The application of the Mössbauer spectroscopy for the study of the contaminants in the double circuit water heat-carrier nuclear power plant

The iron containing corrosion products from water heat-carrier and deposits of the second circuit of the nuclear power plant were investigated by means of absorption Mössbauer spectroscopy. The nonstoichiometric magnetite and paramagnetic (superparamagnetic) iron oxide particles were found to be the main corrosion products. The fraction of the magnetically ordered phase varied in the range 0–100% depending on the location in the second circuit.     

Spatial correlation study of internal magnetic fields in magnets by μSR2-technique

It is shown that using position-sensitive detectors in μSR experiments to determine the muon stopping site in a target permits one to study correlation effects in μSR time histograms produced by the decay of muons stopping in the same domain, i.e. to obtain time correlators of μSR histograms of decays from a small region. These correlators contain information on the spatial correlation of magnetic fields in the sample under study. The proposed method (μSR²-technique) allows measuring correlation radii (r _c ) down to 10⁻⁵ cm in a bulk sample. Among interesting physical phenomena occuring overr _c≥3×10⁻⁶ cm are, for instance, long wavelength fluctuations of the order parameter near the phase transition point in ferromagnets and antiferromagnets and magnetic field correlations in magnet domains and spin glasses. One may use this method also on heavy-current accelerators producing pulsed muon beams to investigate the variation in time of spatial correlations in magnets, spin glasses and superconductors.     

An automated laboratory EXAFS spectrometer of Johansson type: indigenous development and testing

An automated linear laboratory EXAFS spectrometer of the Johansson type has been indigenously developed. Only two translational motions are required to achieve the necessary Rowland circle configuration for the (fixed) X-ray source, the dispersing and focusing bent crystal and the receiving slit. With the available crystals the spectral region from 5 to 25 keV can be scanned. The linear motions of the crystal and receiving slit including the detector assembly are achieved by employing software-controlled DC motors and utilizing optical encoders for position sensing. The appropriate rotation of the crystal is achieved by the geometry of the instrument. There is a facility to place the sample alternately in the path of the X-ray beam and out of the path to record both the incident X-ray intensityI ₀ and the transmitted intensityI employing the scintillation detector. An arrangement with a two-window proportional detector before the sample to measureI ₀ and the scintillation detector to recordI is also developed; in this case it is not necessary to oscillate the sample. Fast electronic circuits are employed to minimize counting errors. The instrument is user-friendly and it is operated through a menu-driven IBM compatible PC. EXAFS spectra of high resolution have been recorded using the spectrometer and employing the Si(111) reflecting planes; the X-ray source being a Rigaku 12 kW rotating anode with Cu target. We describe the spectrometer and discuss its performance with a few representative spectra.     

Variational principles of magnetostatics of superconductors. I

Fundamental and dual variational principles of magnetostatics of superconductors are formulated. It is shown how test fields can be expressed in terms of vector and scalar potentials. General consequences of the variational magnetostatic formulation are discussed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 97–102, September, 1991.     

Radiation heterogeneous processes of14C-acetic acid adsorbed in Na-Montmorillonite

This research addresses itself to the study of the mechanism of the acetic acid decarboxylation in Na-Montmorillonite exposed to ionizing radiation. The results obtained indicated that the decarboxylation reaction is enhanced several times by the irradiation. This behavior is probably due to an oxidation reaction at the edges of the clay. Also it is by energy transfer from the clay to adsorbed molecules by an interaction of non-equilibrium charge carriers with the adsorbed molecules.     

Kinetic study of n-heptane oxidation

The oxidation of n-heptane has been studied in a jet-stirred flow reactor in the temperature range 950–1200 K at atmospheric pressure for a wide range of fuel-oxygen equivalence ratios (0.2 to 2.0). A chemical kinetic reaction mechanism developed from previous studies on smaller hydrocarbons and extended to C₆ and C₇ species was used to reproduce the experimental data. Good agreement between computed and measured concentrations of major chemical species was obtained for the entire range of experimental conditions. Sensitivity analyses were carried out to identify the reactions having the greatest influence on the modeling results. The major reaction paths for n-heptane consumption and for the formation of the main products have been identified. In addition n-heptane ignition delays behind a reflected shock wave measured by other investigators were used to validate the present reaction mechanism at higher temperature and pressure.     

Scaling probability, key to the equilibrium statistical volume distribution in foams

The equilibrium statistical volume distribution in foams, which has been previously demonstrated to be the so-called log-normal, is accounted on probability grounds by a scaling law on the bubble's volume time-evolution. This law states that the conditional probability for a given bubble to have the volume v(t + Δt), he assumption that it was v(t), to depend solely on the relationship v(t + Δt)/v(t), and in particular, to be independent of the time t. The theoretical results, however, allow to go further. Indeed, since the time dependece of its parameters (expectation and variance) are given functions of time, only two parameters are necessary to describe completely the foam.     

Structure of fullerene-containing soot at different formation stages of arc discharge vaporization of graphite

Electron microscopy is used in a study of nanoclusters of the carbon soot deposited on a probe in different areas of arc discharge during graphite vaporization under conditions favorable for fullerene synthesis. It is found that the spatial network of soot nanoclusters consists of alternating regions of higher density or associates of carbon particles. Two types of nanoclusters have been identified with the correlation radii of the associates equal to 0.6–0.8 and 1.6–2.2 nm, respectively. Type I nanoclusters are dominant in the soot microparticles, and their structure shows practically no variations with increasing separation r of the soot collector from the discharge axis over the range of distances studied, r=1–9 cm. The effective radius R ₀ of the “elementary” particles making up the associates in the soot nanoclusters of Type I calculated with the use of scaling relationships is 0.15–0.17 nm and is close to the gas-kinetic radius of carbon atoms. Type II nanoclusters have been identified in soot collected at r>3 cm. Values of R ₀ calculated in this case are 0.6–0.9 nm and decrease with increasing r, which indicates the presence of fullerene molecules in these nanocluster associates.     

Kinetic theory of the generation of magnetic fields in the radiation-dominated stage of expansion of the universe

The system of linearized Einstein and Maxwell equations and a kinetic equation with model collision integral for the cosmological plasma are used to calculate the magnetic field generated by solenoidal perturbations in the radiation-dominated stage of expansion of the universe. The magnetic field is generated by two effects — the Harrison effect and a new effect due to kinetic processes. The second effect contributes to the magnetic field if solenoidal gravitational perturbations exist from the very beginning of the radiation-dominated stage.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 122–126, January, 1992.