thermal decomposition. The decomposition tended to occur in the following order: powdery (CF)_n, white flaky (CF)_n, and (CF₂F)_n. The kinetics of the decomposition reaction induced by electron beams was evaluated by the ZAF correction of the measured intensities of F K- and C K-emission bands. It was found that the kinetic of the decomposition of graphite fluoride was of Avrami-Erofejev type; the rate equations were $\text{-}\text{ln}\text{(1?α)=kt}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ for (CF)_n and -ln(1?α)=kt² for (C₂F)_n. An application to the electron microbeam processing of graphite fluoride was suggested in relation to its unique physicochemical properties.     

Neutron matter densities in the even Ni isotopes

Elastic scattering of 1.047 GeV protons is studied on the isotopically enriched ^58,60,62,64Ni isotopes. A spin independent Glauber theory analysis allowed the extraction of nuclear matter densities for these targets.     

Synthesis in the diazasteroid group VI. A synthesis of 2,3-dimethoxy-15-methyl-8,15-diazaestra-1,3,5(10)triene

Homoveratrylamine (II) was condensed with 3-(2-carbomethoxyethyl)-1,3-dimethyl-2-pyrrol-idone (Ib) to furnish the corresponding amide (III), which was subjected to the Bischler-Napieralski reaction to afford the corresponding dihydroisoquinoline derivative (IV). Compound V was obtained by the reductive ring closure of Vila which was obtained by the hydrogena-tion of IV. The stereochemistry of V is proposed to have the anti-trans-trans quinolizidine conformation.     

Splittings of the octupole strength in Te isotopes

In the (p,p′) reaction on ¹³⁰Te, strong excitation of the second 3^? state was found at 3.36±0.01 MeV excitation energy. No strong second 3^? state was observed in the (p,p′) reaction on ¹²⁶Te.     

Energy levels of92Nb from 92Zr(p,nγ)92Nb

The energy levels of⁹²Nb were studied by means of the⁹²Zr(p, nγ) reaction. The deexcitation γ-rays were observed with a high-resolution Ge(Li) detector in the proton energy range 3.00–4.80 MeV in steps of about 25 keV. Many new excited states of ⁹²Nb were populated by this reaction. Excitation energies up to 1.77 MeV were determined with high precision, and a level scheme of ⁹²Nb is proposed. From a Hauser-Feshbach analysis, the γ-decay scheme and other information, the spin-parities of many levels were assigned.     

Carbon-13 NMR spectra of some epoxides derived from dicyclopentadiene

The ¹³C NMR spectra of a series of epoxides derived from endo- and exo-dicyclopentadiene and their partially hydrogenated compounds were determined to examine the substituent effects arising from the introduction of the oxirane ring in comparison with those found in other ring systems. The ¹³C signals of some epoxides were assigned by using lanthanide shift reagents. Characteristic substituent effects exerted by an oxirane ring were demonstrated. Marked steric γ-effects of ?8—13 ppm were observed at the bridge carbon signal in the bicyclo[2.2.1]heptane skeleton. Differences were found in the substituent effects between endo- and exo-dicyclopentadiene epoxides, and have been discussed in relation to the molecular geometry.     

Enhancement of optical birefringence in tellurite glasses containing silver nanoparticles induced via thermal poling

Wavelength-selective enhancement of optical birefringence has been observed in a tellurite glass containing silver nanoparticles (Ag NPs) induced via thermal poling. The birefringence appears as an optical rotation of linearly polarized light; a large optical rotation is observed at around the wavelength of localized surface plasmon resonance (LSPR) of Ag NPs. The optic axis is oriented along the electric field applied during the thermal poling, suggesting that birefringence induced in the glass matrix through the thermal poling is drastically enhanced by the NPs at around the LSPR. Because of the birefringence of the matrix, the wavelength of LSPR shifts depending on the polarization state of the incident light, which in turn induces the polarization dependence of the real part of the refractive index via the Kramers–Kronig relation.     

Analysis of detected signal performance in multi-tracks of optical disk memory using convex-shaped recording mark

The possibility of multi-valued optical disk memory by using a convex-shaped recording mark fabricated by two-photon absorption is investigated. We fabricate a numerical model for convex-shaped recording marks and evaluate the signal characteristics in terms of the signal-to-noise ratio (SNR). The numerical results show that 6 bit data can be realized when the acceptable average SNR is 2 and a length of the mark is 4T.