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41.
A series of new compounds Ln(Fe3+M2+)O4 [Ln : Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn] were successfully synthesized and their lattice constants were determined. These compounds have the same crystal structure as YbFe2O4 and Fe3+ and M2+ are both surrounded by five oxygen ions forming a trigonal bipyramid. The synthetic conditions are presented. They are strongly dependent upon the constituent cations of the compound. 相似文献
42.
T Sato T Fujiwara Y Abe M Itoh H Fukuda J Hatazawa K Kubota T Ido T Matsuzawa 《Radioisotopes》1989,38(1):7-12
We investigated glucose and amino acid metabolism in tumors and other organs using whole body autoradiography with a short-lived positron emitter and a long-lived beta emitter. The radioactive compounds used were 2-deoxy-2-[18F]-fluoro-D-glucose (18F-FDG) with a half life of 109.8 min and L-[methyl-14C]-methionine (14C-MET) with a half life of 5,730 years. A Donryu rat weighing about 150 g was subcutaneously inoculated at the back with experimental tumors of AH109A and AH272. 74 MBq (2 mCi) of 18F-FDG and 740 kBq (20 microCi) of 14C-MET was administered and after 30 min, the rat was sacrificed. Whole body frozen sections were obtained using autocryotome. For the 18F-FDG autoradiogram, the frozen sections were exposed to an X-ray film for 6 h. After seven days, these frozen sections were again exposed to 14C-MET for a week. Cross-contamination was minimized by adjusting the exposure time, the interval of exposures and the administered dose. The accumulation of the tracers was represented as the optical density ratio of the tissue of interest to the muscle. The tumor ratios were 12.5 for 18F-FDG and 8.6 for 14C-MET showing the highest accumulation in the whole body autoradiogram. In contrast the inflammatory tissue ratios were 1.27 for 18F-FDG and 0.77 for 14C-MET showing very low amino acid metabolism. With the present double tracer whole body autoradiogram, 18F-FDG accumulation was seen in the brain and the heart but not to the liver as against 14C-MET accumulation which was seen to the liver but not to the brain and the heart. 相似文献
43.
Noboru Matsumura Motoyuki Kusamiya Hiroo Inoue Masanori Yasui Fujiko Iwasaki 《Journal of heterocyclic chemistry》1995,32(4):1269-1275
1,3-Bis(p-substituted-phenylthiocarbamoyl)-2-imidazolidinethiones 3a-f reacted with bromine to give trithiadiazapentalene derivatives 5a-f , bearing the exocyclic C-N double bonds, in moderate yields. The molecular structure of 5b was elucidated by the X-ray crystallographic analysis. The treatment of 5b-f with hydrochloric acid gave the ring-opening products, 1,3-bis(p-substituted-phenylthiocarbamoyl)-2-imidazo-lidinones 9b-f , accompanied by the production of elemental sulfur. Reduction of 5b , 5d , and 5e with sodium borohydride gave the ring-opening compounds, 1,3-bis(p-substituted-phenylthiocarbamoyl)-2-imidazolidines 13b , 13d , and 13e respectively. 相似文献
44.
45.
The molecular displacements on the M011-->M101 phase transition of n-hexatriacontane (n-C36H74) have been investigated with an IR microscope designed for the oblique infrared transmission method. It has been clarified that two polytypic structures of the M011 modification, single-layered structure (Mon) and double-layered one (Orth II), both transform to the M101 modification of single-layered structure with their respective mechanisms. On the M011(Mon)-->M101 transition, the inclination direction of molecular axis is changed by 90 degrees through an intermediate state in which the molecular chain is set perpendicular to the basal plane of the single crystal. On the other hand, a polymorphic-polytypic composite structural change on the M011(Orth II)-->M101 transition is accomplished through two kinds of molecular displacements occurring alternately along the stacking direction of molecular layers. 相似文献
46.
