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941.
Three new ruthenium(II)-arene halido complexes, [(η6-p-cymene) RuX(L)] (1–3), were synthesized in a reaction of [(η6-p-cymene)RuX2]2 with 5-chloro-1H-benzimidazole-2-carboxylic acid (HL) in ethanol (X = Cl (1), Br (2), I (3)). The complexes were characterized by elemental analysis, mass spectrometry, IR, 1H and 13C NMR spectroscopy. The cytotoxic activity of the ligand precursor and its ruthenium complexes was tested by MTT assay in human cancer cell lines: lung adenocarcinoma (A549), myelogenous leukemia (K562) as well as in one normal human fetal lung fibroblast cell line (MRC-5). The results show that ruthenium(II)-arene complexes possess enhanced cytotoxicity when compared to HL in the range of concentrations up to 300 µM. In terms of halido ligand substitution, cytotoxic activity toward A549 and K562 cell lines in 1–3 serie significantly increased (e.g., IC50 values for K562: 1: 205.76 µM; 2: 174.77 µM; 3: 83.97 µM). All studied compounds were found to be ineffective toward MRC-5. Hydrolysis of 1–3 was followed by UV-vis spectroscopy at 25?°C, revealing ligand-substitution reactions at the Ru(II) center. Compounds 2 and 3 underwent rapid hydrolysis ranging from a few minutes for the aquation to ca. 20?min, confirming typical Ru-arene behavior in aqueous solutions.  相似文献   
942.

Isotopes of hydrogen (3H, 2H) and oxygen (18O) are perfect candidates for groundwater tracers. A survey of isotopic composition of 34 groundwater samples and one Lake from Vojvodina region (Serbia) is presented here. Tritium activity concentration and stable isotope composition (δ2H, δ18O), as well as deuterium excess, were determined. The groundwater samples lie on the groundwater regression line. Minor deviations and a few lower deuterium excess values indicate waters recharged in a different climate regime and subjected to evaporation, respectively. According to the obtained results, most of the analyzed groundwater can be characterized as modern waters, recharged mostly from precipitation.

  相似文献   
943.
Rotationally resolved pulsed-field-ionization zero-kinetic-energy photoelectron spectra of the 00, 61 and 41 vibrational levels of the ground electronic state of the formaldehyde cation were recorded using a resonant three-color three-photon excitation scheme. The first adiabatic ionization energy of CH2O (87793.33(1.30) cm−1) and the rigid-rotor rotational constants (A+ = 8.874(8) cm−1, B+ = 1.342(15) cm−1, C+ = 1.148(18) cm−1) of the vibronic ground state of CH2O+ were derived. A strong a-type Coriolis interaction between the 61 and 41 vibrational levels was observed. The Coriolis coupling parameter and the deperturbed fundamental vibrational frequencies of the in-plane-rocking mode ν6 and the out-of-plane bending mode ν4 were determined to be 8.70(10) cm−1, 823.67(30) cm−1 and 1036.50(30) cm−1, respectively. The intensity distribution of the photoelectron spectra was analyzed in the realm of a simple photoionization model.  相似文献   
944.
We present 11B NMR studies of the 2D frustrated dimer spin system SrCu2(BO3)_{2} in the field range 27-31 T covering the upper phase boundary of the 1/8 magnetization plateau, identified at 28.4 T. Our data provide a clear evidence that above 28.4 T the spin superlattice of the 1/8 plateau is modified but does not melt even though the magnetization increases. Although this is precisely what is expected for a supersolid phase, the microscopic nature of this new phase is much more complex. We discuss the field-temperature phase diagram on the basis of our NMR data.  相似文献   
945.
We peruse various anomalous physical responses of the cubic (ferromagnetic SrRuO3 and paramagnetic CaRuO3) ruthenates, such as fractional power-law conductivity, anomalous Raman line shapes, and Hall currents. We show how these exciting power-law observations are naturally described within a new, local (orbital) non-Fermi-liquid state arising from strong, multiorbital Coulomb interactions. Introducing a multiorbital, correlated model treated within the dynamical mean-field theory, we also find two distinct relaxation rates for relaxation of transport in complete agreement with experiment.  相似文献   
946.
The motion of an optically trapped sphere constrained by the vicinity of a wall is investigated at times where hydrodynamic memory is significant. First, we quantify, in bulk, the influence of confinement arising from the trapping potential on the sphere's velocity autocorrelation function C(t). Next, we study the splitting of C(t) into C_{parallel}(t) and C_{perpendicular}(t), when the sphere is approached towards a surface. Thereby, we monitor the crossover from a slow t{-3/2} long-time tail, away from the wall, to a faster t{-5/2} decay, due to the subtle interplay between hydrodynamic backflow and wall effects. Finally, we discuss the resulting asymmetric time-dependent diffusion coefficients.  相似文献   
947.
This Letter demonstrates the transporting and focusing of laser-accelerated 14 MeV protons by permanent magnet miniature quadrupole lenses providing field gradients of up to 500 T/m. The approach is highly reproducible and predictable, leading to a focal spot of (286 x 173) microm full width at half maximum 50 cm behind the source. It decouples the relativistic laser-proton acceleration from the beam transport, paving the way to optimize both separately. The collimation and the subsequent energy selection obtained are perfectly applicable for upcoming high-energy, high-repetition rate laser systems.  相似文献   
948.
949.
Journal of Solid State Electrochemistry - The synergistic effects between two Keggin-type heteropoly acids (HPAs) and carbon surface were examined and elucidated. An improved high rate capability...  相似文献   
950.
Nonlinear Dynamics - Two types of constitutive equations consisting of instantaneous and power type hereditary contributions are proposed in order to model generalized capacitor (inductor). The...  相似文献   
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