全文获取类型
收费全文 | 8513篇 |
免费 | 259篇 |
国内免费 | 48篇 |
专业分类
化学 | 5514篇 |
晶体学 | 52篇 |
力学 | 255篇 |
数学 | 1485篇 |
物理学 | 1514篇 |
出版年
2023年 | 47篇 |
2022年 | 115篇 |
2021年 | 133篇 |
2020年 | 140篇 |
2019年 | 156篇 |
2018年 | 161篇 |
2017年 | 154篇 |
2016年 | 255篇 |
2015年 | 257篇 |
2014年 | 252篇 |
2013年 | 528篇 |
2012年 | 595篇 |
2011年 | 643篇 |
2010年 | 380篇 |
2009年 | 331篇 |
2008年 | 482篇 |
2007年 | 466篇 |
2006年 | 429篇 |
2005年 | 401篇 |
2004年 | 350篇 |
2003年 | 315篇 |
2002年 | 250篇 |
2001年 | 147篇 |
2000年 | 120篇 |
1999年 | 93篇 |
1998年 | 77篇 |
1997年 | 67篇 |
1996年 | 69篇 |
1995年 | 54篇 |
1994年 | 65篇 |
1993年 | 75篇 |
1992年 | 57篇 |
1991年 | 69篇 |
1990年 | 65篇 |
1989年 | 59篇 |
1988年 | 50篇 |
1987年 | 40篇 |
1985年 | 54篇 |
1984年 | 72篇 |
1983年 | 37篇 |
1982年 | 56篇 |
1981年 | 45篇 |
1980年 | 48篇 |
1979年 | 40篇 |
1978年 | 38篇 |
1977年 | 53篇 |
1976年 | 39篇 |
1975年 | 39篇 |
1974年 | 35篇 |
1973年 | 32篇 |
排序方式: 共有8820条查询结果,搜索用时 0 毫秒
11.
Pierre Crispel Pierre Degond Céline Parzani Marie-Hélène Vignal 《Comptes Rendus Mathematique》2004,338(4):327-332
In this Note, we propose three formulations of a model describing a quasi-neutral plasma with non-vanishing current. In order to study and compare the numerical efficiency of each formulation, two test-problems are implemented in one dimension. The first is a periodic perturbation of a uniform stationary plasma. The second is a case of plasma expansion in vacuum between two electrodes. To cite this article: P. Crispel et al., C. R. Acad. Sci. Paris, Ser. I 338 (2004). 相似文献
12.
13.
Celik Tarimci Anda? Karamustafa Kutalmi? Güven Mehmet Kabak Akgül Ye?ilada 《Analytical sciences》2003,19(9):1347-1348
The crystal structure of 1-[3-(3,4-dimethoxyphenyl)-2-propenoyl]pyrrolidine (C15H19NO3) (I) has been determined by X-ray analysis. It crystallizes orthorhombic space group Pbca with a = 24.295(3), b = 15.086(3), c = 7.552(3)A, V = 2768(1)A3, Z = 8, Dcalc = 1.254 g/cm3, mu = (Mo K(alpha)) = 0.87 cm(-1). The title compound has analgesic activity of cycloaliphatic amine part. The molecule is deviated from planar configuration. 相似文献
14.
15.
F. Grisch P. Bouchardy M. Péalat B. Chanetz T. Pot M. C. Coët 《Applied physics. B, Lasers and optics》1993,56(1):14-20
Rotational temperature and nitrogen number density are measured in the shock wave/boundary layer interaction region in the vicinity of a two-dimensional compression corner disposed in a low pressure, 55 K, Mach 10 hypersonic air flow. Spatially-resolved data are recorded using a nonlinear optical technique named dual-line coherent anti-Stokes Raman scattering (DLCARS). Averaged temperature and density profiles are compared with those predicted by a Navier-Stokes solver. Good agreement is found. 相似文献
16.
In the field of research on soluble conducting polymers, the poly(o-alkylanilines) are very interesting because we can expect them to give more soluble polymers and new properties. Like poly(o-propylaniline) (POP), which is more soluble than polyaniline (PANi), poly(o-hexylaniline) (POH) appears to be more soluble in organic solvents than POP because of the longer alkyl groups in the 2-position. The higher solubility confers better processability on this new polymer, and because of this solubility, an NMR study in solution became possible.The nitration of hexylbenzene and the reduction of the resulting product to o-hexylaniline were performed according to the literature. The chemical polymerization was easy and it is possible to produce this polymer in large quantities.The polymerization carried out in anhydrous NH4F, 2.35 HF medium and in 5 M perchloric acid gave a polymer with almost quantitative yield. The electrochemical behaviour of POH displayed faster electron transfers than PANi in organic solvents, depending on the acido-basicity level of the aqueous solutions. Unlike PANi, fractal growth was not observed. 相似文献
17.
18.
The purpose of this article is to support the idea that “whenever we can prove a limit theorem in the classical sense for a dynamical system, we can prove a suitable almost-sure version based on an empirical measure with log-average”. We follow three different approaches: martingale methods, spectral methods and induction arguments. Our results apply, among others, to Axiom A maps or flows, to systems inducing a Gibbs–Markov map, and to the stadium billiard. 相似文献
19.
Aza-Michael addition of optically pure 4-phenyl-2-oxazolidinone to 3,3,3-trifluoro-1-nitropropene proceeds smoothly at low temperature with a high yield. Diastereoselectivity of the addition depends on the base used and lithiated species proved to be highly efficient affording 92% de. Optically pure 1,2-diamino-3,3,3-trifluoropropane is prepared in 58% yield from the aza-Michael addition product through a three-step procedure. 相似文献
20.