The thermodynamic properties of the two polytypes of n-hexatriacontane (n-C36H74), single-layered structure Mon and double-layered structure Orth II have been investigated by means of solubility measurements and incoherent inelastic neutron scattering. The solubility measurements reveal that Orth II is more stable than Mon by 1.2 kJ/mol because of the advantage of larger entropy. The neutron scattering measurements show that the vibrational modes of Orth II shift to the lower frequencies compared with those of Mon in the frequency region below 120 cm(-1). The advantage of Orth II in vibrational entropy due to the low-frequency shifts is estimated to be 9.6 J K(-1)/mol at 288 K under the harmonic approximation, which nearly agrees with the entropy difference of 6.8 J K(-1)/mol between Mon and Orth II determined by solubility measurements. These results suggest that the difference in vibrational entropy due to low-frequency modes mainly contributes to the relative thermodynamic stabilities of polytypic structures of long-chain compounds. From the frequency of methyl torsional mode, it is suggested that the cohesive force at the lamellar interface is stronger in Mon than in Orth II. 相似文献
47.
Spectroscopic and excited-state properties of tri-9-anthrylborane (TAB), showing unique absorption and fluorescence characteristics originating from p(boron)-pi(anthryl group) orbital interactions, were studied in 12 solvents. Although the absorption maximum energy (nu(a)) of TAB which appeared at around 21 x 10(3) cm(-1) (band I) was almost independent of the solvent polarity parameter, f(X) (f(X) = (D(s) - 1)/(2D(s) + 1) - (n(2) - 1)/(2n(2) + 1) where D(s) and n represent the static dielectric constant and the refractive index of a solvent, respectively), the fluorescence maximum energy (nu(f)) showed a linear correlation with f(X). The f(X) dependence of the value of nu(a) - nu(f) demonstrated that the change in the dipole moment of TAB upon light excitation was approximately 8.0 D, indicating that absorption band I was ascribed to an intramolecular charge-transfer transition in nature. The excited electron of TAB was thus concluded to localize primarily on the p orbital of the boron atom. Furthermore, it was shown that the fluorescence lifetime and quantum yield of TAB varied from 11.8 to 1.1 ns and from 0.41 to 0.02, respectively, with an increase in f(X). The present results indicated that the nonradiative decay rate constant (k(nr)) of TAB was influenced significantly by f(X). Excited-state decay of TAB was understood by intramolecular back-electron (charge) transfer from the p orbital of the boron atom to the pi orbital of the anthryl group, which was discussed in terms of the energy gap dependence of k(nr). Specific solvent interactions of TAB revealed by the present spectroscopic and photophysical studies are also discussed. 相似文献
48.
M. Kubota 《Journal of Radioanalytical and Nuclear Chemistry》1983,78(2):295-305
Ion exchange resins are widely used in the field of nuclear industry. The present work aimed at the development of a method
for complete decomposition of cation exchange resins with H2O2 in the presence of Fe3+ ion. The decomposition reaction proceeded at ambient temperature and decomposition time was greatly shortened with increasing
concentration of Fe3+ ion rather than that of H2O2. The catalytic action of Fe3+ ion was suppressed with increase of HNO3 concentration. As much as 4 g of the air-dried resin could be decomposed with 8 ml of 30% H2O2, and the use of about 60 ml of 30% H2O2 resulted in the complete decomposition of organic carbon to CO2. Absence of any orgnaic carbon in the residual solution will simplify the final disposal. 相似文献
49.
Noboru Nakanishi 《General Relativity and Gravitation》1995,27(1):65-69
The conventional perturbative approach to quantum gravity is based on the expansion in powers of k, wherek denotes the Einstein gravitational constant. The introduction of a square root is due to the unreasonable postulate that thek0 limit of the gravitational field is ac-number. It is more natural that it is aq-number, which can be determined explicitly by the theory, and then the expansion becomes that in powers ofk but not of k. Thus the nonrenormalizability of Einstein gravity should be completely reconsidered in the light of the new expansion. 相似文献
50.
Edwards KW Ogg M Bellerive A Britton DI Hyatt ER MacFarlane DB Patel PM Spaan B Sadoff AJ Ammar R Baringer P Bean A Besson D Coppage D Copty N Davis R Hancock N Kelly M Kotov S Kravchenko I Kwak N Lam H Kubota Y Lattery M Momayezi M Nelson JK Patton S Poling R Savinov V Schrenk S Wang R Alam MS Kim IJ Ling Z Mahmood AH O'Neill JJ Severini H Sun CR Wappler F Crawford G Daubenmier CM Fulton R Fujino D Gan KK Honscheid K Kagan H Kass R Lee J Sung M White C Wolf A Zoeller MM Butler F Fu X Nemati B 《Physical review letters》1995,74(17):3331-3335